Abstract
The surface of Porapak Q was characterized by inverse gas chromatography (IGC) carried out by the determination of dispersive and specific adsorption components of Porapak Q surface, calculating γ ds and -ΔH sa parameters, respectively. An interpretation was given based on the chemical structure of Porapak Q. The obtained results were confirmed through the surface Lewis acidity and basicity constants, K a and K b, respectively, correlating well with the determined thermodynamic parameters.
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Andrzejewska, E., Voelkel, A., Andrzejewski, M., & Maga, R. (1996). Examination of surfaces of solid polymers by inverse gas chromatography: 2. Acid-base properties. Polymer, 37, 4333–4344. DOI: 10.1016/0032-3861(96)00280-7.
Azanova, V. V., & Hradil, J. (1999). Sorption properties of macroporous and hypercrosslinked copolymers. Reactive and Functional Polymers, 41, 163–175. DOI: 10.1016/S1381-5148(99)00029-2.
Bielicka-Daszkiewicz, K., Voelkel, A., Szejner, M., & Osypiuk, J. (2006). Extraction properties of new polymeric sorbents in SPE/GC analysis of phenol and hydroquinone from water samples. Chemosphere, 62, 890–898. DOI: 10.1016/j.chemosphere.2005.05.032.
Davankov, V. A. (2003). Critical reconsideration of the physical meaning and the use of fundamental retention parameters in gas chromatography. New IUPAC recommendations. Chromatographia, Supplement, 57, 195–198.
García Domínguez, J. A., & Díez-Masa, J. C. (2001). Part B. Retention parameters in gas chromatography, Pure and Applied Chemistry, 73, 969–992. DOI: 10.1351/pac200173060969.
Hradil, J., & Králová, E. (1998). Styrene-divinylbenzene copolymers post-crosslinked with tetrachloromethane. Polymer, 39, 6041–6048. DOI: 10.1016/S0032-3861(98)00057-3.
Huck, C. W., & Bonn, G. K. (2000). Recent developments in polymer-based sorbents for solid-phase extraction. Journal of Chromatography A, 885, 51–72. DOI: 10.1016/S0021-9673(00)00333-2.
Jung, M.-W., Ahn, K.-H., Lee, Y., Kim, K.-P., Paeng, I. R., Rhee, J.-S., Park, J. T., & Paeng, K.-J. (2001). Evaluation on the adsorption capabilities of new chemically modified polymeric adsorbents with protoporphyrin IX. Journal of Chromatography A, 917, 87–93. DOI: 10.1016/S0021-9673(01)00673-2.
Kamdem, D. P., Bose, S. K., & Luner, P. (1993). Inverse gas chromatography characterization of birch wood meal. Langmuir, 9, 3039–3044. DOI: 10.1021/la00035a049.
Kim, D.-G., Jung, M.-W., Paeng, I. R., Rhee, J.-S., & Paeng, K.-J. (1999). Solid-phase extraction of phenol and chlorophenolin water with a chemically modified polymer-supported tetrakis(p-carboxyphenol)porphyrin(H2TCPP). Microchemical Journal, 63, 134–139. DOI: 10.1006/mchj.1999.1775.
León-González, M. E., & Pérez-Arribas, L. V. (2000). Chemically modified polymeric sorbents for sample preconcentration. Journal of Chromatography A, 902, 3–16. DOI: 10.1016/S0021-9673(00)00942-0.
Masque, N., Galia, M., Marce, R. M., & Borrull, F. (1997). Chemically modified polymeric resin used as sorbent in a solid-phase extraction process to determine phenolic compounds in water. Journal of Chromatography A, 771, 55–61. DOI: 10.1016/S0021-9673(97)00125-8.
Muir, B., Duffy, H. B., & Moran, M. C. (2004). Optimisation of solvent desorption conditions for chemical warfare agent and simulant compounds from Porapak Q™ using experimental design I. Methyl salicylate and di(propylene glycol) monomethyl ether. Journal of Chromatography A, 1038, 183–187. DOI: 10.1016/j.chroma.2004.03.014.
Oliveira, A. L., Lopes, R. B., Cabral, F. A., & Eberlin, M. N. (2006). Volatile compounds from pitanga fruit (Eugenia uniflora L.). Food Chemistry, 99, 1–5. DOI: 10.1016/j.foodchem.2005.07.012.
Poole, C. F. (2003). New trends in solid-phase extraction. Trends in Analytical Chemistry, 22, 362–373. DOI: 10.1016/S0165-9936(03)00605-8.
Price, G. J., & Ansari, D. M. (2003). An inverse gas chromatography study of calcinations and surface modification of kaolinite clays. Physical Chemistry Chemical Physics, 5, 5552–5557. DOI: 10.1039/b309641f.
Ponec, V., Knor, Z., & Cerny, S. (1974). Adsorption on solids. Butterworths, London.
Rao, T., Praveen, R., & Daniel, S. (2004). Styrene-divinylbenzene copolymers: Synthesis, characterization, and their role in inorganic trace analysis. Critical Reviews in Analytical Chemistry, 34, 177–193. DOI: 10.1080/10408340490888689.
Riddle, J. F. L., & Fowkes, F. M. (1990) Spectral shifts in acid-base chemistry. 1. van der Waals contributions to acceptor numbers, Journal of American Chemical Society, 112, 3259–3264. DOI: 10.1021/ja00165a001.
Santos, J. M. R. C. A, Fagelman, K., & Guthrie, J. T. (2002). Characterisation of the surface Lewis acid-base properties of poly(butylene terephthalate) by inverse gas chromatography. Journal of Chromatography A, 969, 111–118. DOI: 10.1016/S0021-9673(02)00890-7.
Schmidt, L. W. (1993). Chemically modified polymeric resins for solid-phase extraction and group separation prior to analysis by liquid or gas chromatography. Doctoral dissertation. Iowa State University, Ames, Iowa.
Schultz, J., & Lavielle, L. (1989). Interfacial properties of carbon fiber-epoxy matrix composites. In D. R. Lloyd, T. C. Ward, and H. P. Schreiber (Eds.), Inverse gas chromatography, characterization of polymers and other materials (pp. 185–202). Washington: American Chemical Society.
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Moustafa, N.E., El-Desouki, D.S. Inverse gas chromatographic characterization of Porapak Q as an extractant of pollutants from aqueous media. Chem. Pap. 63, 371–376 (2009). https://doi.org/10.2478/s11696-009-0014-x
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DOI: https://doi.org/10.2478/s11696-009-0014-x