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Noble surface molecularly imprinted polymer modified titanium dioxide toward solanesol adsorption selectivity study

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  • Thermodynamics of Complex Solids
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Abstract

Surface molecularly imprinted polymer of solanesol (SA-SMIP) was prepared by reversed phase suspension polymerization using modified titanium dioxide (TiO2) as carrier, and operation conditions were investigated and optimized. Structures of modified TiO2 and SA-SMIP obtained at optimal conditions were characterized by Fourier transform infrared spectrometer adopting original TiO2 and non-surface molecularly imprinted polymer as reference. The SA-SMIP synthesized under optimal conditions displayed an excellent recognition of SA from the mixture of SA and triacontanol. The maximum separation degree of SA was 2.90. Finally, the adsorption kinetics and isotherm were investigated and analyzed. Adsorption kinetics results indicated that the adsorption of SA-SMIP to SA was a pseudo-second order process, and the adsorption of beginning and later stages was controlled by homogeneous particle diffusion and adsorption reaction process, respectively. Adsorption isotherm results documented hereby were two sorts of bonding sites, complete imprinted cavities and defective imprinted cavities. The adsorption for two bonding sites could be well lined up with the Langmuir model.

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Acknowledgments

This work was supported by the Natural Science Foundation of China (Grant No. 51563015).

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Authors and Affiliations

  1. State Key Laboratory of Advanced Processing and Recycling of Nonferrous Metals, Lanzhou University of Technology, Lanzhou, 730050, China

    Chenglong Duan, Zhenbin Chen, Xiaojiao Liu, Ke Li, Xudong Wang & Weiwei Jia

  2. School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou, 730050, China

    Chenglong Duan, Zhenbin Chen, Xiaojiao Liu, Ke Li, Xudong Wang & Weiwei Jia

  3. Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, School of Environment and Energy, Guangzhou Higher Education Mega Centre, South China University of Technology, Guangzhou, 5100067, China

    Zhenghua Tang

  4. Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control, Guangdong Provincial Engineering and Technology Research Center for Environmental Risk Prevention and Emergency Disposal, School of Environment and Energy, Guangzhou Higher Education Mega Centre, South China University of Technology, Guangzhou, 510006, China

    Zhenghua Tang

  5. Soft Matter and Molecular Biophysics Group, Department of Applied Physics, University of Santiago de Compostela, Santiago de Compostela, 15782, Spain

    Juan M. Ruso

  6. Department of Physics and Engineering, Frostburg State University, Maryland, 21532, USA

    Zhen Liu

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  1. Chenglong Duan
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Correspondence to Zhenbin Chen or Zhen Liu.

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Duan, C., Chen, Z., Liu, X. et al. Noble surface molecularly imprinted polymer modified titanium dioxide toward solanesol adsorption selectivity study. Journal of Materials Research 34, 3271–3287 (2019). https://doi.org/10.1557/jmr.2019.148

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  • DOI: https://doi.org/10.1557/jmr.2019.148

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