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Vibrationally Excited Ozone Relaxation by CO

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Abstract

Time profiles of ozone concentration after pulsed UV laser photolysis in the O2- O3-Ar-CO mixture, measured using time-resolved absorption spectroscopy, are presented. The experimental results show the dominance of the stabilization channel over the reactive one for the interaction between the vibrationally excited ozone molecule O3(υ) and carbon monoxide CO. The rate constant of the process O3(υ)+CO→O3 + CO, obtained by processing experimental data by the kinetic modeling method is (1.5 ± 0.2) · 10−13 cm3/s.

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References

  1. W. T. Rawlins, J. Geophys. Res. 90, 12283 (1985).

    Article  ADS  Google Scholar 

  2. W. T. Rawlins, G. E. Caledonia, and R. A. Armstrong, J. Chem. Phys. 87, 5209 (1987).

    Article  ADS  Google Scholar 

  3. A. A. Pershin, A. P. Torbin, M. Heaven, and V. N. Azyazov, Kratkie Soobshcheniya po Fizike FIAN 42(12), 74 (2015) [Bulletin of the Lebedev Physics Institute 43, 20 (2016)].

    Google Scholar 

  4. V. N. Azyazov and M. C. Heaven, Int. J. Chem. Kinet. 47, 93 (2015).

    Article  Google Scholar 

  5. C. W. Rosenberg and D. W. Trainor, J. Chem. Phys. 61, 2442 (1974).

    Article  ADS  Google Scholar 

  6. J. I. Steinfield, S. M. Adler-Golden, and J.W. Gallagher, J. Phys. Chem. Ref. Data 16, 911 (1987).

    Article  ADS  Google Scholar 

  7. D. H. Stedman and H. Niki, Environ. Lett. 4(4), 303 (1973).

    Article  Google Scholar 

Download references

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Authors and Affiliations

  1. Samara Branch of the Lebedev Physical Institute, Russian Academy of Sciences, ul. Novo-Sadovaya 221, Samara, 443011, Russia

    A. P. Torbin, A. A. Pershin & V. N. Azyazov

  2. Samara National Research University, Moskovskoye shosse 34, Samara, 443086, Russia

    A. P. Torbin, A. A. Pershin, A. M. Mebel & V. N. Azyazov

  3. Florida International University., 11200 SW 8th St, Miami, FL, 33199, USA

    A. M. Mebel

Authors
  1. A. P. Torbin
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  2. A. A. Pershin
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  3. A. M. Mebel
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  4. V. N. Azyazov
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Corresponding author

Correspondence to A. P. Torbin.

Additional information

Original Russian Text © A.P. Torbin, A.A. Pershin, A.M. Mebel, V.N. Azyazov, 2018, published in Kratkie Soobshcheniya po Fizike, 2018, Vol. 45, No. 3, pp. 3–8.

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Torbin, A.P., Pershin, A.A., Mebel, A.M. et al. Vibrationally Excited Ozone Relaxation by CO. Bull. Lebedev Phys. Inst. 45, 67–70 (2018). https://doi.org/10.3103/S1068335618030016

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  • DOI: https://doi.org/10.3103/S1068335618030016

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