Interfacial Nanochemistry

Molecular Science and Engineering at Liquid—Liquid Interfaces

  • Hitoshi Watarai
  • Norio Teramae
  • Tsuguo Sawada

Part of the Nanostructure Science and Technology book series (NST)

Table of contents

  1. Front Matter
    Pages i-xiv
  2. Raymond R. Dagastine, Geoffery W. Stevens
    Pages 77-95
  3. Andriy Kovalenko, Fumio Hirata
    Pages 97-125
  4. Toshiyuki Osakai, Hiroki Hotta
    Pages 171-188
  5. Norio Teramae, Seiichi Nishizawa, Akira Yamaguchi, Tatsuya Uchida
    Pages 233-248
  6. Shoji Ishizaka, Noboru Kitamura
    Pages 249-269
  7. Tsutomu Ono, Masahiro Goto
    Pages 287-302
  8. Back Matter
    Pages 303-321

About this book


The history of the liquid-liquid interface on the earth might be as old as that of the liquid. It is plausible that the generation of the primitive cell membrane is responsible for an accidental advent of the oldest liquid interfaces, since various compounds can be concentrated by an adsorption at the interface. The presence of liquid-liquid interface means that real liquids are far from ideal liquids that must be miscible with any kinds of liquids and have no interface. Thus it can be said that the non-ideality of liquids might generate the liquid-liquid interface indeed and that biological systems might be generated from the non-ideal interface. The liquid-liquid interface has been, therefore, studied as a model of biological membrane. From pairing two-phases of gas, liquid and solid, nine different pairs can be obtained, which include three homo-pairs of gas-gas, liquid-liquid and solid-solid pairs. The gas-gas interface, however, is practically no use under the ordinary conditions. Among the interfaces produced by the pairing, the liquid-liquid interface is most slippery and difficult to be studied experimentally in comparison with the gas-liquid and solid-liquid interfaces, as the liquid-liquid interface is flexible, thin and buried between bulk liquid phases. Therefore, in order to study the liquid-liquid interface, the invention of innovative measurement methods has a primary importance.


analytical chemistry catalyst electrochemistry metals nanochemistry photochemistry spectroscopy

Editors and affiliations

  • Hitoshi Watarai
    • 1
  • Norio Teramae
    • 2
  • Tsuguo Sawada
    • 3
  1. 1.Osaka UniversityOsakaJapan
  2. 2.Tohoku UniversityTohokuJapan
  3. 3.Tokyo UniversityTokyoJapan

Bibliographic information

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