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Determination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatography

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Abstract

Total petroleum hydrocarbons (TPH) are important environmental contaminants which are toxic to human and environmental receptors. Several analytical methods have been used to quantify TPH levels in contaminated soils, specifically through infrared spectrometry (IR) and gas chromatography (GC). Despite being two of the most used techniques, some issues remain that have been inadequately studied: a) applicability of both techniques to soils contaminated with two distinct types of fuel (petrol and diesel), b) influence of the soil natural organic matter content on the results achieved by various analytical methods, and c) evaluation of the performance of both techniques in analyses of soils with different levels of contamination (presumably non-contaminated and potentially contaminated). The main objectives of this work were to answer these questions and to provide more complete information about the potentials and limitations of GC and IR techniques. The results led us to the following conclusions: a) IR analysis of soils contaminated with petrol is not suitable due to volatilisation losses, b) there is a significant influence of organic matter in IR analysis, and c) both techniques demonstrated the capacity to accurately quantify TPH in soils, irrespective of their contamination levels.

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References

  • American Petroleum Institute (API) (1992). Methods for determination of petroleum hydrocarbons in soil. Washington, DC, USA: American Petroleum Institute.

  • American Petroleum Institute (API) (1994). Interlaboratory study of three methods for analyzing petroleum hydrocarbons in soils (API Publication Number 4599). Washington, DC, USA: American Petroleum Institute.

  • American Society for Testing and Materials (ASTM) (1997a). Comparison of waterborne petroleum oils by infrared spectroscopy (D3414). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997b). Oil and grease and petroleum hydrocarbons in water (D3921). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997c). Comparison of waterborne petroleum oils by fluorescence analysis (D3650). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997d). Determination of the aromatic content and polynuclear aromatic content of diesel fuels and aviation turbine fuels by supercritical fluid chromatography (D5186-96). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997e). Oil spill identification by gas chromatography and positive ion electron impact low resolution mass spectrometry (D5739-95). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997f). Comparison of waterborne petroleum oils by gas chromatography (D3328-90). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997g). Comparison of waterborne petroleum oils by high performance liquid chromatography (D5037-90). In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • American Society for Testing and Materials (ASTM) (1997h). Determination of boiling range distribution of crude petroleum by gas chromatography D5307-97. In Annual book of ASTM standards. Philadelphia, PA, USA: American Society for Testing and Materials.

    Google Scholar 

  • Annesley, T. M. (2003). Ion suppression in mass spectrometry. Clinical Chemistry, 49, 1041–1044. DOI: 10.1373/49.7.1041.

    Article  CAS  Google Scholar 

  • Burns, K. A. (1993). Analytical methods used in oil spill studies. Marine Pollution Bulletin, 26, 68–72. DOI: 10.1016/0025-326x(93)90093-y.

    Article  CAS  Google Scholar 

  • Current, R. W., & Tilotta, D. C. (1997). Determination of total petroleum hydrocarbons in soil by on-line supercritical fluid extraction-infrared spectroscopy using a fiber optic transmission cell and a simple filter spectrometer. Journal of Chromatography A, 785, 269–277. DOI: 10.1016/s0021-9673(97)00466-4.

    Article  CAS  Google Scholar 

  • Daling, P. S., Faksness, L. G., Hansen, A. B., & Stout, S. A. (2002). Improved and standardized methodology for oil spill fingerprinting. Environmental Forensics, 3, 263–278. DOI: 10.1080/713848389.

    CAS  Google Scholar 

  • Dumitran, C., Ion, O., & Florinel, D. (2009). Spectroscopy and gas chromatographic measurements of TPH in soil samples contaminated with crude oil. Revista de Chimie, 60, 1335–1337.

    CAS  Google Scholar 

  • Eide, I., & Zahlsen, K. (2005). A novel method for chemical fingerprinting of oil and petroleum products based on electrospray mass spectrometry and chemometrics. Energy & Fuels, 19, 964–967. DOI: 10.1021/ef049743m.

    Article  CAS  Google Scholar 

  • Ge, Z. F., Brown, C. W., & Alberts, J. J. (1995). Infrared fiber optic sensor for petroleum. Environmental Science & Technology, 29, 878–882. DOI: 10.1021/es00004a007.

