Skip to main content
Log in

Void structure of concrete with superabsorbent polymers and its relation to frost resistance of concrete

  • Original Article
  • Published:
Materials and Structures Aims and scope Submit manuscript

Abstract

Superabsorbent polymers (SAP) can be used to control air void formation in concrete. However, due to surfactant left on suspension polymerized SAP particles during production, they may not only create SAP voids but also entrain extra air. In the present investigation, a method is tested to remove surfactant prior to concrete mixing. The method comprises rinsing of the SAP with ethanol. This effectively removes the surfactant. Freeze–thaw testing of concrete with rinsed and non-rinsed SAP shows that for equal dosages of SAP, the extra air entrained due to surfactant is considerable and can make the difference between poor and satisfactory frost-resistance. Furthermore, the results indicate that voids created directly by SAP protect concrete against frost deterioration just like other air voids; if the concrete contains enough SAP voids, these alone can provide sufficient frost resistance.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11

Similar content being viewed by others

References

  1. Litvan GG, Sereda PJ (1978) Particulate admixture for enhanced freeze–thaw resistance of concrete. Cem Concr Res 8:53–60

    Article  Google Scholar 

  2. Jensen OM, Hansen PF (2001) Water-entrained cement-based materials: I. Principles and theoretical background. Cem Concr Res 31:647–654

    Article  Google Scholar 

  3. Mönnig S, Lura P (2007) Superabsorbent polymers – An additive to increase freeze-thaw resistance of high strength concrete. Adv Constr Mater Part V:351-358

  4. Reinhardt H-W, Assmann A, Mönnig S (2008) Superabsorbent polymers (SAPs)—an admixture to increase the durability of concrete. In: Sun W, Breugel Kv, Miao C, Ye G, Chen H (eds) Microstructure related durability of cementitious composites, RILEM Proceedings PRO 61, pp 313–322

  5. Laustsen S, Hasholt MT, Jensen OM (2008) A new technology for air-entrainment of concrete. In: Sun W, Breugel Kv, Miao C, Ye G, Chen H (eds) Microstructure related durability of cementitious composites, RILEM Proceedings PRO 61, pp 1223–1230

  6. Laustsen S, Møller AM (2007) Kontrolleret luftindblanding i beton (in Danish). Technical University of Denmark, Master thesis

    Google Scholar 

  7. Dudziak L, Mechtcherine V (2010) Enhancing early-age resistance to cracking in high-strength cement-based materials by means of internal curing using super absorbent polymers. In: Brameshuber W (ed) Additions improving properties of concrete, RILEM Proceedings PRO 77, pp 129–139

  8. Laustsen S (2011) Engineered air-entrainment of concrete—Use of superabsorbent polymers. Ph.D. thesis, Technical University of Denmark

  9. Dodson VH (1990) Concrete admixtures. Van Nostrand Reinhold, New York

    Book  Google Scholar 

  10. Pigeon M, Pleau R (1995) Durability of concrete in cold climates. E & FN Spon, London

    Google Scholar 

  11. Du L, Folliard KJ (2005) Mechanisms of air entrainment in concrete. Cem Concr Res 35:1463–1471

    Article  Google Scholar 

  12. Pigeon M, Marchand J, Pleau R (1996) Frost resistant concrete. Constr Build Mater 10:339–348

    Article  Google Scholar 

  13. Buchholz FL, Graham AT (1998) Modern superabsorbent polymer technology. John Wiley & Sons, New York

    Google Scholar 

  14. Jensen OM, Hansen PF (2001) Water-entrained cement-based materials: II. Experimental observations. Cem Concr Res 32:973–978

    Article  Google Scholar 

  15. Jensen OM (2011) Water absorption of superabsorbent polymers in a cementitious environment. In: Leung C, Wan KT (eds) Advances in Construction Materials through Science and Engineering, RILEM Proceedings PRO 79, pp. 22–35

  16. DS/EN 12350-2 (2002) Testing fresh concrete: Part 2: Slump test. Danish Standard

  17. DS/EN 12350-7 (2002) Testing fresh concrete: Part 7: Air content–pressure methods. Danish Standard

  18. Lura P, Friedemann K, Stallmach F, Mönning S, Wyrzykowski M, Esteves LP (2012) Kinetics of water migration in cement-based systems containing superabsorbent polymers. Chapter 4 in Mechtcherine V, Reinhard H-W (eds) Application of superabsorbent polymers (SAP) in concrete construction. State of the Art Report prepared by RILEM Technical Committee 225-SAP. Springer, Heidelberg

  19. Laustsen S, Bentz DP, Hasholt MT, Jensen OM (2010) CT measurements of SAP voids in concrete. In Jensen OM, Hasholt MT, Laustsen S (eds) Use of superabsorbent polymers and other new additives in concrete, RILEM Proceedings PRO 74, pp 153–162

  20. DS/EN 480-11 (2005) Admixtures for concrete, mortar and grout—Test methods—Part 11: Determination of air void characteristics in hardened concrete. Danish Standard

  21. DS/EN 12390-3 (2006) Testing hardend concrete—Part 3: Compressive strength of test specimens. Danish Standard

  22. Hasholt MT, Jensen OM, Kovler K, Zhutovsky S (2012) Can superabsorbent polymers mitigate autogenous shrinkage of internally cured concrete without compromising the strength? Constr Build Mater 31:226–230

    Article  Google Scholar 

  23. DS/CEN/TS 12390-9 (2006) Testing hardened concrete—Part 9: Freeze–thaw resistance—Scaling, Danish Standard

  24. DS 2426 (2011) Concrete—Materials—Rules for application of EN 206-1 in Denmark. Danish Standard

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Marianne Tange Hasholt.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Laustsen, S., Hasholt, M.T. & Jensen, O.M. Void structure of concrete with superabsorbent polymers and its relation to frost resistance of concrete. Mater Struct 48, 357–368 (2015). https://doi.org/10.1617/s11527-013-0188-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1617/s11527-013-0188-0

Keywords

Navigation