Kinetics of the Processes of Orientation and Adsorption in Polymer Adhesive Materials

Abstract

An investigation is performed of the mechanism behind the peeling of an adsorbed flexible macromolecule from a surface under the action of a strong mean field formed by intermolecular interactions with other chains. The kinetic equation for the order parameter and its solution are obtained. The effect of a critical slowdown (in a sharp increase in periods of relaxation time at the critical point) is observed for finite chains.

This is a preview of subscription content, access via your institution.

Fig. 1.
Fig. 2.
Fig. 3.

REFERENCES

  1. 1

    Sanchez, I.C. and Fitzpatrick, L.E., Physics of Polymer Surfaces and Interfaces, Boston: Butterworth–Heinemann, 1992, p. 3.

    Google Scholar 

  2. 2

    Karim, A. and Kumar, S., Polymer Surfaces, Interfaces and Thin Films, Singapore: World Sci., 2000, p. 5.

    Book  Google Scholar 

  3. 3

    Skvortsov, A.M., Klushin, L.I., Polotsky, A.A., et al., Phys. Rev. E: Stat., Nonlinear, Soft Matter Phys., 2012, vol. 85, no. 5, 031803.

    ADS  Article  Google Scholar 

  4. 4

    Landau, L.D. and Lifshits, E.M., Teoreticheskaya fizika (Theoretical Physics), vol. 5: Statisticheskaya fizika (Statistical Physics), Moscow: Nauka, 1976, part 1.

  5. 5

    Maksimov, A.V., Maksimova, O.G., and Diordiichuk, D.V., Bull. Russ. Acad. Sci.: Phys., 2013, vol. 77, no. 8, p. 1004.

    Google Scholar 

  6. 6

    Stanley, H.E., Introduction to Phase Transitions and Critical Phenomena, Oxford: Oxford Univ. Press, 1971.

    Google Scholar 

  7. 7

    Fleury, P.A., Science, 1981, vol. 211, no. 4478, p. 125.

    ADS  MathSciNet  Article  Google Scholar 

  8. 8

    Zhang, Sh., Qi, Sh., Klushin, L.I., et al., J. Chem. Phys., 2017, vol. 147, 064902.

    ADS  Article  Google Scholar 

Download references

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 19-42-350001-r_a.

Author information

Affiliations

Authors

Corresponding author

Correspondence to A. V. Maximov.

Ethics declarations

The authors declare there were no conflicts of interest.

Additional information

Translated by P. Vlasov

About this article

Verify currency and authenticity via CrossMark

Cite this article

Maximov, A.V., Maksimova, O.G. & Osipov, S.V. Kinetics of the Processes of Orientation and Adsorption in Polymer Adhesive Materials. Bull. Russ. Acad. Sci. Phys. 84, 1576–1578 (2020). https://doi.org/10.3103/S1062873820120254

Download citation