Abstract
A new volumetric method for monitoring the oscillating Belousov—Zhabotinsky reaction with oxalic acid is described. While an oscillatory behavior in the potential of the Pt redox electrode at slow stirring without inert gas bubbling can be observed, a monotonous, nonoscillatory course was found both at the slow and rapid stirring rates for the carbon dioxide evolution. Possible reasons for such observations are discussed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Epstein, I. R. and Pojman, J. A., An Introduction to Nonlinear Chemical Dynamics. Oxford University Press, New York, 1998.
Field, R. J. and Burger, M., Oscillations and Traveling Waves in Chemical Systems. Wiley and Sons, New York, 1985.
Noszticzius, Z. and Bódiss, J., J. Am. Chem. Soc. 101, 3177 (1979).
Ševčík, P. and Adamčíková, L’., Collect. Czech. Chem. Commun. 47, 891 (1982).
Rastogi, R. P., Yadav, K. D. S., and Rastogi, P., Indian J. Chem. 15A, 338 (1977).
Wittmann, M., Stirling, P., and Bódiss, J., Chem. Phys. Lett. 141, 241 (1987).
Guedes, M. C. and Faria, R. B. J., J. Phys. Chem., A 102, 1973 (1998).
Rastogi, R. P., Prem Chand, Pandey, M. K., and Das, M., J. Phys. Chem., A 109, 4562 (2005).
Rastogi, R. P. and Prem Chand, Chem. Phys. Lett. 369, 434 (2003).
Ševčík, P. and Adamčíková, L’., Collect. Czech. Chem. Commun. 50, 799 (1985).
Gaspar, V. and Galambosi, P., J. Phys. Chem. 90, 2222 (1986).
Ševčík, P. and Adamčíková, L’., J. Chem. Phys. 91, 1012 (1989).
Pelle, K., Wittmann, M., Lovrics, K., Noszticzius, Z., Turco-Liveri, M. L., and Lombardo, R., J. Phys. Chem., A 108, 5377 (2004).
Pelle, K., Wittmann, M., Noszticzius, Z., Lombardo, R., Sbriziolo, C., and Turco-Liveri, M. L., J. Phys. Chem., A 107, 2039 (2003).
Ševčík, P., Kissimonová, K., and Adamčíková, L’., J. Phys. Chem., A 104, 3958 (2000).
Ševčík, P., Kissimonová, K., and Adamčíková, L’., J. Phys. Chem., A 107, 1290 (2003).
Bowers, P. G., Bar-Eli, K., and Noyes, R. M., J. Chem. Soc., Faraday Trans. 92, 2843 (1996).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ševčík, P., Mišicák, D. & Adamčíková, L. Carbon dioxide production in the oscillating Belousov—Zhabotinsky reaction with oxalic acid. Chem. Pap. 60, 1–4 (2006). https://doi.org/10.2478/s11696-006-0001-4
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.2478/s11696-006-0001-4