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Excess molar volumes of the (cyclohexane + pentane, or hexane, or heptane, or octane, or nonane) systems at the temperature 298.15 K

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Abstract

The densities of the (cyclohexane + pentane, or hexane, or heptane, or octane, or nonane) systems were measured at the temperature 298.15 K by means of a vibrating-tube densimeter. Their respective excess molar volumes were calculated and correlated using the fourth-order Redlich—Kister equation, with the maximum likelihood principle being applied in the determination of the adjustable parameters. The values of excess molar volumes were negative for the cyclohexane + pentane system, whereas they were positive for the other systems with the values increasing with the number of carbon atoms in the respective alkane molecules.

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Authors and Affiliations

  1. E. Hála Laboratory of Thermodynamics, Institute of Chemical Process Fundamentals, Academy of Sciences of the Czech Republic, 165 02, Prague, Czech Republic

    J. Balán, L. Morávková & J. Linek

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  1. J. Balán
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  2. L. Morávková
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  3. J. Linek
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Correspondence to J. Linek.

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Balán, J., Morávková, L. & Linek, J. Excess molar volumes of the (cyclohexane + pentane, or hexane, or heptane, or octane, or nonane) systems at the temperature 298.15 K. Chem. Pap. 61, 497–501 (2007). https://doi.org/10.2478/s11696-007-0068-6

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  • DOI: https://doi.org/10.2478/s11696-007-0068-6

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