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Dielectric relaxation of butyl acrylate—alcohol mixtures using time domain reflectometry

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Abstract

Dielectric relaxation measurements of butyl acrylate—alcohol mixtures at different concentrations and temperatures within the frequency range of 10 MHz to 10 GHz have been carried out using time domain reflectometry. Parameters such as the static permittivity, dielectric relaxation time, the Kirkwood correlation factor, the excess inverse relaxation time, and thermodynamic functions were determined and discussed to yield information on the molecular structure and dynamics of the mixture. The value of the dielectric properties decreases with increasing butyl acrylate concentration in alcohol and systematically varies with the length of alcohol alkyl chain. Negative values of the excess inverse relaxation time found for all concentrations and at all temperatures studied may indicate that the effective dipoles rotate slowly.

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References

  1. Ediger, M. D., Angell, C. A., and Nagel, S. R., J. Chem. Phys. 100, 13200 (1996).

    Google Scholar 

  2. De Francesco, L., Cutroni, M., and Mandanici, A., Philos. Mag. B 82, 625 (2002).

    Article  ADS  Google Scholar 

  3. Sengwa, R. J., Chaudhary, R., and Mehrotra, S. C., Mol. Phys. 99, 1805 (2001).

    Article  CAS  Google Scholar 

  4. Iglesias, T. P., Fornies-Marquina, J. M., and De Cominges, B., Mol. Phys. 103, 2639 (2005).

    Article  CAS  Google Scholar 

  5. Schildknecht, C. E., Vinyl and Related Polymers. Wiley, New York, 1977.

    Google Scholar 

  6. Savage, P. E., Chem. Rev. 99, 603 (1999).

    Article  PubMed  CAS  Google Scholar 

  7. Shirke, R. M., Chaudhari, A., More, N. M., and Patil, P. B., J. Chem. Eng. Data 45, 917 (2000).

    Article  CAS  Google Scholar 

  8. Shirke, R. M., Chaudhari, A., More, N. M., and Patil, P. B., J. Mol. Liq. 94, 27 (2001).

    Article  CAS  Google Scholar 

  9. Patil, S. P., Chaudhari, A. S., Lokhande, M. P., Lande, M. K., Shankarwar, A. G., Helambe, S. N., Arbad, B. R., and Mehrotra, S. C., J. Chem. Eng. Data 44, 875 (1999).

    Article  CAS  Google Scholar 

  10. Khirade, P. W., Chaudhari, A., Shinde, J. B., Helambe, S. N., and Mehrotra, S. C., J. Chem. Eng. Data 44, 879 (1999).

    Article  CAS  Google Scholar 

  11. Khirade, P. W., Chaudhari, A., Shinde, J. B., Helambe, S. N., and Mehrotra, S. C., J. Solution Chem. 28, 1031 (1999).

    Article  CAS  Google Scholar 

  12. Chaudhari, A. and Mehrotra, S. C., Mol. Phys. 100, 3907 (2002).

    Article  CAS  Google Scholar 

  13. Sivagurunathan, P., Dharmalingam, K., and Ramachandran, K., Z. Phys. Chem. 219, 1635 (2005).

    CAS  Google Scholar 

  14. Sivagurunathan, P., Dharmalingam, K., and Ramachandran, K., Spectrochim. Acta, Part A 64, 127 (2006).

    Article  CAS  Google Scholar 

  15. Sivagurunathan, P., Dharmalingam, K., and Ramachandran, K., Indian J. Pure Appl. Phys. 43, 905 (2005).

    CAS  Google Scholar 

  16. Dharmalingam, K., Ramachandran, K., and Sivagurunathan, P., Main Group Chem. 4, 241 (2005).

    Article  CAS  Google Scholar 

  17. Dharmalingam, K. and Ramachandran, K., Phys. Chem. Liq. 44, 77 (2006).

    Article  CAS  Google Scholar 

  18. Sivagurunathan, P., Dharmalingam, K., and Ramachandran, K., Indian J. Phys. 79, 1403 (2005).

    CAS  Google Scholar 

  19. Dharmalingam, K., Ramachandran, K., and Sivagurunathan, P., Spectrochim. Acta, Part A 66, 48 (2007).

    Article  CAS  Google Scholar 

  20. Sivagurunathan, P., Dharmalingam, K., and Ramachandran, K., Z. Phys. Chem. 219, 1385 (2005).

    CAS  Google Scholar 

  21. Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., and Kalamse, G. M., Main Group Chem. 4, 227 (2005).

