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Synthesis, structure, and luminescent properties of two novel polynuclear complexes of 1,3-di(pyridin-2-yl)propane-1,3-dione

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Abstract

Two complexes, {[Cd6(o-dppd)2(µ2-Cl)6(µ3-Cl)2(DMF)2(H2O)2Cl2]·DMF·CH3OH} n (I) (DMF = N,N-dimethylformamide; o-dppdH = 1,3-di(pyridin-2-yl)propane-1,3-dione) and [Cu4(o-dppd)2(OAc)4(OH)2]·4H2O (II), were synthesised and characterised by single-crystal X-ray diffraction, elemental analysis, IR, solid fluorescence and TGA. The results showed that complex I had a rodshaped polynuclear chain with hexacoordinating Cd atoms bridged by oxygen, µ2-Cl and µ3-Cl; complex II was a tetranuclear oligomer. In general, supramolecular architectures are constructed through hydrogen-bonding and π-π stacking interactions. I shows luminescence.

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Authors and Affiliations

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an, 710069, China

    Jin-Ting Tan, San-Ping Chen, Xia Li, Ying-Li Lu, Xing Feng & Xu-Wu Yang

  2. Department of Biochemical Engineering, Xianyang Vocational Technical college Xianyang, Xi’an, 712000, China

    Wen-Jie Zhao

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  1. Jin-Ting Tan
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  2. Wen-Jie Zhao
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  3. San-Ping Chen
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  4. Xia Li
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  5. Ying-Li Lu
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  6. Xing Feng
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  7. Xu-Wu Yang
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Correspondence to Xu-Wu Yang.

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Tan, JT., Zhao, WJ., Chen, SP. et al. Synthesis, structure, and luminescent properties of two novel polynuclear complexes of 1,3-di(pyridin-2-yl)propane-1,3-dione. Chem. Pap. 66, 47–53 (2012). https://doi.org/10.2478/s11696-011-0109-z

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