Unusual dry sliding tribological behavior of biomedical ultrafine-grained TiNbZrTaFe composites fabricated by powder metallurgy


Tribological behavior of biomedical ultrafine-grained (UFGed) TiNbZrTaFe (TNZTF) composites fabricated by powder metallurgy was investigated under dry wear condition. Results show that compared with two kinds of conventional biomedical Ti–6Al–4V (TAV) and Ti–13Nb–13Zr (TNZ) alloys, the wear loss of the TNZTF samples is only 3.5% and 1% of that of the TAV and TNZ samples, respectively. Unusual tribological behavior is that the wear loss of the TNZTF samples decreases with the increase in sliding speed at the same load. This is attributed to the formation of a large amount of hard Nb2O5 particles on the contact surface of the material during rubbing and more severe plastic deformation in the material layers adjacent to the contact surfaces. The wear mechanism of the three kinds of alloys was also investigated. The outstanding tribological property proves that the UFGed TNZTF alloys should be an excellent candidate material to be used for biomedical application in the future.

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  1. 1.

    M. Geetha, A.K. Singh, R. Asokamani, and A.K. Gogia: Ti based biomaterials, the ultimate choice for orthopaedic implants — A review. Prog. Mater. Sci. 54, 397 (2009).

    CAS  Article  Google Scholar 

  2. 2.

    M. Niinomi: Recent metallic materials for biomedical applications. Metall. Mater. Trans. A 33, 477 (2002).

    Article  Google Scholar 

  3. 3.

    B.J.K. Matej, J.J. Mark, and A. Waqar: Titanium and titanium alloy applications in medicine. Int. J. Nano Biomater. 1, 3 (2007).

    Article  Google Scholar 

  4. 4.

    L. Marc and H.J. Rack: Titanium alloys in total joint replacement–A materials science perspective. Biomaterials 19, 1621 (1998).

    Article  Google Scholar 

  5. 5.

    G. He and M. Hagiwara: Ti alloy design strategy for biomedical applications. Mater. Sci. Eng., C 26, 14 (2006).

    CAS  Article  Google Scholar 

  6. 6.

    D. Rodriguez, F.J. Gil, and J.A. Planell: Wear resistance of the nitrogen diffusion hardening of the Ti-6Al-4V alloy. J. Biomech. 31, 49 (1998).

    Article  Google Scholar 

  7. 7.

    S. Sathish, M. Geetha, N.D. Pandey, C. Richard, and R. Asokamani: Studies on the corrosion and wear behavior of the laser nitrided biomedical titanium and its alloys. Mater. Sci. Eng., C 30, 376 (2010).

    CAS  Article  Google Scholar 

  8. 8.

    A. Choubey, B. Basu, and R. Balasubramaniam: Tribological behaviour of Ti-based alloys in simulated body fluid solution at fretting contacts. Mater. Sci. Eng., A 379, 234 (2004).

    Article  Google Scholar 

  9. 9.

    S.J. Li, R. Yang, S. Li, Y.L. Hao, Y.Y. Cui, M. Niinomi, and Z.X. Guo: Wear characteristics of Ti-Nb-Ta-Zr and Ti-6Al-4V alloys for biomedical applications. Wear 257, 869 (2004).

    CAS  Article  Google Scholar 

  10. 10.

    Y.Y. Li, L.M. Zou, C. Yang, Y.H. Li, and L.J. Li: Ultrafine-grained Ti-based composites with high strength and low modulus fabricated by spark plasma sintering. Mater. Sci. Eng., A 560, 857 (2013).

    CAS  Article  Google Scholar 

  11. 11.

    T.J. Webster and J.U. Ejiofor: Increased osteoblast adhesion on nanophase metals: Ti, Ti6Al4V, and CoCrMo. Biomaterials 25, 4731 (2004).

    CAS  Article  Google Scholar 

  12. 12.

    L.M. Zou, C. Yang, Y. Long, Z.Y. Xiao, and Y.Y. Li: Fabrication of biomedical Ti-35Nb-7Zr-5Ta alloys by mechanical alloying and spark plasma sintering. Powder Metall. 55, 65 (2012).

