Skip to main content
SpringerLink
Log in

Solidus Surface of the Mo–Ni–B System

  • Production, Structure, Properties
  • Published:
Journal of Superhard Materials Aims and scope Submit manuscript

Abstract

The Mo–Ni–B alloys with a boron content ca.41 at % were prepared by arc melting, annealed at subsolidus temperatures and studied by X-Ray diffraction method, differential thermal analysis and SEM/EPMA microscopy, and the incipient melting temperatures were measured by the Pirani-Alterthum technique. Based on the authors’ experimental data and in view of the data published elsewhere, the partial solidus surface projection has been constructed for the first time for the Mo–Ni–B system in the region Mo–MoB1.0–NiB∼0.8–Ni.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Komai, M., Yamasaki, Y., Ozaki, Sh., and Takagi, K., Mechanical properties of Mo2NiB2 base hard alloys and crystal structures of boride phases, J. Japan Inst. Metals, 1994, vol. 58, no. 8, pp. 959–965.

    Article  CAS  Google Scholar 

  2. Takagi, K., Yamasaki, Y., and Komai, M. High-strength boride base hard materials, J. Sol. State Chem., 1997, vol. 133, pp. 243–248.

    Article  CAS  Google Scholar 

  3. Yamasaki, Y., Nishi, M., and Takagi, K., Development of very high strength Mo2NiB2 complex boride base hard alloy, J. Sol. State Chem., 2004, vol. 177, pp. 551–555.

    Article  CAS  Google Scholar 

  4. Takagi, K., Development and application of high strength ternary boride base cermets, J. Sol. State Chem., 2006, vol. 179, pp. 2809–2818.

    Article  CAS  Google Scholar 

  5. Kublii, V. and Bondar, A., Boron-molybdenum-nickel, in: Landolt-Börnstein, Numerical Data and Functional Relationships in Science and Technology (New Series) Group IV: Physical Chemistry, Edited by W. Martinsen. Ternary Alloy Systems. Phase Diagrams, Crystallographic and Thermodynamic Data Critically Evaluated by MSIT, Edited by G. Effenberg, S. Ilyenko, Berlin, Heidelberg: Springer-Verlag, 2010, vol. 11E2, pp. 1–18.

    Google Scholar 

  6. Massalski, T.V., Binary Alloy Phase Diagrams, Edited by T.V. Massalski, P.R. Subramanian, H. Okomoto, L. Kasprzak: 2nd ed.; in 3 Volumes, Materials Park, Ohio (USA): ASM International, 1990.

  7. Lyakishev, N.P., Diagrammy sostoyaniya dvoinykh sistem: V 3 Tomakh (Phase Diagrams of Binary Systems. In 3 Volumes), Moscow: Mashinostroenie, 1996, vol. 1.

    Google Scholar 

  8. Schöbel, J.D. and Stadelmaier, H.H., Das zweistoffsystem nickel-bor, Z. Metallkunde, 1965, vol. 56, pp. 856–859.

    Google Scholar 

  9. Zhou, S.H., Wang, Y., Jiang, C., Zhu, J.Z., Chen, L.-Q., and Liu, Z.-K., First-principles calculations and thermodynamic modelling of the Ni–Mo system, Mater. Sci. Eng. A, 2005, vol. 397, pp. 288–296.

    Article  Google Scholar 

  10. Witusiewicz, V.T., Bondar, A.A., Hecht, U., Potazhevska, O.A., and Velikanova, T.Ya., Thermodynamic modeling of the ternary B–Mo–Ti system with refined B–Mo description, J. Alloys Compd., 2016, vol. 655, pp. 336–352.

    Article  CAS  Google Scholar 

  11. Villars, P. and Calvert, L.D., Pearson’s Handbook of Crystallographic Data for Intermetallic Phases, 2nd ed., 4 Volumes, Materials Park, Ohio (USA): ASM International, 1991.

    Google Scholar 

  12. Rogl, P. and Schuster, J., The system B–N–Mo, in Phase Diagrams of Ternary Boron Nitride and Silicon Nitride Systems. Materials Park, Ohio (USA): ASM International, 1992, pp. 64–67.

    Google Scholar 

  13. Kayser, G.F. and Kayser, F.X., Ni3B: powder diffraction pattern and lattice parameters, J. Alloys Comp., 1996, vol. 233, pp. 74–79.

    Article  CAS  Google Scholar 

  14. Lundström, T., Preparation and crystal chemistry of some refractory borides and phosphides, Arkiv Kemi, Mineral. Geol., 1969, vol. 31, no. 19, pp. 227–266.

    Google Scholar 

  15. Kuz’ma, Yu.B., Kryp’yakevych, P.I., and Skolozdra, R.V., Crystalline structures of the Mo2NiB2 compound and its analogs, DAN UkrRSR, 1966, no. 10, pp. 1290–1293.

    Google Scholar 

  16. Jedlicka, H., Benesovsky, F., and Nowotny, H., Die kristallstruktur des W3CoB3 und der dazu isotypen phasen Mo3CoB3, Mo3NiB3 und W3NiB3, Monatsh. Chem., 1969, vol. 100, no. 3, pp. 844–850.

