Graphene Oxide as a Two-dimensional Surfactant

Abstract

Graphene oxide (GO) is a nonstoichiometric two-dimensional material obtained from the chemical oxidation and exfoliation of graphite, which has recently attracted intense research interest as a precursor for bulk production of graphene. GO has long been believed to be hydrophilic due to its dispersibility in water. Recent work in our group, however, has found that GO is actually a two-dimensional amphiphile; the edge of the sheet-like material is hydrophilic, while the basal plane of the material contains more hydrophobic graphitic nanodomains. To prove the concept, we demonstrate GO’s surface activity at an air-water interface, as well as its utility in dispersing insoluble aromatic materials such as toluene, graphite, and carbon nanotubes in water. As a colloidal surfactant which can be converted to a conducting material, GO presents unique possibilities for aqueous solution processing of organic electronic materials.

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References

  1. 1.

    Cote, L. J., Kim, F., Huang, J., J. Am. Chem. Soc., 131, 1043 (2009).

    CAS  Article  Google Scholar 

  2. 2.

    Hummers, W. S. and Offeman, R. E., J. Am. Chem. Soc., 80, 1339 (1958).

    CAS  Article  Google Scholar 

  3. 3.

    Lerf, A., He, H.Y., Forster, M., Klinowski, J., J. Phys. Chem. B 102, 4477 (1998).

    CAS  Article  Google Scholar 

  4. 4.

    Gao, W., Alemany, L.B., Ci, L., Ajayan, P.M., Nat. Chem. 1, 403 (2009).

    CAS  Article  Google Scholar 

  5. 5.

    Dobelle, W. H., Beer, M., J. Cell Biol. 39, 733 (1968).

    CAS  Article  Google Scholar 

  6. 6.

    Stankovich, S., Dikin, D.A., Piner, R.D., Kohlhaas, K.A., Kleinhammes, A., Jia, Y., Wu, Y., Nguyen, S.T., Ruoff, R.S., Carbon 45, 1558 (2007).

  7. 7.

    Croft, R.C., Quarterly Rev. 14, 1 (1960).

    CAS  Article  Google Scholar 

  8. 8.

    Schniepp, H.C., Li, J.L., McAllister, M.J., Sai, H., Herrera-Alonso, M., Adamson, D.H., Prud’homme, R.K., Car, R., Saville, D.A., Aksay, I.A., J. Phys. Chem. B 110, 8535 (2006).

  9. 9.

    Cote, L.J., Cruz-Silva, R., Huang, J.. J. Am. Chem. Soc. 131, 11027 (2009).

    CAS  Article  Google Scholar 

  10. 10.

    Gilje, S, Dubin, S., Badakhshan, A., Farrar, J., Danczyk, S.A., Kaner, R.B., Adv. Mater. 22, 419 (2010).

    CAS  Article  Google Scholar 

  11. 11.

    Wang, Z., Zhou, X., Zhang, J., Boey, F., Zha, H., J Phys. Chem. C 113, 14071 (2009).

  12. 12.

    Ramesha, G.K., Sampath S., J. Phys. Chem. C 113, 7985 (2009).

  13. 13.

    Allen, M.J., Tung, V.C., Kaner, R.B., Chem. Rev. 110, 132 (2010).

    CAS  Article  Google Scholar 

  14. 14.

    Park, S., Ruoff R.S., Nat. Nanotechnol. 4, 217 (2009).

    CAS  Article  Google Scholar 

  15. 15.

    Compton, O.C., Nguyen, S.T., Small 6, 711 (2010).

    CAS  Article  Google Scholar 

  16. 16.

    Dikin, D.A., Stankovich, S., Zimney, E.J., Piner, R.D., Dommett, G.H.B., Evmenenko, G., Nguyen, S.T., Ruoff, R.S., Nature 448, 457 (2007).

  17. 17.

    Gilje, S., Han, S., Wang, M., Wang, K.L., Kaner, R.B., Nano Lett. 7, 3394 (2007).

  18. 18.

    Li, D., Kaner, R.B.. Science 320, 1170 (2008).

    CAS  Article  Google Scholar 

  19. 19.

    Li, D., Muller, M.B., Gilje, S., Kaner, R.B., Wallace, G.G., Nat. Nanotechnol. 3, 101 (2008).

  20. 20.

    Erickson K., Erni R., Lee Z., Alem N., Gannett W., Zettl A., Adv. Mater. 22, 4467 (2010).

  21. 21.

    Myers D., Surfactant Science and Technology, Wiley-Interscience, Hoboken, NJ (2006).

  22. 22.

    Lipp, M.M., Lee, K.Y.C., Zasadzinski, J.A., Waring, A.J., Rev. Sci. Instrum. 68, 2574 (1997).

  23. 23.

    Kim, J., Cote, L.J., Kim, F., Yuan, W., Shull, K.R., Huang, J., J. Am. Chem. Soc. 132, 8180 (2010).

    CAS  Article  Google Scholar 

  24. 24.

    Pickering, S.U., J. Chem. Soc. 91, 2001 (1907).

    Article  Google Scholar 

  25. 25.

    Islam, M.F., Rojas, E., Bergey, D.M., Johnson, A.T., Yodh, A.G., Nano Lett. 3, 269 (2003).

    CAS  Article  Google Scholar 

  26. 26.

    Moore, V.C., Strano, M.S., Haroz, E.H., Hauge, R.H., Smalley, R.E., Schmidt, J., Talmon, Y., Nano Lett. 3, 1379 (2003).

    CAS  Article  Google Scholar 

  27. 27.

    Grossiord, N., Loos, J., Regev, O., Koning, C.E., Chem. Mater. 18, 1089 (2006).

    CAS  Article  Google Scholar 

  28. 28.

    Vaisman, L., Wagner, H.D., Marom, G., Adv. Colloid Interface Sci. 128, 37 (2006).

    Article  Google Scholar 

  29. 29.

    Cote, L.J., Kim, J., Tung, V.C., Luo, J., Kim, F., Huang, J., Pure Appl. Chem. 83, 1, 95 (2011).

    CAS  Article  Google Scholar 

  30. 30.

    Luo, J., Cote, L.J., Tung, V.C., Tan, A.T.L., Goins, P.E., Wu, J., Huang, J., J. Am. Chem. Soc., 132, 17667 (2010).

    CAS  Article  Google Scholar 

  31. 31.

    Tung, V.C., Huang, J.H., Tevis, I., Kim, F., Kim, J., Chu, C.W., Stupp, S.I., Huang, J., J. Amer. Chem. Soc., 133, 4940 (2011).

    CAS  Article  Google Scholar 

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Correspondence to Andrew R. Koltonow.

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Koltonow, A.R., Kim, J., Cote, L.J. et al. Graphene Oxide as a Two-dimensional Surfactant. MRS Online Proceedings Library 1344, 907 (2011). https://doi.org/10.1557/opl.2011.1367

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