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Light-induced orientation of the molecules of nematic liquid crystals doped with comb-shaped polymers with different spatial distributions of chromophores

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Abstract

The orienting effect of light on nematic liquid crystals (NLCs) doped with comb-shaped polymers with different spatial distributions of side absorbing azobenzene fragments, i.e., a homopolymer (containing only azofragments), a block copolymer (containing additionally a block of non-absorbing fragments), and a statistical copolymer (containing randomly arranged absorbing and non-absorbing fragments) is experimentally studied. The light-induced Freedericksz transition threshold for the block copolymer is two times lower than that for the homopolymer. For NLC with statistical copolymer dopant, the first-order orientation transition with an extremely wide optical bistability region is observed.

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Correspondence to A. S. Zolot’ko.

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Original Russian Text © I.A. Budagovsky, A.S. Zolot’ko, T.E. Koval’skaya, M.P. Smayev, S.A. Shvetsov, N.I. Boiko, M.A. Bugakov, M.I. Barnik, 2014, published in Kratkie Soobshcheniya po Fizike, 2014, Vol. 41, No. 5, pp. 29–36.

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Budagovsky, I.A., Zolot’ko, A.S., Koval’skaya, T.E. et al. Light-induced orientation of the molecules of nematic liquid crystals doped with comb-shaped polymers with different spatial distributions of chromophores. Bull. Lebedev Phys. Inst. 41, 135–139 (2014). https://doi.org/10.3103/S1068335614050042

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  • DOI: https://doi.org/10.3103/S1068335614050042

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