Catalytic Ammonia Synthesis

Fundamentals and Practice

  • J. R. Jennings

Part of the Fundamental and Applied Catalysis book series (FACA)

Table of contents

About this book


The phenomenon of catalysis is found in many homogeneous and heterogeneous systems undergoing chemical change, where it effects the rates of approach to the equilibrium state in processes as diverse as those found in the stars, the earth's mantle, living organisms, and the various chemistries utilized by industry. The economies and the living standards of both developed and developing countries depend to varying degrees upon the efficacy of their chemical industries. Con­ sequently, this century has seen a wide exploration and expansion of catalytic chemistry together with an intensive investigation of specific, essential processes like those contributing to life-supporting agricultures. Prime among the latter must surely be the "fixation" of atmospheric nitrogen by catalytic hydrogenation to anhydrous ammonia, still the preferred synthetic precursor of the nitrogenous components of fertilizers. In each decade contemporary concepts and techniques have been used to further the understanding, as yet incomplete, of the catalyst, the adsorbates, the surface reactions, and the technology of large-scale operation. The contributors to the present volume review the state of the art, the science, and the technology; they reveal existing lacunae, and suggest ways forward. Around the turn of the century, Sabatier's school was extending the descriptive catalytic chemistry of hydrogenation by metals to include almost all types of multiple bond. The triple bond of dinitrogen, which continued to be more resistant than the somewhat similar bonds in carbon monoxide and ethyne, defied their efforts.


Ion carbon catalysis catalyst iron kinetics metals potassium

Editors and affiliations

  • J. R. Jennings
    • 1
  1. 1.ICI Chemicals and Polymers Ltd.Wilton, ClevelandEngland

Bibliographic information

  • DOI
  • Copyright Information Springer-Verlag US 1991
  • Publisher Name Springer, Boston, MA
  • eBook Packages Springer Book Archive
  • Print ISBN 978-1-4757-9594-3
  • Online ISBN 978-1-4757-9592-9
  • Series Print ISSN 1574-0447
  • Buy this book on publisher's site
Industry Sectors
Materials & Steel
Chemical Manufacturing
Oil, Gas & Geosciences