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Time Variations in the FTIR Spectra of Liquids Measured in the ATR Configuration

  • OPTICS AND SPECTROSCOPY. LASER PHYSICS
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Moscow University Physics Bulletin Aims and scope

Abstract

Attenuated total reflection (ATR) is often employed in the measurements of FTIR spectra. Such a configuration is convenient for experiments with liquid samples, since pressing them to the surface of the ATR crystal is not necessary. Spectral changes that occur in the course of measurements with liquids are revealed. It is shown that significant variations in the concentrations of components may occur in the ATR-FTIR measurements of solutions. Redistribution of components of a solution in the vicinity of the ATR crystal may lead to inhomogeneity of the sample.

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Notes

  1. DNPA and ethyl benzoate may serve as substrates for α-chymotrypsin, whose reactions are of interest in enzymology.

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ACKNOWLEDGMENTS

This work was supported by the Program of Development of Moscow State University and the Russian Foundation for Basic Research (project no. 17-02-01411-a).

We are grateful to A.V. Medved’ko and I.K. Sakodynskaya for preparation of samples and helpful discussions.

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Authors and Affiliations

  1. Department of Physics and International Laser Center, Moscow State University, 119991, Moscow, Russia

    I. G. Shpachenko, N. N. Brandt & A. Yu. Chikishev

Authors
  1. I. G. Shpachenko
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  2. N. N. Brandt
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  3. A. Yu. Chikishev
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Corresponding authors

Correspondence to I. G. Shpachenko, N. N. Brandt or A. Yu. Chikishev.

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Shpachenko, I.G., Brandt, N.N. & Chikishev, A.Y. Time Variations in the FTIR Spectra of Liquids Measured in the ATR Configuration. Moscow Univ. Phys. 73, 644–650 (2018). https://doi.org/10.3103/S002713491806022X

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  • DOI: https://doi.org/10.3103/S002713491806022X

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