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Moscow University Chemistry Bulletin

, Volume 72, Issue 6, pp 275–281 | Cite as

Quantum Chemical Study of Regularities of Electrophilic Substitution in the Synthesis of Pyrroloquinolines

  • O. V. Boyarkina
  • O. B. Tomilin
  • S. A. Yamashkin
Article

Abstract

It has been shown that the cyclization of the indolylenaminoketones prepared from substituted 5-aminoindoles, which is carried out according to the mechanism of electrophilic substitution, is an orbitally controlled interaction. The formation of pyrroloquinolines with a linear or angular structure is determined by the values of the electronic populations of the frontier orbitals of the interacting atoms.

Keywords

electrophilic substitution electron Mulliken population of atoms frontier orbitals pyrroloquinolines linear or angular condensation of cycles 

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Copyright information

© Allerton Press, Inc. 2017

Authors and Affiliations

  • O. V. Boyarkina
    • 1
  • O. B. Tomilin
    • 1
  • S. A. Yamashkin
    • 2
  1. 1.Ogarev Mordovia State UniversitySaranskRussia
  2. 2.Evsev’ev Mordovian State Pedagogical InstituteSaranskRussia

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