Abstract
A study on the effect of the metal-support interaction by employing iron particles supported on magnesium oxide (MgO) nanopowder in an alcohol-CVD process for single-walled carbon nanotubes growth is presented. Upon the prolongation of the process time, three main observations were detected: (i) decrease of the mean nanotubes diameter, (ii) reduction of the diameter distribution by the factor of two, (iii) increase of relative purity of the samples.
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Ago, H., Nakamura, K., Imamura, S., & Tsuji, M. (2004a). Growth of double-wall carbon nanotubes with diameter-controlled iron oxide nanoparticles supported on MgO. Chemical Physics Letters, 391, 308–313. DOI: 10.1016/j.cplett.2004.04.110.
Ago, H., Nakamura, K., Uehara, N., & Tsuji, M. (2004b). Roles of meal-support interaction in growth of single- and double-walled carbon nanotubes studied with diameter-controlled iron particles supported on MgO. Journal of Physical Chemistry B, 108, 18908–18915. DOI: 10.1021/jp046856y.
Anderson, N., Hartschuh, A., & Novotny, L. (2007). Chirality changes in carbon nanotubes studied with near-field Raman spectroscopy. Nano Letters, 7, 577–582. DOI: 10.1021/nl0622496.
Bachmatiuk, A., Borowiak-Palen, E., Rümmeli, M. H., Kramberger, C., Hübers, H-W., Gemming, T., Pichler, T., & Kalenczuk, R. J. (2007). Facilitating the CVD synthesis of seamless double-walled carbon nanotube. Nanotechnology, 18, 275610. DOI: 10.1088/0957-4484/18/27/275610.
Dai, H. (2002). Carbon nanotubes: opportunities and challenges. Surface Science, 500, 218–241. DOI: 10.1016/S0039-6028(01)01558-8
de los Arcos, T., Garnier, M. G., Seo, J. W., Oelhafen, P., Thommen, V., & Mathys, D. (2004). The influence of catalyst chemical state and morphology on carbon nanotube growth. Journal of Physical Chemistry B, 108, 7728–7734. DOI: 10.1021/jp049495v.
Endo, M., Takeuchi, K., Kobori, K., Takahashi, K., Kroto, H. W., & Sarkar, A. (1995). Pyrolytic carbon nanotubes from vapor-grown carbon fibers. Carbon, 33, 873–881. DOI: 10.1016/0008-6223(95)0016-7
Frank, S., Poncharal, P., Wang, Z. L., & De Heer, W. A. (1998). Carbon nanotube quantum resistors. Science, 280, 1744–1746. DOI: 10.1126/science.280.5370.1744.
Iijima, S. (1991). Helical microtubes of graphitic carbon. Nature, 354, 56–58. DOI: 10.1038/354056a0.
Joseyacaman, M., Mikiyoshida, M., Rendon, L., & Santiesteban, J. G. (1993). Catalytic growth of carbon microtubules with fullerene structure. Applied Physics Letters, 62, 657–659. DOI: 10.1063/1.108857.
Kim, P, & Lieber, C. M. (1999). Nanotube nanotweezers. Science, 286, 2148–2150. DOI: 10.1126/science.286.5447.2148.
Kong, J., Zhou, C., Morpurgo, A., Soh, H. T., Quate, C. F., Marcus, C., & Dai, H. (1999). Synthesis, integration, and electrical properties of individual single-walled carbon nanotubes. Applied Physics A: Materials Science & Processing, 69, 305–308. DOI: 10.1007/s003390051005.
Lamouroux, E., Serp, P., & Kalck, P. (2007). Catalytic routes towards single wall carbon nanotubes. Catalysis Reviews, 49, 341–405. DOI: 10.1080/01614940701313200.
Liu, C., Fan, Y. Y., Liu, M., Cong, H. T., Cheng, H. M., & Dresselhaus, M. S. (1999). Hydrogen storage in single-walled carbon nanotubes at room temperature. Science, 286, 1127–1129. DOI: 10.1126/science.286.5442.1127.
Lolli, G., Zhang, L., Balzano, L., Sakulchaicharoen, N., Tan, Y. Q., & Resasco, D. E. (2006). Tailoring (n, m) structure of single-walled carbon nanotubes by modifying reaction conditions and the nature of the support of CoMo catalysts. Journal of Physical Chemistry B, 110, 2108–2115. DOI: 10.1021/jp056095e.
Piscanec, S., Lazzeri, M., Robertson, J., Ferrari, A. C., & Mauri, F. (2007). Optical phonons in carbon nanotubes: Kohn anomalies, Peierls distortions, and dynamic effects. Physical Review B, 75, 035427. DOI: 10.1103/PhysRevB.75.035427.
Ren, Z. F., Huang, Z. P., Xu, J. W., Wang, J. H., Bush, P., Siegal, M. P., & Provencio, P. N. (1998). Synthesis of large arrays of well-aligned carbon nanotubes on glass. Science, 282, 1105–1107. DOI: 10.1126/science.282.5391.1105.
Schäffel, F., Kramberger, C., Rümmeli, M. H., Grimm, D., Mohn, E., Gemming, T., Pichler, T., Rellinghaus, B., Büchner, B., & Schultz, L. (2007). Nanoengineered catalyst particles as a key for tailor-made carbon nanotubes. Chemistry of Matererials, 19, 5006–5009. DOI: 10.1021/cm070950k.
Thess, A., Lee, R., Nikolaev, P., Dai, H. J., Petit, P., Robert, J., Xu, C., Lee, Y. H., Kim, S. G., Rinzler, A. G., Colbert, D. T., Scuseria, G. E., Tománek, D., Fischer, J. E., & Smalley, R. E. (1996). Crystalline ropes of metallic carbon nanotubes. Science, 273, 483–487. DOI: 10.1126/science.273.5274.483.
Wang, B., Yang, Y., Li, L., & Chen, Y. (2009). Effect of different catalyst supports on the (n,m) selective growth of singlewalled carbon nanotube from Co-Mo catalyst. Journal of Materials Science, 44, 3285–3295. DOI: 10.1007/s10853-009-3444-5.
Wu, H. Q., Wei, X. W., Shao, M. W., Gu, J. S., & Qu, M. Z. (2002). Preparation of Fe-Ni alloy nanoparticles inside carbon nanotubes via wet chemistry. Journal of Materials Chemistry, 12, 1919–1921. DOI: 10.1039/b200470d.
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Steplewska, A., Borowiak-Palen, E. & Kalenczuk, R.J. Effect of time on the metal-support (Fe-MgO) interaction in CVD synthesis of single-walled carbon nanotubes. Chem. Pap. 64, 255–260 (2010). https://doi.org/10.2478/s11696-009-0111-x
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DOI: https://doi.org/10.2478/s11696-009-0111-x