Titanium carbonitride (TiCN) is a popular hard coating for carbide cutting tools in various applications. This paper studied the influence of the carbon content and coating composition within TiCxN1−x coatings with regard to their adhesive strength on tungsten carbide substrate and subsequently, the performance of cutting tool in the dry turning of stainless steel. Among all the TiCxN1−x coatings, the TiCN coating has exhibited the highest adhesivity onto a substrate, followed by a TiC coating and lastly, a TiN coating. It was found that the adhesive strength of TiCN coating increased with the carbon content. The C/N ratio or C–N bond is a vital contributor to the adhesivity of the TiCxN1−x coating rather than the C or N atoms in the TiCxN1−x coating. It was found that the coating was delaminated before the exposure of substrate material. Hence, coating with higher adhesivity will promote longer tool life.
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J. Destefani: Cutting tools 101, Manufacturing Engineering, Society of Manufacturing Engineers (2002); p. 1.
L. Chen, S.Q. Wang, S.Z. Zhou, J. Li, and Y.Z. Zhang: Microstructure and mechanical properties of Ti(C,N) and TiN/Ti(C,N) multilayer PVD coatings. Int. J. Refract. Met. Hard Mater. 26 (5), 456 (2008).
S.J. Suresha, R. Bhide, V. Jayaram, and S.K. Biswas: Processing, microstructure and hardness of TiN/(Ti, Al)N multilayer coatings. Mater. Sci. Eng., A 429 (1–2), 252 (2006).
B. Navinšek, P. Panjan, and I. Milošev: Industrial applications of CrN (PVD) coatings, deposited at high and low temperatures. Surf. Coat. Technol. 97 (1–3), 182 (1997).
Y.H. Cheng, T. Browne, B. Heckerman, and E.I. Meletis: Influence of the C content on the mechanical and tribological properties of the TiCN coatings deposited by LAFAD technique. Surf. Coat. Technol. 205 (16), 4024 (2011).
S.J. Bull, D.G. Bhat, and M.H. Staia: Properties and performance of commercial TiCN coatings. Part 1: Coating architecture and hardness modelling. Surf. Coat. Technol. 163–164, 499 (2003).
W.Y.H. Liew and X. Ding: Wear progression of carbide tool in low-speed end milling of stainless steel. Wear 265 (1–2), 155 (2008).
R. Yigit, E. Celik, F. Findik, and S. Koksal: Tool life performance of multilayer hard coatings produced by HTCVD for machining of nodular cast iron. Int. J. Refract. Hard Met. 26 (6), 514 (2008).
P.C. Siow, J.A. Ghani, R.J. Talib, M.J. Ghazali, M.A. Selamat, and C.H. Che Haron: Characterization using XPS and XRD of Ti(C,N) coating properties for cutting tool applications. Interceram 64 (6), 287 (2015).
MicroMaterials: Nano-Scratch & Wear Catalogue (Micro Materials Ltd., Wrexham, 2013).
L. Karlsson, L. Hultman, M.P. Johansson, J.E. Sundgren, and H. Ljungcrantz: Growth, microstructure, and mechanical properties of arc evaporated TiCxN1−x (0 ≤ x ≤ 1) films. Surf. Coat. Technol. 126 (1), 1 (2000).
E. Lugscheider, C. Barimani, C. Wolff, S. Guerreiro, and G. Doepper: Comparison of the structure of PVD-thin films deposited with different deposition energies. Surf. Coat. Technol. 86, 177 (1996).
L. Karlsson, L. Hultman, and J.E. Sundgren: Influence of residual stresses on the mechanical properties of TiCxN1−x (x = 0, 0.15, 0.45) thin films deposited by arc evaporation. Thin Solid Films 371 (1–2), 167 (2000).
Y. Yang, W. Yao, and H. Zhang: Phase constituents and mechanical properties of laser in-situ synthesized TiCN/TiN composite coating on Ti–6Al–4V. Surf. Coat. Technol. 205 (2), 620 (2010).
E. Bemporad, C. Pecchio, S. De Rossi, and F. Carassiti: Characterization and hardness modelling of alternate TiN/TiCN multilayer cathodic arc PVD coating on tool steel. Surf. Coat. Technol. 146–147, 363 (2001).
K. Narasimhan, S.P. Boppana, and D.G. Bhat: Development of a graded TiCN coating for cemented carbide cutting tools—a design approach. Wear 188 (1–2), 123 (1995).
S.K. Khrais and Y.J. Lin: Wear mechanisms and tool performance of TiAlN PVD coated inserts during machining of AISI 4140 steel. Wear 262 (1–2), 64 (2007).
M.Y. Noordin, V.C. Venkatesh, and S. Sharif: Dry turning of tempered martensitic stainless tool steel using coated cermet and coated carbide tools. J. Mater. Process. Technol. 185 (1–3), 83 (2007).
A. Attanasio, D. Umbrello, C. Cappellini, G. Rotella, and R. M’Saoubi: Tool wear effects on white and dark layer formation in hard turning of AISI 52100 steel. Wear 286–287, 98 (2012).
J. Deng, J. Zhou, H. Zhang, and P. Yan: Wear mechanisms of cemented carbide tools in dry cutting of precipitation hardening semi-austenitic stainless steels. Wear 270 (7–8), 520 (2011).
Part of this paper was originally accepted for and presented at the MITC 2015. The authors would like to thank the government of Malaysia, Universiti Kebangsaan Malaysia, and Advanced Materials Research Center, SIRIM Berhad, for their support in terms of finances, manpower, and facilities.
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Siow, P.C., Abdul Ghani, J., Che Haron, C.H. et al. Effect of carbon content in TiCxN1−x coating on the adhesivity of carbide cutting tools and machining performance. Journal of Materials Research 31, 1880–1884 (2016). https://doi.org/10.1557/jmr.2016.16