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Oxidized Single-Walled Carbon Nanotubes: Removal of Carbonaceous Functionalized Material by Washing with Solvents or Base

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Abstract

Oxidized single-walled carbon nanotubes (SWNTs) have been prepared following a widely reported two-step purification/oxidation procedure in the presence or absence of a treatment with base (NaOH). The oxidized nanotube samples washed with solvents or base appear close to identical with respect to both appearance and properties. Efficient removal of both metal and carbonaceous impurities and introduction of –COOH groups on the nanotube surface have been demonstrated by AFM, Raman and FTIR spectroscopy. Furthermore, persistence of optical properties was confirmed using UV-vis/NIR absorption and NIR photoluminescence spectroscopies.

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References

  1. M. E. Itkis, S. Niyogi, M. E. Meng, M. A. Hamon, H. Hu and R. C. Haddon, Nano Lett 2 (2), 155–159 (2002).

    Google Scholar 

  2. P. Singh, S. Campidelli, S. Giordani, D. Bonifazi, A. Bianco and M. Prato, Chem Soc Rev 38, 2214–2230 (2009).

    Google Scholar 

  3. A. Bianco, K. Kostarelos, C. D. Partidos and M. Prato, Chem Comm (5), 571–577 (2005).

  4. S. Niyogi, M. A. Hamon, H. Hu, B. Zhao, P. Bhowmik, R. Sen, M. E. Itkis and R. C. Haddon, Acc Chem Res 35 (12), 1105–1113 (2002).

    Google Scholar 

  5. H. Hu, B. Zhao, M. E. Itkis and R. C. Haddon, J Phys Chem B 107 (50), 13838–13842 (2003).

    Google Scholar 

  6. A. C. Dillon, T. Gennett, K. M. Jones, J. L. Alleman, P. A. Parilla and M. J. Heben, Adv Mater 11 (16), 1354–1358 (1999).

    Google Scholar 

  7. D. Tasis, N. Tagmatarchis, A. Bianco and M. Prato, Chem Rev 106 (3), 1105–1136 (2006).

    Google Scholar 

  8. D. Bonifazi, C. Nacci, R. Marega, S. Campidelli, G. Ceballos, S. Modesti, M. Meneghetti and M. Prato, Nano Lett 6 (7), 1408–1414 (2006).

    Google Scholar 

  9. D. Movia, E. Del Canto and S. Giordani, J Phys Chem C 114 (43), 18407–18413 (2010).

    Google Scholar 

  10. S. Giordani, J.F. Colomer, F. Cattaruzza, J. Alfonsi, M. Meneghetti, M. Prato and D. Bonifazi, Carbon 47, 578–588 (2009).

    Google Scholar 

  11. E. Del Canto, K. Flavin, M. Natali, T. Perova and S. Giordani, Carbon 48, 2815–2824 (2010).

    Google Scholar 

  12. C. G. Salzmann, S. A. Llewellyn, G. Tobias, M. A. H. Ward, Y. Huh and M. L. H. Green, Adv Mater 19 (6), 883–887 (2007).

    Google Scholar 

  13. L. Shao, G. Tobias, C. G. Salzmann, B. Ballesteros, S. Y. Hong, A. Crossley, B. G. Davis and M. L. H. Green, Chem Comm (47), 5090–5092 (2007).

    Google Scholar 

  14. E. Del Canto, K. Flavin, D. Movia, C. Navio, C. Bittencourt and S. Giordani, Chem Mater 23 (1), 67–74 (2011).

    Google Scholar 

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Correspondence to Silvia Giordani.

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Canto, E.D., Flavin, K., Movia, D. et al. Oxidized Single-Walled Carbon Nanotubes: Removal of Carbonaceous Functionalized Material by Washing with Solvents or Base. MRS Online Proceedings Library 1362, 944 (2011). https://doi.org/10.1557/opl.2011.1085

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  • DOI: https://doi.org/10.1557/opl.2011.1085

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