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Formation of associates of solvated cations in salt solutions in polar dielectric liquids

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Abstract

Experimental results are presented on excitation of oscillations of polarization charges of solvated ions in an aqueous solution of a mixture of cerium and lead nitrates under an external asymmetric electric field and the directed motion of solvated cerium and lead cations, caused by this process. The applicability of the approximation of the existence of a self-consistent electric field in the solution volume to explain the observed frequency ranges of the manifestation of the effect of electroinduced selective drift of solvated cations is demonstrated. The results of a theoretical analysis of the possibility of forming associates from solvated ions are presented.

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References

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Authors and Affiliations

  1. Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991, Russia

    M. A. Kazaryan & A. N. Lobanov

  2. Tomsk Polytechnic University, pr. Lenina 30, Tomsk, 634050, Russia

    I. V. Shamanin, I. V. Lomov & S. Yu. Dolgopolov

Authors
  1. M. A. Kazaryan
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  2. I. V. Shamanin
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  3. I. V. Lomov
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  4. S. Yu. Dolgopolov
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  5. A. N. Lobanov
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Corresponding author

Correspondence to M. A. Kazaryan.

Additional information

Original Russian Text © M.A. Kazaryan, I.V. Shamanin, I.V. Lomov, S.Yu. Dolgopolov, A.N. Lobanov, 2011, published in Kratkie Soobshcheniya po Fizike, 2011, Vol. 38, No. 9, pp. 3–14.

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Kazaryan, M.A., Shamanin, I.V., Lomov, I.V. et al. Formation of associates of solvated cations in salt solutions in polar dielectric liquids. Bull. Lebedev Phys. Inst. 38, 247–254 (2011). https://doi.org/10.3103/S1068335611090016

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  • DOI: https://doi.org/10.3103/S1068335611090016

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