Quinoxalines

Synthesis, Reactions, Mechanisms and Structure

  • Vakhid A. Mamedov

Table of contents

  1. Front Matter
    Pages i-xv
  2. Vakhid A. Mamedov
    Pages 1-4
  3. Vakhid A. Mamedov
    Pages 5-133
  4. Vakhid A. Mamedov
    Pages 135-210
  5. Vakhid A. Mamedov
    Pages 271-342
  6. Back Matter
    Pages 423-437

About this book

Introduction

This book reviews the fundamental aspects of quinoxaline chemistry: synthesis, reactions, mechanisms, structure, properties, and uses. The first four chapters present a survey of the developments in quinoxaline chemistry since the publication of the monograph on “Condensed Pyrazines” by Cheeseman and Cookson in 1979. These chapters give comprehensive coverage of all the methods of the synthesis of quinoxalines and  the important quinoxaline-containing ring systems such as thiazolo[3,4-a]-, pyrrolo[1,2-a]-, and imidazo[1,5-a]quinoxalines. Chapter five describes many new methods for the construction of quinoxaline macrocycles, which are important in applications such as optical devices and materials. The final chapter reviews all previously known rearrangements of heterocyclic systems that lead to benzimidazole derivatives. Mamedov critically analyses these transformations to reveal a novel acid-catalyzed rearrangement of quinoxalinones giving 2-heteroarylbenzimidazoles and 1-heteroarylbenzimidazolones in the presence of nucleophilic reactants (MAMEDOV Heterocycle Rearrangement). This book is of interest to researchers in the fields of heterocyclic and synthetic organic chemistry. 

Keywords

Benzimidazoles Heterocyclic rearrangements Quinoxalines Quinoxalines macrocycles Quinoxalines synthesis biheterocyclic systems condensed imidazopyridines condensed pyrazines

Authors and affiliations

  • Vakhid A. Mamedov
    • 1
  1. 1.Kazan Scientific CenterA.E. Arbuzov Inst. of Org. and Phy. ChemKazanRussia

Bibliographic information

  • DOI https://doi.org/10.1007/978-3-319-29773-6
  • Copyright Information Springer International Publishing Switzerland 2016
  • Publisher Name Springer, Cham
  • eBook Packages Chemistry and Materials Science
  • Print ISBN 978-3-319-29771-2
  • Online ISBN 978-3-319-29773-6
  • About this book
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