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Chemical Papers

, Volume 64, Issue 4, pp 409–414 | Cite as

Multi-elemental analysis of marine sediment reference material MESS-3: one-step microwave digestion and determination by high resolution inductively coupled plasma-mass spectrometry (HR-ICP-MS)

  • Vibor RojeEmail author
Original Paper

Abstract

Single-step microwave digestion methods using four different acidic dissolving reagents were investigated with the main objective to obtain a simple, rapid method for multi-elemental analysis of marine sediment samples by high resolution inductively coupled plasma-mass spectrometry (HRICP-MS), especially for environmental studies. Closed-vessels microwave digestion procedures were carried out using the reagents as follows: HNO3, mixture of HNO3-HCl (φ r = 9: 1), aqua regia, and mixture of HNO3-HCl-HF (φ r = 8: 1: 1). The elements analyzed were: Al, As, Ba, Be, Bi, Cd, Co, Cr, Cu, Fe, K, Li, Mn, Mo, Na, Ni, Pb, Sb, Sn, Sr, Ti, Tl, V, and Zn. Good recoveries were established for many of the metals analyzed even when only nitric acid was employed. However, for a good recovery of Sb and Tl, aqua regia should be employed.

Keywords

rapid elemental analysis inductively coupled plasma mass spectrometry microwave digestion marine sediment trace elements 

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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2010

Authors and Affiliations

  1. 1.Division for Marine and Environmental ResearchRuđer Bošković InstituteZagrebCroatia

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