Abstract
Microstructure and mechanical properties of Mg-0.43Nd-xY-0.08Zn-0.11Zr (x = 0, 0.03, 0.06, and 0.12 at.%) alloys were investigated. The results indicated that Mg24Y5 phase was formed in the as-cast Y-containing alloys, the grains were refined and the amount of needle-like Mg12Nd phase in the α-Mg grain interior was increased with increasing Y addition. After solution treatment, the Mg24Y5 phase and needle-like Mg12Nd phase nearly completely dissolved into the α-Mg matrix and long-rod-like Zn2Zr3 phase occurred. The amount of Zn2Zr3 phase was increased with increasing Y content after age treatment. Mg-0.43Nd-0.12Y-0.08Zn-0.11Zr alloy exhibited the best combination of strength and elongation in all conditions, especially in the temperature range of 200–300 °C, and an Arrhenius model was established to study the plastic flow behavior. The improvement in mechanical properties was attributed to the grain refining, solution strengthening and enhanced precipitation hardening of Zn2Zr3 phase and β-type phase.
Similar content being viewed by others
References
C. Antion, P. Donnadieu, F. Perrard, A. Deschampa, C. Tassin, and A. Pisch: Hardening precipitation in a Mg–4Y–3RE alloy. Acta Mater. 51, 5335 (2003).
L. Yuan, W.C. Shi, W.M. Jiang, Z. Zhao, and D.B. Shan: Effect of heat treatment on elevated temperature tensile and creep properties of the extruded Mg–6Gd–4Y–Nd–0.7Zr alloy. Mater. Sci. Eng., A 658, 339 (2016).
L. Zhang, J.H. Zhang, C. Xu, S.J. Liu, Y.F. Jiao, L.J. Xu, Y.B. Wang, J. Meng, R.Z. Wu, and M.L. Zhang: Investigation of high-strength and superplastic Mg–Y–Gd–Zn alloy. Mater. Des. 61, 168 (2014).
Y.L. Li, G.H. Wu, A.T. Chen, H.R.J. Nodooshan, W.C. Liu, Y.X. Wang, and W.J. Ding: Effects of Gd and Zr additions on the microstructures and high-temperature mechanical behavior of Mg–Gd–Y–Zr magnesium alloys in the product form of a large structural casting. J. Mater. Res. 30, 3461 (2015).
H.R.J. Nodooshan, W.C. Liu, G.H. Wu, W.J. Ding, and R. Mahmudi: Effect of Gd addition on the wear behavior of Mg–x Gd–3Y–0.5 Zr alloys. J. Mater. Res. 31, 1133 (2016).
H.Z. Li, F. Lv, X.P. Liang, Y.L. Qi, Z.X. Zhu, and K.L. Zhang: Effect of heat treatment on microstructures and mechanical properties of a cast Mg–Y–Nd–Zr alloy. Mater. Sci. Eng., A 667, 409 (2016).
Z.L. Ning, J.Y. Yi, M. Qian, H.C. Sun, F.Y. Cao, H.H. Liu, and J.F. Sun: Microstructure and elevated temperature mechanical and creep properties of Mg–4Y–3Nd–0.5Zr alloy in the product form of a large structural casting. Mater. Des. 60, 218 (2014).
P.H. Fu, L.M. Peng, H.Y. Jiang, J.W. Chang, and C.Q. Zhai: Effects of heat treatments on the microstructures and mechanical properties of Mg–3Nd–0.2Zn–0.4Zr (wt%) alloy. Mater. Sci. Eng., A 486, 183 (2008).
Z.M. Li, P.H. Fu, L.M. Peng, Y.X. Wang, H.Y. Jiang, and G.H. Wu: Comparison of high cycle fatigue behaviors of Mg–3Nd–0.2Zn–Zr alloy prepared by different casting processes. Mater. Sci. Eng., A 579, 170 (2013).
A. Sanaty-Zadeh, A.A. Luo, and D.S. Stone: Comprehensive study of phase transformation in age-hardening of Mg–3Nd–0.2Zn by means of scanning transmission electron microscopy. Acta Mater. 94, 294 (2015).
Z.J. Su, C.M. Liu, Y.C. Wang, and X. Shu: Effect of Y content on microstructure and mechanical properties of Mg–2.4Nd–0.2Zn–0.4Zr alloys. Mater. Sci. Technol. 29, 148 (2013).
G.S. Hu, B. Xing, F.L. Huang, M.P. Zhong, and D.F. Zhang: Effect of Y addition on the microstructures and mechanical properties of as-aged Mg–6Zn–1Mn–4Sn (wt%) alloy. J. Alloy Compd 689, 326 (2016).
J. Zhao, J. Zhang, W.C. Liu, G.H. Wu, and L. Zhang: Effect of Y content on microstructure and mechanical properties of as-cast Mg–8Li–3Al–2Zn alloy with duplex structure. Mater. Sci. Eng., A 650, 240 (2016).