    Article  CAS  Google Scholar 

  • Harris, D. C. (2003). Quantitative chemical analysis (6th ed.). New York, NY, USA: Freeman.

    Google Scholar 

  • Hesse, P. R. (1972). A textbook of soil chemical analysis. New York, NY, USA: Chemical Publishing Co.

    Google Scholar 

  • Krahn, M. M., & Stein, J. E. (1998). Peer reviewed: Assessing exposure of marine biota and habitats to petroleum compounds. Analytical Chemistry, 70, 186A–192A. DOI: 10.1021/ac981748r.

    Article  CAS  Google Scholar 

  • Krahn, M. M., Ylitalo, G. M., Buzitis, J., Chan, S. L., & Varanasi, U. (1993). Rapid high-performance liquid chromatographic methods that screen for aromatic compounds in environmental samples. Journal of Chromatography A, 642, 15–32. DOI: 10.1016/0021-9673(93)80073-h.

    Article  CAS  Google Scholar 

  • Lambert, P., Fingas, M., & Goldthorp, M. (2001). An evaluation of field total petroleum hydrocarbon (TPH) systems. Journal of Hazardous Materials, 83, 65–81. DOI: 10.1016/s0304-3894(00)00328-9.

    Article  CAS  Google Scholar 

  • Lynn, T. B., Lynn, A. C., & Balog, D. (2002). Analysis of SITE program TPH field trial data for SW-846 method 9074 — The PetroFLAG hydrocarbon analyzer. In Proceedings of the 10th International On-Site 2002 Conference, January 22–25, 2002. San Diego, CA, USA.

  • Mao, D., Lookman, R., Van De Weghe, H., Weltens, R., Vanermen, G., De Brucker, N., & Diels, L. (2009). Estimation of ecotoxicity of petroleum hydrocarbon mixtures in soil based on HPLC-GCXGC analysis. Chemosphere, 77, 1508–1513. DOI: 10.1016/j.chemosphere.2009.10.004.

    Article  CAS  Google Scholar 

  • Miclean, M., Levei, E., Gog, A., Ferenczi, L., Majdik, C., Puia, C., & Roman, C. (2010). Determination of total petroleum hydrocarbons in contaminated soil by FTIR and GC-FID methods. Studia Universitatis Babes-Bolyai, Chemia, 55(3), 83–91.

    CAS  Google Scholar 

  • Miller, J. C. & Miller, J. N. (2000). Statistics for analytical chemistry (3rd ed.). Harlow, UK: Pearson Education.

    Google Scholar 

  • Ministry of Housing, Physical Planning and Environment (VROM) (1987). Soil protection act. Den Haag, The Netherlands.

  • Pál, R., Juhász, M., & Stumpf, Á. (1998). Detailed analysis of hydrocarbon groups in diesel range petroleum fractions with on-line coupled supercritical fluid chromatography-gas chromatography-mass spectrometry. Journal of Chromatography A, 819, 249–257. DOI: 10.1016/s0021-9673(98)00505-6.

    Article  Google Scholar 

  • Park, I. S., & Park, J. W. (2011). Determination of a risk management primer at petroleum-contaminated sites: Developing new human health risk assessment strategy. Journal of Hazardous Materials, 185, 1374–1380. DOI:10.1016/j.jhazmat. 2010.10.058.

    Article  CAS  Google Scholar 

  • Rauckyte, T., Zak, S., Pawlak, Z., & Oloyede, A. (2010). Determination of oil and grease, total petroleum hydrocarbons and volatile aromatic compounds in soil and sediment samples. Journal of Environmental Engineering and Landscape Management, 18(3), 163–169. DOI: 10.3846/jeelm.2010.19.

    Article  Google Scholar 

  • Schreier, C. G., Walker, W. J., Burns, J., & Wilkenfeld, R. (1999). Total organic carbon as a screening method for petroleum hydrocarbons. Chemosphere, 39, 503–510. DOI: 10.1016/s0045-6535(98)00598-0.

    Article  CAS  Google Scholar 

  • Shin, H. S., & Kwon, O. S. (2000). The simultaneous analysis of benzene, toluene, ethylbenzene, o, m, p-xylenes and total petroleum hydrocarbons in soil by GC-FID after ultrasonication. Bulletin of Korean Chemical Society, 21, 1101–1105.

