Abstract
Large-area fast lithium ion conducting ceramic thin freestanding sheets was successfully prepared using a sheet forming technique. This ceramic sheet contains the crystalline phase of Li1+x+yAlxTi2-xSiyP3-yO12 with the NASICON type structure. The ceramic sheet showed maximum overall conductivity over 10−3 S cm−1 at room temperature. And, the developed thin ceramic sheet has sufficient flexibility against bending stress. Because a thin large-area ceramic electrolyte sheet was prepared using less energy compared with a conventional glass casting method, it is suitable for practical use.
Similar content being viewed by others
References
K. M. Abraham and Z. Jian, Electrochem. Soc., 143, 1 (1996).
Z. Peng, S. A. Freunberger, Y. Chen and P. G. Bruce, Science, 337, 563 (2012).
A. Kraytsberg and Y. Ein-Eli, Journal of Power Sources, 196, 886 (2011).
Y. Wang and H. Zhou, Journal of Power Sources, 195, 358 (2010).
M. Armand, J.-M. Tarascon, Nature, 451, 652 (2008).
H. Aono, E. Sugimoto, Y. Sadaoka, N. Imanaka and G. Adachi, J. Electrochem. Soc., 136, 590 (1989).
H. Aono, E. Sugimoto, Y. Sadaoka, N. Imanaka and G. Adachi, Chem. Lett., 1990, 1825 (1990).
J. Fu, Solid State Ionics, 96, 195 (1997).
J. Fu, Solid State Ionics, 104, 191 (1997).
J. Fu, J. Mater. Sci., 33, 1549 (1998).
J. S. Thokchom and B. Kumar, Solid State Ionics, 177, 727 (2006).
J. S. Thokchom and B. Kumar, J. Electrochem. Soc., 154, A331 (2007).
J. S. Thokchom, N. Gupta, and B. Kumar, J. Electrochem. Soc., 155, A915 (2008).
L. Puech, C. Cantau, P. Vinatier, G. Toussaint and P. Stevens, Journal of Power Sources, 214, 330 (2012).
S. Wong, P. J. Newman, A. S. Best, K. M. Nairn, D. R. MacFarlane and M. Forsyth, J. Mater. Chem., 8, 2199 (1998).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Hamamoto, K., Matveev, D., Yamaguchi, T. et al. Flexible Fast Lithium Ion Conducting Ceramic Electrolyte. MRS Online Proceedings Library 1496, 57 (2012). https://doi.org/10.1557/opl.2013.376
Published:
DOI: https://doi.org/10.1557/opl.2013.376