Skip to main content
Log in

Microstructure and mechanical properties of Mg–3.0Y–2.5Nd–1.0Gd–x Zn–0.5Zr alloys produced by metallic and sand mold casting

  • Article
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

Abstract

Mg–3.0Y–2.5Nd–1.0Gd–x Zn–0.5Zr (x = 0, 0.2, 0.5, and 1.0) (wt%) alloys were produced by metallic and sand mold casting to study the microstructure and mechanical properties of the alloys. The as-cast Zn-free alloys consist of α-Mg and eutectics, whereas the Zn-containing alloys contain additional long-period stacking ordered (LPSO) structures. With a higher solidification, the cooling rate brought by metallic mold casting, grains, and eutectics are refined, which enhances the elongation of the alloys, accompanied by a decrease of area fraction of the LPSO structure. Some residual eutectics in the Mg–3.0Y–2.5Nd–1.0Gd–1.0Zn–0.5Zr alloys act as obstacles to grain boundary migration during solution treatment, which make the average grain size 15–20 μm smaller than that of the other alloys and hence improve the elongation of the alloys. The Zn addition brings notable enhancements to mechanical properties of the alloys due to solid solution strengthening of Zn. Especially, the peak-aged Mg–3.0Y–2.5Nd–1.0Gd–0.5Zn–0.5Zr alloys perform with the highest overall tensile properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

FIG. 1.
FIG. 2.
FIG. 3.
FIG. 4.
FIG. 5.
FIG. 6.
FIG. 7.
FIG. 8.

Similar content being viewed by others

References

  1. B.L. Mordike and T. Ebert: Magnesium: Properties—Applications—Potential. Mater. Sci. Eng., A 302, 37–45 (2001).

    Article  Google Scholar 

  2. Y.M. Zhu, A.J. Morton, and J.F. Nie: The 18R and 14H long-period stacking ordered structures in Mg–Y–Zn alloys. Acta Mater. 58, 2936–2947 (2010).

    Article  CAS  Google Scholar 

  3. W. Liu, J. Zhang, C. Xu, X. Zong, J. Hao, Y. Li, and Z. Zhang: High-performance extruded Mg89Y4Zn2Li5 alloy with deformed LPSO structures plus fine dynamical recrystallized grains. Mater. Des. 110, 1–9 (2016).

    Article  CAS  Google Scholar 

  4. K. Liu, J. Zhang, G. Su, D. Tang, L.L. Rokhlin, F.M. Elkin, and J. Meng: Influence of Zn content on the microstructure and mechanical properties of extruded Mg–5Y–4Gd–0.4Zr alloy. J. Alloys Compd. 481, 811–818 (2009).

    Article  CAS  Google Scholar 

  5. X. Gao and J.F. Nie: Enhanced precipitation-hardening in Mg–Gd alloys containing Ag and Zn. Scr. Mater. 58, 619–622 (2008).

    Article  CAS  Google Scholar 

  6. X.Z. Han, W.C. Xu, and D.B. Shan: Effect of precipitates on microstructures and properties of forged Mg–10Gd–2Y–0.5Zn–0.3Zr alloy during ageing process. J. Alloys Compd. 509, 8625–8631 (2011).

    Article  CAS  Google Scholar 

  7. W. Rong, Y. Wu, Y. Zhang, M. Sun, J. Chen, L. Peng, and W. Ding: Characterization and strengthening effects of γ′ precipitates in a high-strength casting Mg–15Gd–1Zn–0.4Zr (wt%) alloy. Mater. Charact. 126, 1–9 (2017).

    Article  CAS  Google Scholar 

  8. Y. Xu, D. Xu, X. Shao, and E. Han: Guinier-preston zone, quasicrystal and long-period stacking ordered structure in Mg-based alloys, a review. Acta Metall. Sin. (Engl. Lett.) 26, 217–231 (2013).

    Article  CAS  Google Scholar 

  9. Y. Chino, M. Mabuchi, S. Hagiwara, H. Iwasaki, A. Yamamoto, and H. Tsubakino: Novel equilibrium two phase Mg alloy with the long-period ordered structure. Scr. Mater. 51, 711–714 (2004).

    Article  CAS  Google Scholar 

  10. M. Tane, Y. Nagai, H. Kimizuka, K. Hagihara, and Y. Kawamura: Elastic properties of an Mg–Zn–Y alloy single crystal with a long-period stacking-ordered structure. Acta Mater. 61, 6338–6351 (2013).

    Article  CAS  Google Scholar 

  11. T. Itoi, T. Seimiya, Y. Kawamura, and M. Hirohashi: Long period stacking structures observed in Mg97Zn1Y2 alloy. Scr. Mater. 51, 107–111 (2004).

