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Russian Journal of Non-Ferrous Metals

, Volume 58, Issue 6, pp 600–607 | Cite as

Preparation of V2O5 from Ammonium Metavanadate via Microwave Intensification

  • Bingguo Liu
  • Jinhui Peng
  • Libo Zhang
  • Junwen Zhou
  • C. Srinivasakannan
Metallurgy of Rare and Noble Metals
  • 19 Downloads

Abstract

Parameters of technique to prepare of V2O5 by microwave intensification from ammonium metavanadate were optimized using central composite design of response surface methodology. A quadratic equation model for decomposition rate was built and effects of main factors and their corresponding relationships were obtained. The microwave heating behavior indicated that ammonium metavanadate had weak capability to absorb microwave radiation, while V2O5 had good capability to absorb microwave radiation. The results of the statistical analysis showed that the decomposition rate of ammonium metavanadate was significantly affected by calcination temperature and calcination time in the range studied. The optimized conditions were as follows: calcination temperature 645.35 K, calcination time 9.66 min and 4.3 g, respectively. The decomposition rates of ammonium metavanadate were 99.13%, which coincided well with experiments values 99.33% under these conditions. These suggest that regressive equation fits the decomposition rates perfectly. XRD reveals that it is feasible to prepare the V2O5 by microwave intensification from ammonium metavanadate, which mixed with small amounts of V2O5.

Keywords

response surface methodology ammonium metavanadate microwave intensification vanadium pentoxide rising behavior 

