Quantum-Chemical Analysis of the Structural Phase Transition in Quasi–One-Dimensional Ferroelectrics Pb(H/D)PO4

  • S. P. Dolin
  • T. Yu. Mikhailova
  • N. N. Breslavskaya
Proceedings of the XXI National Conference on Magnetoelectrics Physics


The applicability of the simplest cluster models for semi-quantitative descriptions of the thermodynamics of structural phase transitions in quasi–one-dimensional ferroelectrics is considered. A lead hydrogen phosphate is used as an example. Even such simple models can qualitatively and, in some cases, quantitatively reproduce experimental data.


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  1. 1.
    Vaks, V.G., Vvedenie v mikroskopicheskuyu teoriyu segnetoelektrikov (Introduction to the Microscopic Theory of Ferroelectrics), Moscow: Fizmatlit, 1973.Google Scholar
  2. 2.
    Blinc, R. and Žekš, B., Soft Modes in Ferroelectrics and Antiferroelectrics, Amsterdam: North-Holland, 1974.Google Scholar
  3. 3.
    Strukov, B.A. and Levanyuk, A.P., Fizicheskie osnovy segnetoelektricheskikh yavlenii v kristallakh (Physical Foundations of Ferroelectric Phenomena in Crystals), Moscow: Nauka, 1983.Google Scholar
  4. 4.
    Levin, A.A. and Dolin, S.P., J. Mol. Struct., 2000, vol. 552, p.39.ADSCrossRefGoogle Scholar
  5. 5.
    Dolin, S.P., Mikhailova, T.Yu., and Levin, A.A., Int. J. Quantum Chem., 2007, vol. 107, p. 10165.CrossRefGoogle Scholar
  6. 6.
    Dolin, S.P., Mikhailova, T.Yu., Breslavskaya, N.N., et al., Int. J. Quantum Chem., 2010, vol. 110, p.77.ADSCrossRefGoogle Scholar
  7. 7.
    Dolin, S.P., Mikhailova, T.Yu., Breslavskaya, N.N., et al., Int. J. Quantum Chem., 2016, vol. 116, no. 3, p.202.CrossRefGoogle Scholar
  8. 8.
    Mikhailova, T.Yu. and Pupyshev, V.I., Opt. Spectrosc., 1999, vol. 87, p.35.ADSGoogle Scholar
  9. 9.
    Blinc, R. and Svetina, S., Phys. Rev., 1966, vol. 147, p.430.ADSCrossRefGoogle Scholar
  10. 10.
    Vaks, V.G. and Zinenko, V.I., J. Exp. Theor. Phys., 1973, vol. 37, p.330.ADSGoogle Scholar
  11. 11.
    Negran, T.J., Glass, A.M., Brickenkamp, C.S., et al., Ferroelectrics, 1974, vol. 6, p.179.CrossRefGoogle Scholar
  12. 12.
    McMahon, M.I., Nelmes, R.J., Kuhs, W.F., et al., Nature, 1990, vol. 348, p.317.ADSCrossRefGoogle Scholar
  13. 13.
    Katrusiak, A. and Nelmes, R.J., J. Phys.: Condens. Matter, 1989, vol. 1, p. 10165.ADSGoogle Scholar

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© Allerton Press, Inc. 2018

Authors and Affiliations

  • S. P. Dolin
    • 1
  • T. Yu. Mikhailova
    • 1
  • N. N. Breslavskaya
    • 1
  1. 1.Kurnakov Institute of General and Inorganic ChemistryRussian Academy of SciencesMoscowRussia

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