Moscow University Chemistry Bulletin

, Volume 73, Issue 6, pp 293–297 | Cite as

Sulfobridged Polynuclear Complexes of Platinum(II) and Palladium(II)

  • A. N. AzizovaEmail author
  • D. B. Tagiyev
  • Sh. G. Gasimov
  • Kh. I. Gasanov


When the platinum(II) and palladium(II) salts interact with ligands such as cystamine-(mercamine) HSCH2CH2NH2 and 2-mercaptoethanol HSCH2CH2OH under certain conditions, polynuclear complexes of the compositions are obtained: [Pt6(SCH2CH2NH2)8]Cl4. 5H2O and [Pd6(SCH2CH2OH)8]Cl4. In a comparative study of the IR and X-ray spectra of synthesized complexes and ligands, as well as the results of X-ray diffraction studies, it was established that sulfur atoms of 2-mercaptoethanol occupy a bridge position with a mixed coordination of ligands in the palladium complex. In the platinum(II) complex bidentate coordination of ligands is realized through sulfur and nitrogen atoms.


2-mercaptoethanol cysteamine chelating platinum and palladium complexes mixed coordination bridge position 


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Copyright information

© Allerton Press, Inc. 2018

Authors and Affiliations

  • A. N. Azizova
    • 1
    Email author
  • D. B. Tagiyev
    • 1
  • Sh. G. Gasimov
    • 2
  • Kh. I. Gasanov
    • 2
  1. 1.Nagiyev Institute of Catalysis and Inorganic ChemistryAzerbaijan National Academy of SciencesBakuAzerbaijan
  2. 2.Azerbaijanian Medical UniversityBakuAzerbaijan

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