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References

  1. 1.
    Bahgat, A.A., Ibrahim, F.A., and El-Desoky, M.M., Electrical and optical properties of highly oriented nanocrystalline vanadium pentoxide, Thin Sol. Films, 2005, vol. 489, no. 1–2, pp. 68–73.CrossRefGoogle Scholar
  2. 2.
    Losurdo, M., Barreca, D., Bruno, G., and Tondello, E., Spectroscopic ellipsometry investigation of V2O5 nanocrystalline thin films, Thin Sol. Films, 2001, vol. 384, no. 1, pp. 58–64.CrossRefGoogle Scholar
  3. 3.
    Weckhuysen, B.M. and Keller, D.E., Chemistry, spectroscopy and the role of supported vanadium oxides in heterogeneous catalysis, Catal. Today, 2003, vol. 78, no. 1–4, pp. 25–46.CrossRefGoogle Scholar
  4. 4.
    Ertl, G., Knozinger, H., and Weitkamp, J., Eds., Handbook of Hetero-Geneous Catalysis, Weinheim: Wiley-VCH, 1997.CrossRefGoogle Scholar
  5. 5.
    Hagen, J, Industrial Catalysis, A Practical Approach, Weinheim: Wiley-VCH, 1999.Google Scholar
  6. 6.
    Guan, Z.S., Yao, J.N., Yang, Y.A., and Loo, B.H., Electrochromism of the annealed vacuum-evaporated V2O5 films, J. Electroanal. Chem., 1998, vol. 443, no. 2, pp. 175–179.CrossRefGoogle Scholar
  7. 7.
    Rajendra Kumar, R.T., Karunagaran, B., Venkatachalam, S., Mangalaraj, D., Narayandass, Sa.K., and Kesavamoorthy, R., Influence of deposition temperature on the growth of vacuum evaporated V2O5 thin films, Mater. Lett., 2003, vol. 57, no. 24–25, pp. 3820–3825.CrossRefGoogle Scholar
  8. 8.
    Ozer, N., Electrochemical properties of sol gel deposited vanadium pentoxide films, Thin Sol. Films, 1997, vol. 305, no. 1–2, pp. 80–87.CrossRefGoogle Scholar
  9. 9.
    Cazzanelli, Mariotto, G., Passerini, S., Smyrl, W.H., Gorenstein, A., Energymater, Sol., Raman and XPS characterization of vanadium oxide thin films deposited by reactive RF sputtering, Energy Mater. Sol. Cells, 1999, vol. 56, no. 3–4, pp. 249–258.CrossRefGoogle Scholar
  10. 10.
    Bing Guo Liu, Jin Hui Peng, and Li Bo Zhang, Optimization of preparing V2O5 by calcination from ammonium metavanadate using response surface methodology, Trans. Nonferrous Met. Soc. China, 2011, vol. 21, no. 3, pp. 673–678.CrossRefGoogle Scholar
  11. 11.
    Ghanashyam Krishna, M., Debauge, Y., and Bhattacharya, A.K., X-ray photoelectron spectroscopy and spectral transmittance study of stoichiometry in sputtered vanadium oxide films, Thin Sol. Films, 1998, vol. 312, no. 1–2, pp. 116–122.CrossRefGoogle Scholar
  12. 12.
    Pickles, C.A., Microwave heating behaviour of nickeliferous limonitic laterite ores, Miner. Eng., 2004, vol. 17, pp. 775–780.CrossRefGoogle Scholar
  13. 13.
    Mujundar, Handbook of Industrial Drying, vol. 1/2, New York, USA: Marcel Dekker Inc., 1995.Google Scholar
  14. 14.
    Keysona, D., Volantic, D.P., and Cavalcanteb, L.S., Domestic microwave oven adapted for fast heat treatment of Ba0.5Sr0.5(Ti0.8Sn0.2)O3 oowders, J. Mater. Process. Technol., 2007, vol. 189, no. 1, pp. 316–319.CrossRefGoogle Scholar
  15. 15.
    Zhang, P., Ling, X.L., Xu, M.X., and Liu, L., The new red luminescent Sr3Al2O6:Eu2+ phosphor powders pynthesized via sol-gel route by microwave-assisted, J. Alloys Compd., 2008, vol. 456, no. 1, pp. 216–219.CrossRefGoogle Scholar
  16. 16.
    Menzies, D.B., Qing Dai, Yi-Bing Cheng, Simon, G.P., and Leone Spiccia, One-step microwave calcination of ZrO2-coated TiO2 electrodes for use in dye-sensitized solar cells, C. R. Chimie, 2006, vol. 9, pp. 713–716.CrossRefGoogle Scholar
  17. 17.
    Selmi, F., Guerin, F., Yu, X.D., and Varadan, V.K., Microwave calcination and sintering of barium strontium titanate, Mater. Lett., 1992, vol. 12, pp. 424–428.CrossRefGoogle Scholar
  18. 18.
    Guo Shenghui, Peng Jinhui, Fan Xingxiang, and Zhang Libo, Calcination of ZnCO3 · 2Zn(OH)2 · H2O by microwave heating, Nonferrous Met., 2002, vol. 54, no. 4, pp. 53–55.Google Scholar
  19. 19.
    Venter, G., Non-Dimensional Response Surfaces for Structural Optimization with Uncertainty, University of Florida, USA, 1998.Google Scholar
