Abstract
New macrocyclic polyethers, 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10-trioxacyclododeca-2,5-diene (I), 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13-tetra oxacyclo pentadeca-2,5-diene (II), and 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13,16-penta oxa cyclo octadeca-2,5-dien (III), and macrocylic lactones 2,3,5,6-bis-[5′(5′)-chlorobenzo]-1,7,10,13-tetraoxacyclopentadeca-2,5-diene-8,15-dione (IV) and 2,3,5,6-bis[5′(5′)-chlorobenzo]-1,7,10,13,16-pentaoxacyclooctadeca-2,5-diene-8,18-dione (V) were synthesized. Complexes of ligands III and V with metal cations were prepared. Furthermore, their metal-picrate extraction with some metal salts was attempted. Structures of the ligands and complexes were confirmed using spectroscopic techniques.
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Ertul, Ş., Bedük, A.D., Bayrakci, M. et al. Synthesis of macrocyclic polyethers and polyether diesters and preparation of their cationic complexes. Chem. Pap. 62, 589–595 (2008). https://doi.org/10.2478/s11696-008-0065-4
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DOI: https://doi.org/10.2478/s11696-008-0065-4