    Article  CAS  Google Scholar 

  12. M. Matsuda, S. Ii, Y. Kawamura, Y. Ikuhara, and M. Nishida: Variation of long-period stacking order structures in rapidly solidified Mg97Zn1Y2 alloy. Mater. Sci. Eng., A 393, 269–274 (2005).

    Article  CAS  Google Scholar 

  13. E. Abe, Y. Kawamura, K. Hayashi, and A. Inoue: Long-period ordered structure in a high-strength nanocrystalline Mg–1 at.% Zn–2 at.% Y alloy studied by atomic-resolution Z-contrast STEM. Acta Mater. 50, 3845–3857 (2002).

    Article  CAS  Google Scholar 

  14. T. Honma, T. Ohkubo, S. Kamado, and K. Hono: Effect of Zn additions on the age-hardening of Mg–2.0Gd–1.2Y–0.2Zr alloys. Acta Mater. 55, 4137–4150 (2007).

    Article  CAS  Google Scholar 

  15. J.F. Nie, X. Gao, and S.M. Zhu: Enhanced age hardening response and creep resistance of Mg–Gd alloys containing Zn. Scr. Mater. 53, 1049–1053 (2005).

    Article  CAS  Google Scholar 

  16. S. Zhang, G.Y. Yuan, C. Lu, and W.J. Ding: The relationship between (Mg,Zn)3RE phase and 14H-LPSO phase in Mg–Gd–Y–Zn–Zr alloys solidified at different cooling rates. J. Alloys Compd. 509, 3515–3521 (2011).

    Article  CAS  Google Scholar 

  17. Q. Wang, G. Wu, Z. Hou, B. Chen, Y. Zheng, and W. Din: A comparative study of Mg–Gd–Y–Zr alloy cast by metal mould and sand mould. China Foundry 7, 6–12 (2009).

    Google Scholar 

  18. Z. Su, C. Liu, and Y. Wan: Microstructures and mechanical properties of high performance Mg–4Y–2.4Nd–0.2Zn–0.4Zr alloy. Mater. Des. 45, 466–472 (2013).

    Article  CAS  Google Scholar 

  19. H. Zhang, J. Fan, L. Zhang, G. Wu, W. Liu, W. Cui, and S. Feng: Effect of heat treatment on microstructure, mechanical properties and fracture behaviors of sand-cast Mg–4Y–3Nd–1Gd–0.2Zn–0.5Zr alloy. Mater. Sci. Eng., A 677, 411–420 (2016).

    Article  CAS  Google Scholar 

  20. Y.H. Kang, D. Wu, R.S. Chen, and E.H. Han: Microstructures and mechanical properties of the age hardened Mg–4.2Y–2.5Nd–1Gd–0.6Zr (WE43) microalloyed with Zn. J. Magnesium Alloys 2, 109–115 (2014).

    Article  CAS  Google Scholar 

  21. Z. Zhang, X. Yang, Z. Xiao, J. Wang, D. Zhang, C. Liu, and T. Sakai: Dynamic recrystallization behaviors of a Mg–4Y–2Nd–0.2Zn–0.5Zr alloy and the resultant mechanical properties after hot compression. Mater. Des. 97, 25–32 (2016).

    Article  CAS  Google Scholar 

  22. S. Pang, G. Wu, W. Liu, M. Sun, Y. Zhang, Z. Liu, and W. Ding: Effect of cooling rate on the microstructure and mechanical properties of sand-casting Mg–10Gd–3Y–0.5Zr magnesium alloy. Mater. Sci. Eng., A 562, 152–160 (2013).

    Article  CAS  Google Scholar 

  23. D. Holmgren: Review of thermal conductivity of cast iron. Int. J. Cast Met. Res. 18, 331–345 (2013).

    Article  CAS  Google Scholar 

  24. P.K. Krajewski, G. Piwowarski, P.L. Zak, and W.K. Krajewski: Experiment and numerical modelling the time of plate-shape casting solidification vs. thermal conductivity of mould material. Arch. Metall. Mater. 59, 1045–1048 (2014).

    Article  CAS  Google Scholar 

  25. S.X. Chen: Thermal conductivity of sands. Heat Mass Transfer 44, 1241–1246 (2008).

    Article  Google Scholar 

  26. Q. Zhang, L. Fu, T. Fan, B. Tang, L. Peng, and W. Ding: Ab initio study of the effect of solute atoms Zn and Y on stacking faults in Mg solid solution. Phys. B 416, 39–44 (2013).

    Article  CAS  Google Scholar 

  27. Y.M. Zhu, A.J. Morton, and J.F. Nie: Growth and transformation mechanisms of 18R and 14H in Mg–Y–Zn alloys. Acta Mater. 60, 6562–6572 (2012).