  20. 20.
    Shweta Sharma, Anushree Malik, and Santosh Satya, Application of response surface methodology (RSM) for optimization of nutrient supplementation for Cr(VI) removal by Aspergillus lentulus AML05, J. Hazard. Mater., 2009, vol. 164, no. 2–3, pp. 1198–1204.Google Scholar
  21. 21.
    Myers, R.H. and Montgomery, D.C., Response Surface Methodology, USA: John Wiley & Sons, Inc., 2002.Google Scholar
  22. 22.
    Chen, M.J., Chen, K.N., and Lin, C.W., Optimization on response surface models for the optimal manufacturing conditions of dairy tofu, J. Food Eng., 2005, vol. 68, no. 4, pp. 471–480.CrossRefGoogle Scholar
  23. 23.
    Azargohar, R. and Dahai, A.K., Production of activated carbon from luscar char: Experimental and modeling studies, Micropor. Mesopor. Mater., 2005, vol. 85, no. 3, pp. 219–227.CrossRefGoogle Scholar
  24. 24.
    Bingguo Liu, Jinhui Penga, Libo Zhang, Rundong Wan, and Shenghui Guo, Optimization of preparation for Co3O4 by calcination from cobalt oxalate using response surface methodology, Chem. Eng. Res. Design, 2010, vol. 88, pp. 971–976.CrossRefGoogle Scholar
  25. 25.
    Zhang Mei, Lin Qin, and Xu Ai-Ju, Application of thermal analysis in study of mechanism of thermal decomposition of NH4VO3, Modem. Sci. Instrum., 2007, no. 3, pp. 98–100.Google Scholar
  26. 26.
    Huang, Mengyang, Jinhui Peng, and Ying Lei, The temperature rise behavior and microwave-absorbing characteristics of ilmenite concentrate in microwave field, J. Sichuan Univ., 2007, vol. 39, pp. 111–115.Google Scholar
  27. 27.
    Bingguo Liu, Jinhui Peng, Libo Zhang, et al., Coupling and absorbing behavior of microwave irradiation on the Co(C2O4) · 2H2O:Co3O4 system, J. Taiwan Inst. Chem. Eng., 2011, vol. 42, pp. 92–96.CrossRefGoogle Scholar
  28. 28.
    Pickles, C.A., Microwave heating behaviour of nickeliferous limonitic laterite ores, Miner. Eng., 2004, vol. 17, pp. 775–784.CrossRefGoogle Scholar
  29. 29.
    Zhang Libo, Ma Aiyuan, Liu Chenhui, et al., Dielectric properties and temperature increase characteristics of zinc oxide dust from a fuming furnace, Trans. Nonferrous Met. Soc. China, 2014, vol. 24, no. 12, pp. 4004–4011.CrossRefGoogle Scholar
  30. 30.
    Istadi, I. and Amin, N.A.S., Optimization of process parameters and catalyst compositions in carbon dioxide oxidative coupling of methane over CaO–MnO/CeO2 catalyst using response surface methodology, Fuel Proc. Technol., 2006, vol. 87, pp. 449–459.CrossRefGoogle Scholar
  31. 31.
    Ahmadi, M., Vahabzadeh, F., Bonakdarpour, B., Mofarrah, E., and Mehranian, M., Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton’s peroxidation, J. Hazard. Mater. B, 2005, vol. 123, pp. 187–195.CrossRefGoogle Scholar
  32. 32.
    Korbahti, B.K. and Rauf, M.A., Determination of optimum operating conditions of carmine decoloration by UV/H2O2 using response surface methodology, J. Hazard. Mater., 2009, vol. 161, no. 1, pp. 281–286.CrossRefGoogle Scholar
  33. 33.
    Selim, S.A., Philip, Ch.A., and Mikhail, R.Sh., Thermal decomposition of ammonium metavanadate, Thermochim. Acta, 1980, vol. 36, pp. 287–297.CrossRefGoogle Scholar

Copyright information

© Allerton Press, Inc. 2017

Authors and Affiliations

  • Bingguo Liu
    • 1
    • 2
    • 3
  • Jinhui Peng
    • 1
    • 2
    • 3
  • Libo Zhang
    • 1
    • 2
    • 3
  • Junwen Zhou
    • 1
    • 2
    • 3
  • C. Srinivasakannan
    • 4
  1. 1.State Key Laboratory of Complex Nonferrous Metal Resources Clean UtilizationKunming University of Science and TechnologyKunmingChina
  2. 2.Faculty of Metallurgical and Energy EngineeringKunming University of Science and TechnologyKunmingChina
  3. 3.Key Laboratory of Unconventional Metallurgy, Ministry of EducationKunming University of Science and TechnologyKunmingChina
  4. 4.Chemical Engineering Departmentthe Petroleum InstituteAbudhabiUAE

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