    Article  CAS  Google Scholar 

  17. Omori, S., Koyama, K., Hashimoto, Ya., and Yamashita, M., Phase relations in Ni–Mo–B and Ni–W–B systems at 1223 K, J. Japan Inst. Metals, 1984, vol. 48, no. 7, pp. 682–687.

    Article  CAS  Google Scholar 

  18. Steinitz, R. and Binder, I., New ternary boride compounds, Powder Met. Bull., 1953, vol. 6, no. 4, pp. 123–125.

    Google Scholar 

  19. Haschke, H., Nowotny, H., and Benesovsky, F., Untersuchungen in den Dreistoffen {Mo, W}-{Fe, Co, Ni}-B, Monatsh. Chem., 1966, vol. 97, no. 5, pp. 1459–1468.

    Article  CAS  Google Scholar 

  20. Rieger, W., Nowotny, H., and Benesovsky, F., Die kristallstruktur von W2CoB2 und isotypen phasen, Monatsh. Chem., 1966, vol. 97, no. 2, pp. 378–382.

    Article  CAS  Google Scholar 

  21. Kolomytsev, P.T. and Moskaleva, N.V., Phase composition and some properties of alloys of the system molybdenum-nickel-boron, Powder Metall. Met. Ceram., 1966, vol. 5, issue 8, pp. 665–670.

    Article  Google Scholar 

  22. Morishita, M., Koyama, K., Yagi, S., and Zhang, G., Calculated phase diagram of the Ni–Mo–B ternary system, J. Alloys Com., 2001, vol. 314, pp. 212–218.

    Article  CAS  Google Scholar 

  23. Kuz’ma, Yu.B. and Chepiga, M.V., An X-ray diffraction investigation of the systems Ti–Ni–B, Mo–Ni–B, and W–Ni–B, Powder Metall. Met. Ceram., 1969, vol. 8, issue 10, pp. 832–835.

    Article  Google Scholar 

  24. Kocherzhinsky, Ju.A., Differential thermocouple up to 2450°C and thermographic investigations of refractory silicides. Thermal Analysis (vol. 1): Proc. Third ICTA (Davos). Basel: Birkhäuser Verlag, 1971, pp. 549–559.

    Google Scholar 

  25. Kocherzhinsky, Yu.A., Shishkin, E.A., and Vasilenko, V.I., An DTA apparatus with with a thermocouple transmitter up to 2200°C, in Diagrammy sostoyaniya metallicheskikh sistem (Phase Diagrams of Metallic Systems), Moscow: Nauka, 1971, pp. 245–249.

    Google Scholar 

  26. Kublii, V.Z., Utkin, S.V., Sleptsov, S., Dovbenko, A., and Bondar, A., Phase equilibria in the Mo-rich area of Mo–Ni–B system at temperatures of melting-crystallization, Sovr. Probl. Fiz. Materialoved. (Modern Problems in Physical Materials Science), Kyiv: Frantsevich Institute for Problems of Materials Science NASU, 2013, no. 22, pp. 10–22.

    Google Scholar 

  27. Pirani, M. and Alterthum, H., Über eine methode zur schmelzpunktbestimmung an hochschmelzenden metallen, Z. Elektrochem., 1923, vol. 29, no. 1/2, pp. 5–8.

    CAS  Google Scholar 

  28. Velikanova, T.Ya., Bondar, A.A., and Grytsiv, A.V., The chromium-nickel-carbon phase diagram, J. Phase Equilibria, 1999, vol. 20, no. 2, pp. 125–147.

    Article  CAS  Google Scholar 

  29. Koyama, K., Morishita, M., and Zhang, G., Calculated phase diagrams of the Ni–Mo–B and Ni–W–B ternary systems on the basis of the data obtained by thermodynamic measurement of the related materials, J. Jpn. Soc. Powder Metallurgy, 2006, vol. 53, no. 5, pp. 419–429.

    Article  CAS  Google Scholar 

  30. Ohmori, S., Hashimoto, Y., and Kohyama, K., Liquidus surface of the Ni–Mo–B system, Koon-gakkai-shi, 1981, vol. 7, no. 4, pp. 167–173.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Frantsevich Institute for Problems of Materials Science, National Academy of Sciences of Ukraine, vul. Krzhyzhanovskogo 3, Kyiv, 03680, Ukraine

    S. V. Utkin, V. Z. Kublii, S. V. Sleptsov, A. A. Bondar, P. P. Levchenko, G. A. Osokin & T. Ya. Velikanova

Authors
  1. S. V. Utkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Z. Kublii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Sleptsov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. A. Bondar
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. P. Levchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. G. A. Osokin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. T. Ya. Velikanova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. V. Utkin.

Additional information

Russian Text © The Author(s), 2019, published in Sverkhtverdye Materialy, 2019, Vol. 41, No. 5, pp. 3–19.

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Utkin, S.V., Kublii, V.Z., Sleptsov, S.V. et al. Solidus Surface of the Mo–Ni–B System. J. Superhard Mater. 41, 287–301 (2019). https://doi.org/10.3103/S1063457619050010

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S1063457619050010

Keywords

Search

Navigation