Abstract
5-[p-(R-Sulfonyl)phenylazo]-1,10-o-phenanthroline (L) and its octahedral complexes of the type [Ni(R2dtp)2(L)] (where R2dtp = diethyl-or dipropyldithiophosphate) with the core NiN2S4 have been prepared and characterized by spectral, magnetic, and thermogravimetric methods. The thermal decomposition mechanism of the compounds was proposed and the kinetic parameters of decomposition were calculated making use of the Coats—Redfern and Horowitz—Metzger equations.
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References
Schmidt, L. H., Ann. Rev. Microbiol. 23, 427 (1977).
Vaichulis, A. J., U.S. 8273362 (1977).
Awad, I. M. A., Osman, A. H., and Aly, A. A. M., Phosphorus, Sulfur, Silicon 178, 1339 (2003).
Livingstone, S. E. and Mihkelson, A. E., Inorg. Chem. 9, 2545 (1970) and references therein.
McCleverty, J. A., Gill, S., Kowalski, R. S. J., Bailey, N. A., Adams, H., Lumbard, K. W., and Murphy, M. A., J. Chem. Soc., Dalton Trans. 1982, 493.
Gupta, A. K. S., Srivastava, R. C., and Parma, S. S., Can. J. Chem. 45, 2293 (1967).
Rufenacht, K., Helv. Chim. Acta 51, 518 (1968).
Sacconi, L., Lomardo, G., and Ciafalo, R., J. Am. Chem. Soc. 82, 4182 (1960).
Machala, V., Travnicek, Z., Sindelar Z., and Kvitek, L., Transition Met. Chem. 25, 715 (2000).
Aly, A. A. M., El-Shahawy, A. S., El-Zohyr, M. F., and Mohamed, A. A., Bull. Soc. Chim. Fr. 6, 930 (1988).
Liu, T. Fu., Lin, H. K., Zhu, S. R., Wang, Z. M., Wang, H. G., Leng, X. B., and Chen, Y. T., Indian J. Chem. 41A, 2530 (2002).
Awad, I. M. A. and Aly, A. A. M., Synth. React. Inorg. Met.-Org. Chem. 21, 375 (1991).
Awad, I. M. A., Phosphorus, Sulfur, Silicon 163, 219 (2000).
Schilt, A. A. and Taylor, R. C., J. Inorg. Nucl. Chem. 9, 211 (1959).
Inskeep, R. G., J. Inorg. Nucl. Chem. 24, 763 (1962).
Nakamoto, K., Infrared and Raman Spectra of Inorganic and Coordination Compounds. Wiley—Interscience, New York, 1991.
Lever, A. B. P., Inorganic Electronic Spectroscopy. Elsevier, New York, 1968.
Figgis, B. N., Introduction to Ligand Fields. Interscience Publishers, New York, 1964.
Bell, F. and Morcom, R. E., J. Therm. Anal. 17, 7 (1979).
Coats, A. W. and Redfern, J. P., Nature 20, 68 (1964).
Horowitz, H. and Metzger, G., Anal. Chem. 35, 1464 (1963).
Cordes, H. F., J. Phys. Chem. 72, 2135 (1968).
Shannon, R. B., Trans. Faraday Soc. 60, 1902 (1964).
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Aly, A.A.M., Awad, I.M.A., Abd El-Mottaleb, M. et al. Complexes of biologically important ligands. I. Ternary complexes of nickel(II) comprising 1,10-o-phenanthrolineazosulfonamide derivatives and alkyldithiophosphates. Chem. Pap. 60, 143–148 (2006). https://doi.org/10.2478/s11696-006-0026-8
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DOI: https://doi.org/10.2478/s11696-006-0026-8