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Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water

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Abstract

Anilinium 5-sulfosalicylate was prepared and characterized by elemental analysis, and FTIR and NMR spectroscopies. It was polymerized in an aqueous solution using ammonium peroxydisulfate as an oxidant. The precipitated polyaniline 5-sulfosalicylate exhibited high thermal stability and conductivity of 0.13 S cm−1. Its mass-average molar mass and polydispersity index were determined by gel-permeation chromatography as 22,900 g mol−1 and 2.7, respectively. Elemental analysis and FTIR spectroscopy study of polyaniline 5-sulfosalicylate revealed the doping level and the oxidation state between emeraldine and protoemeraldine salt while corresponding studies of the polyaniline base indicate a small extent of the covalent bonding of 5-sulfosalicylate anions to polyaniline chains.

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Authors and Affiliations

  1. Centrohem, Vuka Karadžića bb, 22300, Stara Pazova, Serbia

    Budimir Marjanović

  2. Faculty of Chemistry, University of Belgrade, Studentski trg 12-16, 11158, Belgrade, Serbia

    Ivan Juranić

  3. Faculty of Physical Chemistry, University of Belgrade, Studentski trg 12-16, 11158, Belgrade, Serbia

    Slavko Mentus & Gordana Ćirić-Marjanović

  4. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovský Sq. 2, 162 06, Prague 6, Czech Republic

    Petr Holler

Authors
  1. Budimir Marjanović
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  2. Ivan Juranić
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  3. Slavko Mentus
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  4. Gordana Ćirić-Marjanović
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  5. Petr Holler
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Correspondence to Budimir Marjanović.

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Marjanović, B., Juranić, I., Mentus, S. et al. Oxidative polymerization of anilinium 5-sulfosalicylate with peroxydisulfate in water. Chem. Pap. 64, 783–790 (2010). https://doi.org/10.2478/s11696-010-0064-0

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