Abstract
The effect of high pressure (7.7 GPa) and temperature (1700°C) on the phase transformations of both graphene plates with a high degree of crystallinity having less than four layers and thickness not exceeding 5 nm and powders of multilayer graphenes (of 10–20 monolayers) and 8–12 nm in thickness was experimentally studied in the presence of carbon solvents (Ni–Mn alloy, iron). Factors both contributing and inhibiting the diamond synthesis from graphene in the presence of the solvents for carbon are defined. It is shown that the transformation of multilayer graphenes into diamond at high pressure and temperature by a two-stage scheme of the diamond synthesis (i.e., after three-dimensional structural ordering of graphene at the first stage) is preferable.
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Shul’zhenko, A.A., Synthesis of diamond crystals at high static pressures, 5th Int. Symposium on High Purity Materials in Science and Technology, Dresden, GDR: May 5–9, 1980, Dresden, GDR: Zentralinst. für Festktrperphysik und Werkstofforschung, 1980, Proc. 1, pp. 122–128.
Wentorf, R.H., The behavior of some carbonaceous materials at very high pressures and high temperatures, J. Phys. Chem., 1965, vol. 69, no. 9, pp. 3063–3069.
Prikhna, A.I., Shul’zhenko, A.A., Zhitnetsky, V.I., et al., Influence of the graphite structure on the synthesis of diamond, Superhard Mater., 1980, no. 2, pp. 3–5.
Prikhna, A.I., Shulzhenko, A.A., and Katsay, M.Ya., On the question of the role of graphite crystallites in the diamond synthesis process, Sinteticheskie Almazy, 1974, no. 4, pp. 3–8.
Shul’zhenko, A.A. and Sokolov, A.N., Effect of the graphite particles sizes (including the nanorange) on the p,T conditions of the diamond synthesis, Nanosystems, Nanomaterials, Nanotechnologies, 2008, vol. 64, no. 4, pp. 1219–1226.
Sorokin, P.B., Theoretical studies of physicochemical properties of low-dimension structures, Doctoral (Phys.Math.) Dissertation, Moscow, 2014.
Novoselov, K.S., Geim, A.K., Morozov, S.V., et al., Electric field effect in atomically thin carbon films, Science, 2004, vol. 306, no. 10, pp. 666–669.
Kostogrud, I.A., Zamchiy, A.A., Baranov, E.A., et al., Synthesis of multilayer graphene by gaseous-phase deposition on copper, Modern Problems of Science and Education, 2013, no. 5.
Morozov, S.V., Novoselov, K.S., Katsnelson, M.I., et al., Giant intrinsic carrier mobilities in graphene and its bilayer, Phys. Rev. Lett., 2008, vol. 100, no. 1, p. 016602.
Clark, S.M., Jeon, Ki-Joon, Chen, Jing-Yin, and Yoo, Choong-Shik, Few-layer graphene under high pressure: Raman and X-ray diffraction studies, Solid State Commun., 2013, vol. 154, no. 1, pp. 15–18.
Lu, Sh., Yao, M., Yang, X., et al., High pressure transformation of graphene nanoplates: A Raman study, Chem. Phys. Let., 2013, vol. 585, pp. 101–106.
Antipina, L.Yu., Sorokina, T.P., and Sorokin, P.B., Transformation of a multilayer graphene into a diamond film under the action of chemical functionalization: theoretical study, in Abstracts of Papers of the 9th Int. Conference on Carbon: Fundamental Problems of Science, Material Science, Technology, Moscow, Troitsk, 2014, pp. 32–34.
Kvashnin, A.G., Sorokin, P.B., and Billups, W.E., Formation of nanodiamonds in amorphous carbon under the action of ionizing radiation, Ibid., pp. 216–218.
Kvashnin, A.G., Chernozatonskii, L.A., Yakobson, B.I., and Sorokin, P.B., Phase diagram of quasi-two-dimensional carbon, Nano Letters, 2014, viol. 14, no. 2, pp. 676–681.
Ferrari, A.C., Meyer, J.C., Scardaci, V., et al., Raman spectrum of graphene and graphene layers, Phys. Rev. Lett., 2006, vol. 97, no. 18, art. 187401(4).
Shmidt, U., Diing, T., Ibakh, V., and Khollrikher, O., Investigation of graphene: Confocal Raman and atomic-force microscopies, Nanoindustry, 2012, no. 6, pp. 48–51.
Casiraghi, C., Hartschuh, A., Qian, H., et al., Raman spectroscopy of graphene edges, Nano Lett., 2009, vol. 9, no. 4, pp. 1434–1441.
Novikov, N.V., Fedoseev, D.V., Shulzhenko, A.A., and Bogatyreva, G.P., Sintez almazov (Synthesis of diamond), Novikov, N.V., Ed., Kiev: Naukova Dumka, 1987.
Shulepov, S.V., Fizika uglegrafitovukh materialov (Physics of carbon and graphite materials), Moscow: Metallurgiya, 1968.
Saenko, N.S. and Ziatdinov, A.M., Evaluation of sizes of graphite nanoparticles from spectra of X-ray diffraction of activated carbon fibbers not using the Scherer formula, Papers Abstracts, the 8th Int. conference on Carbon: Fundamental Problems of Science, Material Science, Technology, Moscow, Troitsk, 2012, pp. 422–427.
Loladze, N.T., Polyakov, V.P., and Fedoseev, D.V., Dependence of the diamond formation on the sizes of crystallites of the initial carbon material, Colloid J., 1987, vol. 49, no. 2, pp. 352–353.
Galashev, A.E., Computer modelling of heating nickel films on two-layer graphene, Physics Solid State, 2014, vol. 56, no. 5, pp. 1009–1014.
Chepurov, A.I., Fedorov, I.I., and Sonin, V.M., Experimental modelling of processes of diamond formation, Chepurov, A.I., and Kirdyashkin, A.G., Eds., Siberian Division of RAN, Joint Institute of Geology, Geophysics, and Mineralogy, Novosibirsk, RF: SD RAN, NITs OIGGM, 1997.
Eletskii, A.V., Iskanderova, I.M., Knizhnik, A.A., and Krasikov, D.N., Graphene: methods of producing and thermophysical properties, Physics-Uspekhi, 2011, vol. 181, no. 3, pp. 233–268.
Yadgarov, I.D., Stel’makh, V.G., Rasulov, A.M., and Dzhurakhalov, A.A., Defects in graphene in the results of its scattering of carbon atoms with the energies 10 and 100 eV, J. Technical Physics, 2015, vol. 85, no. 3, pp. 156–158.
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Original Russian Text © A.A. Shul’zhenko, L. Jaworska, A.N. Sokolov, V.G. Gargin, N.N. Belyavina, 2017, published in Sverkhtverdye Materialy, 2017, Vol. 39, No. 2, pp. 3–13.
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Shul’zhenko, A.A., Jaworska, L., Sokolov, A.N. et al. Phase transformations of n-layer graphenes into diamond at high pressures and temperatures. J. Superhard Mater. 39, 75–82 (2017). https://doi.org/10.3103/S1063457617020010
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DOI: https://doi.org/10.3103/S1063457617020010