Moscow University Chemistry Bulletin

, Volume 74, Issue 5, pp 246–256 | Cite as

Regularities of Chlorination of the Detonation NanoDiamond Surface

  • I. I. KulakovaEmail author
  • A. Yu. Pereyaslavcev
  • G. V. Lisichkin


The published and the authors’ own data on the methods of chlorination of the surface of diamond micropowders are critically assessed. The features of different methods of chlorination of detonation nanodiamond (DND) are compared; the optimum process conditions are revealed. The method of gas-phase chlorination with molecular chlorine at elevated temperatures is preferable when using DND in biomedical applications; this method also helps lower the concentration of metal impurities. The use of thionyl chloride and sulfuryl chloride results in the contamination of DND-Cl samples with sulfur. It is shown that the DND-Cl samples have satisfactory hydrolytic stability.


detonation nanodiamond surface chlorination molecular chlorine sulfuryl chloride thionyl chloride 



This work was supported by the Russian Foundation for Basic Research, project no. 16-08-01156. The scientific equipment used was acquired with funds from the Development Program of Moscow State University.


The authors declare that they have no conflict of interest.


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Copyright information

© Allerton Press, Inc. 2019

Authors and Affiliations

  • I. I. Kulakova
    • 1
    Email author
  • A. Yu. Pereyaslavcev
    • 2
  • G. V. Lisichkin
    • 1
  1. 1.Department of Chemistry, Moscow State UniversityMoscowRussia
  2. 2.Dukhov Research Institute of AutomaticsMoscowRussia

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