    Article  CAS  Google Scholar 

  28. C. Xu, T. Nakata, X. Qiao, M. Zheng, K. Wu, and S. Kamado: Effect of LPSO and SFs on microstructure evolution and mechanical properties of Mg–Gd–Y–Zn–Zr alloy. Sci. Rep. 7, 40846–40855 (2017).

    Article  CAS  Google Scholar 

  29. C.Q. Li, D.K. Xu, Z.R. Zeng, B.J. Wang, L.Y. Sheng, X.B. Chen, and E.H. Han: Effect of volume fraction of LPSO phases on corrosion and mechanical properties of Mg–Zn–Y alloys. Mater. Des. 121, 430–441 (2017).

    Article  CAS  Google Scholar 

  30. R. Chen, S. Sandlöbes, X. Zeng, D. Li, S. Korte-Kerzel, and D. Raabe: Room temperature deformation of LPSO structures by non-basal slip. Mater. Sci. Eng., A 682, 354–358 (2017).

    Article  CAS  Google Scholar 

  31. J. Li, R. Chen, and W. Ke: Microstructure and mechanical properties of Mg–Gd–Y–Zr alloy cast by metal mould and lost foam casting. Trans. Nonferrous Met. Soc. China 21, 761–766 (2011).

    Article  CAS  Google Scholar 

  32. T. Rzychon and A. Kielbus: Microstructure of WE43 casting magnesium alloy. J. Achiev. Mater. Manuf. Eng. 21, 31–34 (2007).

    Google Scholar 

  33. Z. Liu, G. Wu, W. Liu, S. Pang, and W. Ding: Effect of heat treatment on microstructures and mechanical properties of sand-cast Mg–4Y–2Nd–1Gd–0.4Zr magnesium alloy. Trans. Nonferrous Met. Soc. China 22, 1540–1548 (2012).

    Article  CAS  Google Scholar 

  34. X. Gao, B.C. Muddle, and J.F. Nie: Transmission electron microscopy of Zr–Zn precipitate rods in magnesium alloys containing Zr and Zn. Philos. Mag. Lett. 89, 33–43 (2009).

    Article  CAS  Google Scholar 

  35. G. Sha, H.M. Zhu, J.W. Liu, C.P. Luo, Z.W. Liu, and S.P. Ringer: Hydrogen-induced decomposition of Zr-rich cores in an Mg–6Zn–0.6Zr–0.5Cu alloy. Acta Mater. 60, 5615–5625 (2012).

    Article  CAS  Google Scholar 

  36. Y.M. Zhu, A.J. Morton, M. Weyland, and J.F. Nie: Characterization of planar features in Mg–Y–Zn alloys. Acta Mater. 58, 464–475 (2010).

    Article  CAS  Google Scholar 

  37. G. Atiya, M. Bamberger, and A. Katsman: Crystalline structure of metastable phases in Mg–Nd alloy containing Zn and Zr. Mater. Sci. Forum 690, 218–221 (2011).

    Article  CAS  Google Scholar 

  38. H. Liu, Y. Gao, J.Z. Liu, Y.M. Zhu, Y. Wang, and J.F. Nie: A simulation study of the shape of β′ precipitates in Mg–Y and Mg–Gd alloys. Acta Mater. 61, 453–466 (2013).

    Article  CAS  Google Scholar 

  39. Z. Liu, G. Wu, W. Liu, S. Pang, and W. Ding: Microstructure, mechanical properties and fracture behavior of peak-aged Mg–4Y–2Nd–1Gd alloys under different aging conditions. Mater. Sci. Eng., A 561, 303–311 (2013).

    Article  CAS  Google Scholar 

  40. J. Lee, K. Sato, T.J. Konno, and K. Hiraga: Stabilization of stacking faults and a long period stacking phase dispersed in α-Mg crystalline grains of Mg–0.7 at.% Zn–1.4 at.% Y alloy. Mater. Trans. 50, 222–225 (2009).

    Article  CAS  Google Scholar 

  41. B.L. Mordike: Creep-resistant magnesium alloys. Mater. Sci. Eng., A 324, 103–112 (2002).

    Article  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work is supported by National Key Research and Development Program of China (No. 2016YFB0301003); Shanghai Yang-fan Program (No. 14YF1402000), National Natural Science Foundation of China (No. 51404153); Research Program of Joint Research Center of Advanced Spaceflight Technologies (No. USCAST2015-25); and Science Innovation Foundation of Shanghai Academy of Spaceflight Technology (Nos. SAST2015047 and SAST2016048).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Liang Zhang.

Supplementary Material

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, H., Zhang, L., Wu, G. et al. Microstructure and mechanical properties of Mg–3.0Y–2.5Nd–1.0Gd–x Zn–0.5Zr alloys produced by metallic and sand mold casting. Journal of Materials Research 32, 3191–3201 (2017). https://doi.org/10.1557/jmr.2017.302

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2017.302

Navigation