Advertisement

Moscow University Chemistry Bulletin

, Volume 73, Issue 6, pp 293–297 | Cite as

Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)

  • A. N. AzizovaEmail author
  • D. B. Tagiyev
  • Sh. G. Gasimov
  • Kh. I. Gasanov
Article

Abstract

When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH2CH2NH2 and 2-mercaptoethanol HSCH2CH2OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt6(SCH2CH2NH2)8]Cl4. 5H2O and [Pd6(SCH2CH2OH)8]Cl4. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms.

Keywords

2-mercaptoethanol cysteamine chelating platinum and palladium complexes mixed coordination bridge position 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Gasanov, Kh.I., Fatullaeva, S.S., Tagiev, D.B., and Mirzai, Dzh.I., Azerb. Khim. Zh., 1998, no. 3, p. 38.Google Scholar
  2. 2.
    Gasanov, Kh.I., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2000, vol. 43, no. 33, p. 133.Google Scholar
  3. 3.
    Makhmudov, K.T., Hasanov, X.I., Maharramov, A.M., Azizova, A.N., Ragimov, K.Q., Askerov, R.K., Kopylovich, M.N., Zen Ma, and Pombeiro, A.J.L., Inorg. Chem. Commun., 2013, vol. 29, p. 37.CrossRefGoogle Scholar
  4. 4.
    Bellamy, L.J., The Infra-Red Spectra of Complex Molecules, London: Wiley, 1959, 2nd ed.Google Scholar
  5. 5.
    Zheligovskaya, N.N., Kasymbekov, D.Kh., Butinchieva, T.S., and Osmanov, Kh.K., Koord. Khim., 1992, vol. 18, no. 32, p. 176.Google Scholar
  6. 6.
    Jocelyn, P.C., Biochemistry of the SH Group, New York: Academic, 1972.Google Scholar
  7. 7.
    Efimenko, I.A., Gasanov, Kh.I., Ivanova, N.A., Lokshin, B.V., Zakharov, A.A., and Kuz’mina, L.G., Russ. J. Coord. Chem., 2000, vol. 26, no. 2, p. 112.Google Scholar
  8. 8.
    Kokozei, V.N., Polyakov, V.R., Simonov, Yu.A., and Senkevich, A.V., Zh. Neorg. Khim., 1992, vol. 37, no. 8, p. 1810.Google Scholar
  9. 9.
    Shebaldova, A.D. and Safronova, D.A., Koord. Khim., 1995, vol. 21, no. 6, p. 486.Google Scholar
  10. 10.
    Chandresekharan, M., Udupa, M.R., and Aravamudan, G., J. Inorg. Nucl. Chem., 1974, vol. 36, no. 5, p. 1153.CrossRefGoogle Scholar
  11. 11.
    Bol’shakova, L.D. and Lapkin, V.V., Russ. J. Inorg. Chem., 1998, vol. 43, no. 1, p. 69.Google Scholar
  12. 12.
    Brown, D.W., Floyd, A.J., and Sainsbury, M., Organic Spectroscopy, Chichester: Wiley, 1988.Google Scholar
  13. 13.
    Kukushkin, V.Yu., Tkachuk, V.M., Krol’, I.A., Starikova, Z.A., Zhdanov, B.V., and Kiseleva, N.P., Zh. Obshch. Khim., 1991, vol. 61, no. 1, p. 51.Google Scholar
  14. 14.
    Nepol, J.R. and Dubey, S.N., J. Indian Chem. Soc., 1988, vol. 65, no. 11, p. 795.Google Scholar

Copyright information

© Allerton Press, Inc. 2018

Authors and Affiliations

  • A. N. Azizova
    • 1
    Email author
  • D. B. Tagiyev
    • 1
  • Sh. G. Gasimov
    • 2
  • Kh. I. Gasanov
    • 2
  1. 1.Nagiyev Institute of Catalysis and Inorganic ChemistryAzerbaijan National Academy of SciencesBakuAzerbaijan
  2. 2.Azerbaijanian Medical UniversityBakuAzerbaijan

Personalised recommendations