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In situ and ex situ characterization of a Fe-Cr-Ni alloy in mouthwashes and Hank’s solution

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Abstract

The aim of the present study was to classify the surface oxide layers formed on a Fe-Cr-Ni alloy according to their corrosion resistance in Hank’s solution and mouthwashes by SEM and electrochemical techniques. The SEM micrographs showed the presence of localized corrosion and the polarization curves showed that the passive layer is less stable in the presence of Hank’s solution than of mouthwashes, as a result of the presence of chloride ions.

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References

  • Assis, S. L., Wolynec, S., & Costa, I. (2006). Corrosion characterization of titanium alloys by electrochemical techniques. Electrochimica Acta, 51, 1815–1819. DOI: 10.1016/j.electacta.2005.02.121.

    Article  Google Scholar 

  • Böhni, H. (1987). In F. Mansfeld (Ed.). Corrosion mechanisms (p. 285). New York: Dekker.

    Google Scholar 

  • Böhni, H. (1987). Breakdown of passivity and localized corrosion processes. Langmuir, 3, 924–930. DOI: 10.1021/la00078a010.

    Article  Google Scholar 

  • Frankel, G. S. (1998). Pitting corrosion of metals: A review of critical factors. Journal of Electrochemical Society, 145, 2186–2198. DOI: 10.1149/1.1838615.

    Article  CAS  Google Scholar 

  • Huang, H. H., Chiu, H. Y., Lee, T. H., Wu, S. C., Yang, H. W., Su, K. H., & Hsu, C. C. (2003). Ion release from NiTi orthodontic wires in artificial saliva with various acidities. Biomaterials, 24, 3585–3592. DOI: 10.1016/S0142-9612(03)00188-1.

    Article  CAS  Google Scholar 

  • Jones, D. A. (1996). Principles and prevention of corrosion (2nd ed.). Upper Saddle River, NJ: Prentice Hall.

    Google Scholar 

  • Kaneko, K., Yokoyama, K., Moriyama, K., Asaoka, K., Sakai, J., & Nagumo, M. (2003). Delayed fracture of beta titanium orthodontic wire in fluoride aqueous solutions. Biomaterials, 24, 2113–2120. DOI: 10.1016/S0142-9612(02)00642-7.

    Article  CAS  Google Scholar 

  • López, M. F., Gutiérrez, A., & Jiménez, J. A. (2001). Surface characterization of new non-toxic titanium alloys for use as biomaterials. Surface Science, 300, 482–485. DOI: S0039-6028(00)01005-0.

    Google Scholar 

  • López, M. F., Gutiérrez, A., García-Alonso, M. C., & Escudero, M. L. (1997). Synchrotron radiation photoemission study of the passive layers of heat treated Fe3Al-type alloy. Solid State Comunication, 101, 575–580. DOI: SOO38-1098(96)00663-1.

    Article  Google Scholar 

  • Marinho, V. C., Higgins, J. P., Logan, S., & Sheiham, A. (2003). Fluoride mouthrinses for preventing dental caries in children and adolescents. Cochrane Database of Systematic Reviews, 3, Pages CD002284. DOI: 10.1002/14651858.CD002284.

  • Metikos-Hurkovic, M., Pilic, Z., Babic, R., & Omanovic, D. (2006). Influence of alloying elements on the corrosion stability of CoCrMo implant alloy in Hank’s solution. Acta Biomaterialia, 2, 693–700. DOI: 10.1016/j.actbio.2006.06.002.

    Article  Google Scholar 

  • Rondelli, G., & Vicentine, B. (1999). Localized corrosion behaviour in simulated human body fluids of commercial Ni-Ti orthodontic wires. Biomaterials, 20, 785–792. DOI: S0142-9612(98)00233-6.

    Article  CAS  Google Scholar 

  • Rondelli, G. (1996). Corrosion resistance tests on NiTi shape memory alloy. Biomaterials, 17, 2003–2008. DOI: 0142-9612(95)00352-5.

    Article  CAS  Google Scholar 

  • Schiff, N., Grosgogeat, B., Lissac, M., & Dalard, F. (2004). Influence of fluoridated mouthwashes on corrosion resistance of orthodontics wires. Biomaterials, 25, 4535–4542. DOI: 10.1016/j.biomaterials.2003.11.042.

    Article  CAS  Google Scholar 

  • Schmuki, P. (2002). From Bacon to barriers: a review on the passivity of metals and alloys. Journal of Solid State Electrochemistry, 3, 145–164. DOI: 10.1007/s100080100219.

    Article  Google Scholar 

  • Talbot, D., & Talbot, J. (1998). Corrosion science and technology. Boston: CRC Press.

    Google Scholar 

  • Watanabe, I., & Watanabe, E. (2003). Surface changes induced by fluoride prophylactic agents on titanium-based orthodontic wires. American Journal of Orthodontics and Dentofacial Orthopedics, 123, 653–656. DOI: 10.1016/S0889-5406(03)00197-5.

    Article  Google Scholar 

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Correspondence to Dane T. Cestarolli.

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Cestarolli, D.T., Alves, V.A. & da Silva, L.A. In situ and ex situ characterization of a Fe-Cr-Ni alloy in mouthwashes and Hank’s solution. Chem. Pap. 62, 326–328 (2008). https://doi.org/10.2478/s11696-008-0031-1

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  • DOI: https://doi.org/10.2478/s11696-008-0031-1

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