    CAS  Google Scholar 

  • Sink, C.W., & Hardy, D. R. (1994). Quantification of compound classes in complex mixtures and fuels using HPLC with differential refractive index detection. Analytical Chemistry, 66, 1334–1338. DOI: 10.1021/ac00080a020.

    Article  CAS  Google Scholar 

  • Tang, L., & Kerbarle, P. (1993). Dependence of ion intensity in electrospray mass spectrometry on the concentration of the analytes in the electrosprayed solution. Analytical Chemistry, 65, 3654–3668. DOI: 10.1021/ac00072a020.

    Article  CAS  Google Scholar 

  • United States Environmental Protection Agency (USEPA) (1978). Test method for evaluating total recoverable petroleum hydrocarbons (Spectrophotometric, Infrared) (Method 418.1). Washington, DC, USA: U.S. Government Printing Office.

  • United States Environmental Protection Agency (USEPA) (1996a). Turbidimetric screening method for total recoverable petroleum hydrocarbons in soil (Method 9074). Washington, DC, USA: U.S. Government Printing Office.

    Google Scholar 

  • United States Environmental Protection Agency (USEPA) (1996b). Total petroleum hydrocarbons (TPH) as gasoline and diesel (Method 8015B). Washington, DC, USA: U.S. Government Printing Office.

    Google Scholar 

  • United States Environmental Protection Agency (USEPA) (1996c). Total recoverable petroleum hydrocarbon by infrared spectrophotometry (Method 8440). Washington, DC, USA: U.S. Government Printing Office.

    Google Scholar 

  • United States Environmental Protection Agency (USEPA) (1998). n-Hexane extractable material (HEM) for sludge, sediment, and solid samples (Method 9071B). Washington, DC, USA: U.S. Government Printing Office.

  • Wang, Z. D., & Fingas, M. (1997). Developments in the analysis of petroleum hydrocarbons in oils, petroleum products and oil-spill-related environmental samples by gas chromatography. Journal of Chromatography A, 774, 51–78. DOI: 10.1016/s0021-9673(97)00270-7.

    Article  CAS  Google Scholar 

  • Wang, Z. D., & Fingas, M. F. (2003). Development of oil hydrocarbon fingerprinting and identification techniques. Marine Pollution Bulletin, 47, 423–452. DOI: 10.1016/s0025-326x(03)00215-7.

    Article  CAS  Google Scholar 

  • Wang, Z. D., Fingas, M., & Page, D. S. (1999). Oil spill identification. Journal of Chromatography A, 843, 369–411. DOI: 10.1016/s0021-9673(99)00120-x.

    Article  CAS  Google Scholar 

  • Wang, S. J., Guo, G. L., Yan, Z. G., Lu, G. L., Wang, Q. H., & Li, F. S. (2010). The development of a method for the qualitative and quantitative determination of petroleum hydrocarbon components using thin-layer chromatography with flame ionization detection. Journal of Chromatography A, 1217, 368–374. DOI: 10.1016/j.chroma.2009.11.022.

    Article  CAS  Google Scholar 

  • Wright, K. A. (1995). Evaluation of a new field test kit for determining total petroleum hydrocarbon concentrations in soil at a site contaminated by diesel fuel. In Proceedings of the AEHS Conference on Hydrocarbon Contaminated Soils, January 11–13, 1995. New Orleans, LA, USA.

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Authors and Affiliations

  1. REQUIMTE, Rua Dr. António Bernardino de Almeida, 431, 4200-072, Porto, Portugal

    Paula Paíga, José T. Albergaria & Cristina M. Delerue-Matos

  2. Instituto Superior de Engenharia do Porto, Rua Dr. António Bernardino de Almeida, 431, 4200-072, Porto, Portugal

    Lurdes Mendes

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  1. Paula Paíga
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  2. Lurdes Mendes
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  3. José T. Albergaria
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  4. Cristina M. Delerue-Matos
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Correspondence to José T. Albergaria.

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Paíga, P., Mendes, L., Albergaria, J.T. et al. Determination of total petroleum hydrocarbons in soil from different locations using infrared spectrophotometry and gas chromatography. Chem. Pap. 66, 711–721 (2012). https://doi.org/10.2478/s11696-012-0193-8

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