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Oxygen evolution on Ti/Co3O4-coated electrodes in alkaline solution

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Abstract

The electrochemical performances of Co3O4 nanopowders, obtained by the sol-gel method, were investigated and compared with those of commercial Co3O4 powders, for oxygen evolution reaction in alkaline solution. The active oxide powder was mixed with teflon and assembled on Ti substrate to form thin catalyst film. Cyclic voltammetry, polarization curves, and electrochemical impedance spectroscopy were used to assess the mechanism of oxygen evolution reaction, chemical structure, and morphology of the catalyst.

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References

  1. Electrodes of Conductive Metallic Oxides, Parts A and B (Trasatti, S. Editor). Elsevier, Amsterdam, 1981.

    Google Scholar 

  2. O’Grady, W. E., Iwakura, C., Huang, J., and Yeager, E., in Electrocatalysis (Breiter, M. W., Editor), p. 286. The Electrochemical Society, Pentagon, NJ, 1977.

    Google Scholar 

  3. Performance of Electrodes for Industrial Electrochemical Processes (Hine, F., Tilak, B. V., Denton, J. M., and Lisius, J. D., Editors). The Electrochemical Society, Pentagon, NJ, 1989.

    Google Scholar 

  4. Veggetti, E., Kodintsev, I. M., and Trasatti, S., J. Electroanal. Chem. 339, 255 (1992).

    Article  CAS  Google Scholar 

  5. Trasatti, S., in Electrochemistry of Novel Materials (Lipkowski, J. and Ross, P. N., Editors), p. 207. VCH, New York, 1994.

    Google Scholar 

  6. De Faria, L. A., Prestat, M., Koenig, J.-F., Chartier, P., and Trasatti, S., Electrochim. Acta 44, 1481 (1998).

    Article  Google Scholar 

  7. Boggio, R., Carugati, A., and Trasatti, S., J. Appl. Electrochem. 17, 828 (1987).

    Article  CAS  Google Scholar 

  8. Singh, R. N., Hamdani, M., Koenig, J. F., Poillerat, G., Gautier, J. L., and Chartier, P., J. Appl. Electrochem. 20, 442 (1990).

    Article  CAS  Google Scholar 

  9. Singh, R. N., Pandey, J. P., Singh, N. K., Lal, B., Chartier, P., and Koenig, J. F., Electrochim. Acta 45, 1911 (2000).

    Article  CAS  Google Scholar 

  10. Conway, B. E., in Electrodes of Conductive Metallic Oxides, Part B (Trasatti, S. Editor), p. 433. Elsevier, Amsterdam, 1981.

    Google Scholar 

  11. O’sullivan, E. J. M. and Calvo, E. J., in Comprehensive Chemical Kinetics, Vol. 27 (Compton, R. G., Editor), p. 274. Elsevier, Amsterdam, 1987.

    Google Scholar 

  12. Conway, B. E. and Liu, T. C., Ber. Bunsen.-Ges. Phys. Chem. 91, 461 (1987).

    CAS  Google Scholar 

  13. Tejuca, L. G., Fierro, J. L. F., and Tascon, J. M., Advances in Catalysis, Vol. 36. Academic Press, New York, 1989.

    Google Scholar 

  14. Singh, S. P., Samuels, S., Tiwari, S. K., and Singh, R. N., Int. J. Hydrogen Energy 21, 171 (1996).

    Article  CAS  Google Scholar 

  15. Svegl, F., Orel, B., Grabec-Svegl, I., and Kaucic, V., Electrochim. Acta 45, 4359 (2000).

    Article  CAS  Google Scholar 

  16. Singh, N. K., Singh, J. P., and Singh, R. N., Int. J. Hydrogen Energy 27, 895 (2002).

    Article  CAS  Google Scholar 

  17. Castro, E. B. and Gervasi, C. A., Int. J. Hydrogen Energy 25, 1163 (2000).

    Article  CAS  Google Scholar 

  18. Ito, M., Murakami, Y., Kaji, H., Ohkawauchi, H., Yahikozawa, K., and Takasu, Y., J. Electrochem. Soc. 141, 1243 (1994).

    Article  CAS  Google Scholar 

  19. Takasu, Y., Onove, S., Kameyama, K., Murakami, Y., and Yahikozawa, K., Electrochim. Acta 39, 91 (1994).

    Article  Google Scholar 

  20. de Vidales, M. J. L., Gracia-Martinez, O., Vila, E., Rojas, R. N., and Torralvo, M. J., Mater. Res. Bull. 28, 1135 (1993).

    Article  Google Scholar 

  21. Cannas, C., Musinu, A., Peddis, D., and Piccaluga, G., J. Nanopart. Res. 6, 223 (2004).

    Article  CAS  Google Scholar 

  22. Alexander, K., X-Ray Diffraction Procedures. Wiley, New York, 1962.

    Google Scholar 

  23. Casella, I. G., J. Electroanal. Chem. 520, 119 (2002).

    Article  CAS  Google Scholar 

  24. Trasatti, S. and Buzzanca, G., J. Electroanal. Chem. 29, App. 1 (1971).

  25. Burke, L. D. and Murphy, O. J., J. Electroanal. Chem. 96, 19 (1979).

    Article  CAS  Google Scholar 

  26. Spinolo, G., Ardizzone, S., and Trasatti, S., J. Electroanal. Chem. 423, 49 (1997).

    Article  CAS  Google Scholar 

  27. Rasiyah, P. and Tseung, A. C. C., J. Electrochem. Soc. 365, 130 (1983).

    Google Scholar 

  28. Bocca, C., Cerisola, G., Magnone, E., and Barbucci, A., Int. J. Hydrogen Energy 24, 699 (1999).

    Article  CAS  Google Scholar 

  29. Magnone, E., Cerisola, G., Ferretti, M., and Barbucci, A., J. Solid State Chem. 144, 8 (1999).

    Article  CAS  Google Scholar 

  30. Grenier, J. C., Wattiaux, A., Doumerc, J. P., Dordor, P., Fournes, L., Chaminade, J. P., and Pouchard, M., J. Solid State Chem. 96, 20 (1992).

    Article  CAS  Google Scholar 

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Palmas, S., Ferrara, F., Pisu, A. et al. Oxygen evolution on Ti/Co3O4-coated electrodes in alkaline solution. Chem. Pap. 61, 77–82 (2007). https://doi.org/10.2478/s11696-007-0002-y

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  • DOI: https://doi.org/10.2478/s11696-007-0002-y

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