J.H. Li, G. Sha, W.Q. Jie, and S.P. Ringer: Precipitation microstructure and their strengthening effects of an Mg–2.8Nd–0.6Zn–0.4Zr alloy with a 0.2 wt% Y addition. Mater. Sci. Eng., A 538, 272 (2012).
Z.M. Li, P.H. Fu, L.M. Peng, Y.X. Wang, and H.Y. Jiang: Strengthening mechanisms in solution treated Mg–y Nd–z Zn–x Zr alloy. J. Mater. Sci. 48, 6367 (2013).
R. Wilson, C.J. Bettles, B.C. Muddle, and J.F. Nie: Precipitation hardening in Mg–3 wt% Nd (–Zn) casting alloys. Mater. Sci. Forum 419, 267 (2003).
P.H. Fu, L.M. Peng, H.Y. Jiang, L. Ma, and C.Q. Zhai: Chemical composition optimization of gravity cast Mg–y Nd–x Zn–Zr alloy. Mater. Sci. Eng., A 496, 177 (2008).
J.F. Nie: Precipitation and hardening in magnesium alloys. Metall. Mater. Trans. A 43, 3891 (2012).
I. Toda-Caraballo, E.I. Galindo-Nava, and P.E.J. Rivera-Díaz-del-Castillo: Understanding the factors influencing yield strength on Mg alloys. Acta Mater. 75, 287 (2014).
R.L. Fleischer: Substitutional solution hardening. Acta Metall. Mater. 11, 203 (1963).
R. Labusch: A statistical theory of solid solution hardening. Phys. Status Solidi B 41, 659 (1970).
C. Do Lee: Effect of grain size on the tensile properties of magnesium alloy. Mater. Sci. Eng., A 459, 355 (2007).
L. Gao, R.S. Chen, and E.H. Han: Effects of rare-earth elements Gd and Y on the solid solution strengthening of Mg alloys. J. Alloy Compd. 481, 379 (2009).
A. Akhtar and E. Teghtsoonian: Substitutional solution hardening of magnesium single crystals. Philos. Mag. 25, 897 (1972).
S.J. Liu, G.Y. Yang, S.F. Luo, and W.Q. Jie: Microstructure evolution during heat treatment and mechanical properties of Mg–2.49Nd–1.82Gd–0.19Zn–0.4Zr cast alloy. Mater. Charact. 107, 334 (2015).
C.P. Tang, W.H. Liu, Y.Q. Chen, X. Liu, and Y.L. Deng: Effects of thermal treatment on microstructure and mechanical properties of a Mg–Gd-based alloy plate. Mater. Sci. Eng., A 659, 63 (2016).
H.Y. Yue, P.H. Fu, Z.M. Li, and L.M. Peng: Tensile crack initiation behavior of cast Mg–3Nd–0.2Zn–0.5Zr magnesium alloy. Mater. Sci. Eng., A 673, 458 (2016).
S.R. Agnew, M.G. Yoo, and C.N. Tome: Application of texture simulation to understanding mechanical behavior of Mg and solid solution alloys containing Li or Y. Acta Mater. 49, 4277 (2001).
X.W. Zheng, A.A. Luo, J. Dong, A.K. Sachdev, and W.J. Ding: Plastic flow behavior of a high-strength magnesium alloy NZ30K. Mater. Sci. Eng., A 532, 616 (2012).
H.R.J. Nodooshan, G.H. Wu, W.C. Liu, G.L. Wei, Y.L. Li, and S. Zhang: Effect of Gd content on high temperature mechanical properties of Mg–Gd–Y–Zr alloy. Mater. Sci. Eng., A 651, 840 (2016).
I.A. Maksoud, H. Ahmed, and J. Rödel: Investigation of the effect of strain rate and temperature on the deformability and microstructure evolution of AZ31 magnesium alloy. Mater. Sci. Eng., A 504, 40 (2009).
K. Hirai, H. Somekawa, Y. Takigawa, and K. Higashi: Effects of Ca and Sr addition on mechanical properties of a cast AZ91 magnesium alloy at room and elevated temperature. Mater. Sci. Eng., A 403, 276 (2005).
A. Galiyev, R. Kaibyshev, and G. Gottstein: Correlation of plastic deformation and dynamic recrystallization in magnesium alloy ZK60. Acta Mater. 49, 1199 (2001).
M.R. Barnett: Influence of deformation conditions and texture on the high temperature flow stress of magnesium AZ31. J. Light Met. 1, 167 (2001).
ACKNOWLEDGMENTS
This work is supported by National Key Research and Development Program of China (No. 2016YFB0701205), Science Innovation Foundation of Shanghai Academy of Spaceflight Technology (Nos. SAST2015047 and SAST2016048).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, Y., Wu, G., Liu, W. et al. Effects of minor Y addition on microstructure and mechanical properties of Mg-Nd-Zn-Zr alloy. Journal of Materials Research 32, 3712–3722 (2017). https://doi.org/10.1557/jmr.2017.277
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1557/jmr.2017.277