    Article  CAS  Google Scholar 

  22. Vogel, A. I., Text Book of Practical Organic Chemistry, 3rd Edition. Longman, London, 1957.

    Google Scholar 

  23. Samulon, H. A., Proc. IRE 39, 175 (1951).

    MathSciNet  Google Scholar 

  24. Shannon, C. E., Proc. IRE 37, 10 (1949).

    MathSciNet  Google Scholar 

  25. Cole, R. H., Berbarian, J. G., Mashimo, S., Chryssikos, G., Burns, A., and Tombari, E., J. Appl. Phys. 66, 793 (1989).

    Article  ADS  Google Scholar 

  26. Cole, K. S. and Cole, R. H., J. Chem. Phys. 9, 341 (1941).

    Article  CAS  Google Scholar 

  27. Davidson, D. W. and Cole, R. H., J. Chem. Phys. 18, 1417 (1950).

    Article  CAS  Google Scholar 

  28. Havriliak, S. and Negami, S., J. Polym. Sci., Part C Polym. Symp. 1966, 99.

  29. Bevington, P. R., Data Reduction and Error Analysis for the Physical Sciences. Mc Graw-Hill, New York, 1969.

    Google Scholar 

  30. Abd-El-Messieh, S. L., Mohamed, M. G., Mazrouaa, A. M., and Soliman, A., J. Appl. Polym. Sci. 85, 271 (2002).

    Article  CAS  Google Scholar 

  31. Singh, P. J. and Sharma, K. S., Indian J. Pure Appl. Phys. 31, 721 (1993).

    CAS  Google Scholar 

  32. Prakash, J. and Rai, B., Indian J. Pure Appl. Phys. 24, 187 (1986).

    CAS  Google Scholar 

  33. Kirkwood, J. G., J. Chem. Phys. 7, 911 (1939).

    Article  CAS  Google Scholar 

  34. Puranik, S. M., Kumbharkhane, A. C., and Mehrotra, S. C., J. Mol. Liq. 50, 143 (1991).

    Article  Google Scholar 

  35. Kauzmann, W., Rev. Mod. Phys. 14, 12 (1942).

    Article  ADS  CAS  Google Scholar 

  36. Singh, A., Misra, R., Shukla, J. P., and Saxena, M. C., J. Mol. Liq. 26, 29 (1983).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Annamalai University, Annamalai Nagar, 608 002, Tamilnadu, India

    K. Dharmalingam, K. Ramachandran & P. Sivagurunathan

  2. Department of Physics, Dr. B. A. M. University, Aurangabad, 431 004, Maharashtra, India

    B. Prabhakar Undre & P. W. Khirade

  3. Department of Electronics and Computer Science, Dr. B. A. M. University, Aurangabad, 431 004, Maharashtra, India

    S. C. Mehrotra

Authors
  1. K. Dharmalingam
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  2. K. Ramachandran
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  3. P. Sivagurunathan
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  4. B. Prabhakar Undre
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  5. P. W. Khirade
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  6. S. C. Mehrotra
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Dharmalingam, K., Ramachandran, K., Sivagurunathan, P. et al. Dielectric relaxation of butyl acrylate—alcohol mixtures using time domain reflectometry. Chem. Pap. 61, 300–307 (2007). https://doi.org/10.2478/s11696-007-0037-0

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  • DOI: https://doi.org/10.2478/s11696-007-0037-0

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