Abstract
Carbon nanotubes come in many varieties, with chemical, mechanical, and electrical properties depending on carbon nanotube (CNT) structural morphology. In order to provide a platform for CNT structural tuning, a membrane reactor was designed and constructed. This reactor provided more intimate gas-catalyst contact by decoupling the carbon feedstock gas from carrier gas in a chemical vapour deposition (CVD) environment using an asymmetric membrane and a macroporous membrane. Growth using this membrane reactor demonstrated normalized yield improvements of ∼300% and ∼1000% for the asymmetric and macroporous membrane cases, respectively, over standard CVD methods. To illustrate the possibility for control, growth variation with time was successfully demonstrated by growing vertically aligned multi-walled CNTs to heights of 0.71 mm, 1.36 mm, and 1.84 mm after growth for 15, 30, and 60 minutes in a commercial thermal CVD reactor. To demonstrate CNT diameter control via catalyst particle size, dip coating and spray coating methods were explored using ferrofluid and Fe(NO3)3 systems. CNT diameter was demonstrated to increase with increasing particle size, yielding CNT like growth with diameters ranging from 15 -150 nm. Demonstration of these dimensions of control coupled with the dramatic efficiency increases over growth in a commercialized CVD reactor establish this new reactor technology as a starting point for further research into CNT structural tuning.
Similar content being viewed by others
References
S. Iijima. Helical microtubules of graphitic carbon. Nature 354(6348), pp. 56–58. 1991.
E. W. Wong, P. E. Sheehan and C. M. Lieber. Nanobeam mechanics: Elasticity, strength, and toughness of nanorods and nanotubes. Science 277(5334), pp. 1971–1975. 1997.
J. -. Salvetat, J. -. Bonard, N. B. Thomson, A. J. Kulik, L. Forró, W. Benoit and L. Zuppiroli. Mechanical properties of carbon nanotubes. Applied Physics A: Materials Science and Processing 69(3), pp. 255–260. 1999.
N. N. Hamada., New one-dimensional conductors: Graphitic microtubules. Phys. Rev. Lett. 68(10), pp. 1579–1581.
M.C. Weisenberger M.C.., Enhanced mechanical properties of polyacrylonitrile/multiwall carbon nanotube composite fibers. Journal of Nanoscience and Nanotechnology 3(6), pp. 535–539.
E.T. Thostenson E.T.., Aligned multi-walled carbon nanotube-reinforced composites: Processing and mechanical characterization. J. Phys. D 35(16),.
P.-C. Ma P.-C.., Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: A review. Composites Part A: Applied Science and Manufacturing 41(10), pp. 1345–1367.
P. P. Liu., Modifications of carbon nanotubes with polymers. European Polymer Journal 41(11), pp. 2693–2703.
A.B. Dalton A.B.., Super-tough carbon-nanotube fibres. Nature 423(6941),.
M. P. Siegal, D. L. Overmyer, P. P. Provencio and D. R. Tallant. Linear behavior of carbon nanotube diameters with growth temperature. Journal of Physical Chemistry C 114(35), pp. 14864–14867. 2010.
K. Liu, K. Jiang, Y. Wei, S. Ge, P. Liu and S. Fan. Controlled termination of the growth of vertically aligned carbon nanotube arrays. Adv Mater 19(7), pp. 975–978. 2007.
M. Maeda, T. Kamimura and K. Matsumoto. One by one control of the exact number of carbon nanotubes formed by chemical vapor deposition growth: A digital growth process. Appl. Phys. Lett. 90(4), 2007.
K. Li, “Transport mechanisms,” in Ceramic Membranes for Separation and Reaction, John Wiley & Sons ed. Anonymous Hoboken: John Wiley & Sons, Ltd, 2007, pp. 103.
A. A. Puretzky, D. B. Geohegan, X. Fan and S. J. Pennycook. Dynamics of single-wall carbon nanotube synthesis by laser vaporization. Applied Physics A: Materials Science and Processing 70(2), pp. 153–160. 2000.
Acknowledgments
The authors would like to thank Dr. Louise Weaver, Steven Cogswell, Suporn Boonsue, Keith Rollins, and Adon Briggs for technical support and discussions. Research supported by the Richard J. Currie Chair in Nanotechnology.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Sheppard, D.J.K., Chibante, L.P.F. Structural Tuning Using a Novel Membrane Reactor for Carbon Nanotube Synthesis. MRS Online Proceedings Library 1752, 39–44 (2015). https://doi.org/10.1557/opl.2015.209
Published:
Issue Date:
DOI: https://doi.org/10.1557/opl.2015.209