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Homo- and heteronuclear complexes of a new, vicinal dioxime ligand

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Abstract

A new symmetrical vicinal dioxime, N,N′-bis-{4-[[(2-hydroxyphenyl)methylene]hydrazinecarbonyl]phenyl}diaminoglyoxime (LH4), was prepared by reacting anti-dichloroglyoxime with salicylaldehyde 4-aminobenzoylhydrazone. The reaction of ligand with Ni2+ salts gave mono-and homopentanuclear complexes, [Ni(LH3)2] and [Ni5(LH)2X2]. Furthermore, heteropentanuclear complexes of dioxime ligand, [Cu4Ni(LH)2X4], were prepared by the reaction of [Ni(LH3)2)] with Cu2+ salt and a monodentate ligand (X = SCN−, CN−, or N −3 ). The structures of both the new symmetrical vicinal dioxime and its complexes were identified by elemental analyses, IR, 1H NMR, UV-VIS spectra, and magnetic susceptibility. The elemental analyses and spectral data indicate that the hydrazone side of ligand acts as a O,N,O′ tridentate and the fourth position is occupied with monodentate anion such as SCN−, CN−, N −3 .

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References

  1. Kahn, O., Angew. Chem., Int. Ed. Engl. 24, 834 (1985).

    Article  Google Scholar 

  2. Simmons, M. G., Merril, C. L., Wilson, L. J., Bottomly, L. A., and Kadish, K. M., J. Chem. Soc., Dalton Trans. 10, 1827 (1980).

    Article  Google Scholar 

  3. Smith, A. G., Tasker, P. A., and White, D. J., Coord. Chem. Rev. 241, 61 (2003).

    Article  CAS  Google Scholar 

  4. Cheng, M. Y., De, B., Almstead, N. G., Pikul, S., Dowty, M. E., Dietsch, C. R., Dunaway, C. M., Gu, F., Hsieh, L. C., Janusz, M. J., Taiwo, Y. O., Natchus, M. G., Hudlicky, T., and Mandel, M., J. Med. Chem. 42, 5426 (1999).

    Article  PubMed  CAS  Google Scholar 

  5. Kitajima, N. and Moro-oka, Y., Chem. Rev. 94, 737 (1994).

    Article  CAS  Google Scholar 

  6. Garnovskii, A. D. and Kharisov, B. I., Synthetic Coordination and Organometallic Chemistry. Marcel Dekker, New York, 2003.

    Google Scholar 

  7. Chaudhuri, P., Coord. Chem. Rev. 243, 143 (2003).

    Article  CAS  Google Scholar 

  8. Fenton, D. E., Biocoordination Chemistry. Oxford University Press, Oxford (1997).

    Google Scholar 

  9. Kuse, S., Motomizu, S., and Tôei, K., Anal. Chim. Acta 70, 65 (1974).

    Article  CAS  Google Scholar 

  10. Nemeth, S. and Simondi, L., J. Mol. Catal. A 14, 87 (1982).

    Article  CAS  Google Scholar 

  11. Gelmini, L. and Stephan, D. W., Inorg. Chem. 25, 1222 (1986).

    Article  CAS  Google Scholar 

  12. Gup, R., Russ. J. Coord. Chem. 32, 99 (2006).

    Article  CAS  Google Scholar 

  13. Brintzinger, H. and Titzmann, R., Chem. Ber. 85, 344 (1952).

    Article  CAS  Google Scholar 

  14. Komurcu, S. G., Rollas, S., Ulgen, M., Gorrod, J. W., and Cevikbas, A., Boll. Chim. Farm. 134, 375 (1995).

    PubMed  CAS  Google Scholar 

  15. Gup, R. and Beduk, A. D., Synth. React. Inorg. Met.-Org. Chem. 32, 1043 (2002).

    Article  CAS  Google Scholar 

  16. Canpolat, E., Kaya, M., and Yazici, A., Russ. J. Coord. Chem. 30, 87 (2004).

    Article  CAS  Google Scholar 

  17. Gup, R. and Kirkan, B., Spectrochim. Acta A 62, 1188 (2005).

    Article  Google Scholar 

  18. Saha, M. K., Sen, S., Gupta, T., Mitra, S., Kundu, P., and Karmakar, A. K., Trans. Met. Chem. 23, 635 (1998).

    Article  CAS  Google Scholar 

  19. Voloshin, Y. Z., Varzatskii, O. A., Strizhakova, N. G., and Tkachenko, E. Yu., Inorg. Chim. Acta 299, 104 (2000).

    Article  CAS  Google Scholar 

  20. Bilgin, A., Serbest, K., and Gök, Y., Trans. Met. Chem. 25, 63 (2000).

    Article  CAS  Google Scholar 

  21. Gök, Y. and Kantekin, H., Polyhedron 16, 2413 (1997).

    Article  Google Scholar 

  22. Gup, R., Kirkan, B., and Giziroglu, E., Chin. J. Chem. 24, 199 (2006).

    Article  CAS  Google Scholar 

  23. Gup, R. and Kirkan, B., Spectrochim. Acta, Part A 64, 809 (2006).

    Article  Google Scholar 

  24. Sreeja, P. B., Prathapachandra Kurup, M. R., Kishare, A., and Jasmin, C., Polyhedron 23, 575 (2004).

    Article  CAS  Google Scholar 

  25. Ainscough, E. W., Brodie, A. M., Denny, W. A., Finlay, G. J., Gothe, S. A., and Ranford, J. D., J. Inorg. Biochem. 77, 125 (1999).

    Article  PubMed  CAS  Google Scholar 

  26. Koh, L. L., Kon, O. L., Loh, K. W., Long, Y. C., Ranford, J. D., Tan, A. L. C., and Tjan, Y. Y., J. Inorg. Biochem. 72, 155 (1998).

    Article  PubMed  CAS  Google Scholar 

  27. Sreekanth, A. and Prathapachandra Kurup, M. R., Polyhedron 22, 3321 (2003).

    Article  CAS  Google Scholar 

  28. Gupta, R., Lal, T. K., and Mukherjee, R., Polyhedron 21, 1245 (2002).

    Article  CAS  Google Scholar 

  29. Kandaz, M., Yilmaz, I., Keskin, S., and Koca, A., Polyhedron 21, 825 (2002).

    Article  CAS  Google Scholar 

  30. Karaböcek, N. and Karaböcek, S., Trans. Met. Chem. 24, 84 (1999).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Mugla University, 48000, Kotekli-Mugla, Turkey

    M. Serin, G. Karayel & R. Gup

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  1. M. Serin
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  2. G. Karayel
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  3. R. Gup
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Correspondence to R. Gup.

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Serin, M., Karayel, G. & Gup, R. Homo- and heteronuclear complexes of a new, vicinal dioxime ligand. Chem. Pap. 61, 286–291 (2007). https://doi.org/10.2478/s11696-007-0035-2

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  • DOI: https://doi.org/10.2478/s11696-007-0035-2

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