    CAS  Article  Google Scholar 

  13. 13.

    Y.Y. Li, C. Yang, W.P. Chen, and X.Q. Li: Effect of WC content on glass formation, thermal stability and phase evolution of a TiNbCuNiAl alloy synthesized by mechanical alloying. J. Mater. Res. 23, 745 (2008).

    Article  Google Scholar 

  14. 14.

    Y.Y. Li, C. Yang, W.P. Chen, X.Q. Li, and S.G. Qu: Ultrafine-grained Ti66Nb13Cu8Ni6.8Al6.2 composites fabricated by spark plasma sintering and crystallization of amorphous phase. J. Mater. Res. 24, 2118 (2009).

    CAS  Article  Google Scholar 

  15. 15.

    Y.Y. Li, C. Yang, W.P. Chen, X.Q. Li, and M. Zhu: Oxygen-induced amorphization of metallic titanium by ball milling. J. Mater. Res. 22, 1927 (2007).

    CAS  Article  Google Scholar 

  16. 16.

    I. Cvijović-Alagić, Z. Cvijović, S. Mitrović, M. Rakin, Đ. Veljović, and M. Babic: Tribological behaviour of orthopaedic Ti-13Nb-13Zr and Ti-6Al-4V alloys. Tribol. Lett. 40, 59 (2010).

    Article  Google Scholar 

  17. 17.

    Y.Y. Li, C. Yang, S.G. Qu, X.Q. Li, and W.P. Chen: Nucleation and growth mechanism of crystalline phase for fabrication of ultrafine-grained Ti66Nb13Cu8Ni6.8Al6.2 composites by spark plasma sintering and crystallization of amorphous phase. Mater. Sci. Eng., A 528, 486 (2010).

    Article  Google Scholar 

  18. 18.

    I. Cvijović-Alagić, Z. Cvijović, S. Mitrović, V. Panić, and M. Rakin: Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution. Corros. Sci. 53, 796 (2011).

    Article  Google Scholar 

  19. 19.

    J.F. Archard: Contact, and rubbing of flat surfaces. J. Appl. Phys. 24, 981 (1953).

    Article  Google Scholar 

  20. 20.

    H.D. Li and J.M. Xiao: Surface and Interface of Materials (Tsinghua University Press, Beijing, 1990).

    Google Scholar 

  21. 21.

    A. Molinari, G. Straffelini, B. Tesi, and T. Bacci: Dry sliding wear mechanisms of the Ti6Al4V alloy. Wear 208, 105 (1997).

    CAS  Article  Google Scholar 

  22. 22.

    G. Straffelini and A. Molinari: Dry sliding wear of Ti-6Al-4V alloy as influenced by the counterface and sliding conditions. Wear 236, 328 (1999).

    CAS  Article  Google Scholar 

  23. 23.

    T. John and J. Burwell: Survey of possible wear mechanisms. Wear 1, 119 (1957).

    Article  Google Scholar 

  24. 24.

    M. Long and H.J. Rack: Ultrasonic in situ continuous wear measurements of orthopaedic titanium alloys. Wear 205, 130 (1997).

    CAS  Article  Google Scholar 

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This work was supported by the Guangdong Natural Science Foundation (No. S2013010012147), the Science and Technology Innovation Project of Higher School of Guangdong Province (No. 2012KJCX0010), the Fundamental Research Funds for the Central Universities (No. 2013ZZ0008), the Program for New Century Excellent Talents in University (No. NCET-11-0163), and open fund from National Engineering Research Center of Near-net-shape Forming for Metallic Materials (No. 2013007).

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Correspondence to Chao Yang.

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Zou, L., Zhou, L., Yang, C. et al. Unusual dry sliding tribological behavior of biomedical ultrafine-grained TiNbZrTaFe composites fabricated by powder metallurgy. Journal of Materials Research 29, 902–909 (2014). https://doi.org/10.1557/jmr.2014.58

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