Abstract
Ni–base alloy coatings were fabricated on 45 steel by laser cladding using a CW-CO2 laser system. The microstructure of the coatings was analyzed using optical microscope (OM), scanning electronic microscope (SEM), and x-ray diffractometer (XRD). The phase fractions, phase compositions, and solidification process in the coatings were calculated using Thermo-Calc software and compared with experimental results. The results show that a dense crack- and porous-free coating with good metallurgical bond is obtained under optimal process parameters. The coatings can be divided into three regions: clad zone (CZ), bonding zone, and heat-affected zone of the substrate. The CZ consists of γ-Ni, M7C3, CrB, and Ni3B phases. Based on the calculated results, the solidification process and reaction scheme in the coatings were discussed. The calculated results obtained from Thermo-Calc software agree with the experimental data well. It is beneficial to the coating design for a desirable microstructure and mechanical properties.
This is a preview of subscription content, access via your institution.








References
- 1.
M. Yan and W-Z. Zhu: Surface treatment of 45 steel by plasma-arc melting. Surf. Coat. Technol. 91, 183 (1997).
- 2.
S. Yang, N. Chen, W-J. Liu, M-L. Zhong, Z-J. Wang, and H. Kokawa: Fabrication of nickel composite coatings reinforced with TiC particles by laser cladding. Surf. Coat. Technol. 183, 254 (2004).
- 3.
S-L. Ma, Y-H. Li, and K-W. Xu: The composite of nitrided steel of H13 and TiN coatings by plasma duplex treatment and the effect of pre-nitriding. Surf. Coat. Technol. 137, 116 (2001).
- 4.
M. Zlatanovic, T. Gredic, A. Kunosic, N. Backovic, and N. Whittle: Substrate-induced changes of TiN and (Ti, Al)N coatings due to plasma nitriding. Surf. Coat. Technol. 63, 35 (1994).
- 5.
Y-W. Lei, R-L. Sun, J-B. Lei, Y. Tang, and W. Niu: A new theoretical model for high power laser clad TiC/NiCrBSiC composite coatings on Ti6Al4V alloys. Opt. Lasers Eng. 48, 899 (2010).
- 6.
Y-T. Pei and T-C. Zuo: Gradient microstructure in laser clad TiC-reinforced Ni-alloy composite coating. Mater. Sci. Eng., A 241, 259 (1998).
- 7.
D-W. Zhang, T. Li, and T-C. Lei: Laser cladding of Ni-Cr3C2/(Ni+Cr) composite coating. Surf. Coat. Technol. 110, 81 (1998).
- 8.
D-W. Zhang, T-C. Lei, and F-J. Li: Laser cladding of stainless steel with Ni-Cr3C2 for improved wear performance. Wear 251, 1372 (2001).
- 9.
Q. Li, T-C. Lei, and W-Z. Chen: Microstructural characterization of laser-clad TiCp-reinforced Ni-Cr-B-Si-C composite coatings on steel. Surf. Coat. Technol. 114, 278 (1999).
- 10.
M-J. Tobar, C. Álvarez, J-M. Amado, G. Rodríguez, and A. Yáñez: Morphology and characterization of laser clad composite NiCrBSi-WC coatings on stainless steel. Surf. Coat. Technol. 200, 6313 (2006).
- 11.
R-L. Sun, Y-S. Wang, Y. Tang, and X-C. Yang: Microstructure and microhardness of NiCrBSi alloy laser cladding layer on 45 steel substrate. Tianjin Gongye Daxue Xuebao 22, 79 (2003).
- 12.
K-F. Tam, F-T. Cheng, and H-C. Man: Cavitation erosion behavior of laser-clad Ni-Cr-Fe-WC on brass. Mater. Res. Bull. 37, 1341 (2002).
- 13.
A. Viswanathan, D. Sastikumar, P. Rajarajan, H. Kumar, and A-K. Nath: Laser irradiation of AISI 316L stainless steel coated with Si3N4 and Ti. Opt. Laser Technol. 39, 1504 (2007).
- 14.
Y. Chen and H-M. Wang: Growth morphology and mechanism of primary TiC carbide in laser clad TiC/FeAl composite coating. Mater. Lett. 57, 1233 (2003).
- 15.
B. Sundman, B. Jansson, and J-O. Andersson: The thermo-calc databank system. Calphad 9, 153 (1985).
- 16.
M. Hillert and L.I. Staffansson: Regular solution model for stoi-chiometric phases and ionic. Melts. Acta Chem. Scand. 24, 3618 (1970).
- 17.
S-L. Hu, Y. Guo, Y-G. Dong, J-L. Yang, J. Liu, and S-R. Cao: Understanding the effects of the structures on the energy gaps in carbon nanoparticles from laser synthesis. J. Mater. Chem. 22, 12053 (2012).
- 18.
S-L. Hu, F. Tian, P-K. Bai, S-R. Cao, J. Sun, and J. Yang: Synthesis and luminescence of nanodiamonds from carbon black. Mater. Sci. Eng., B 157, 11 (2009).
ACKNOWLEDGMENTS
The authors would like to thank the financial support provided by Tianjin Research Program of Application Foundation and Advanced Technology (Grant No. 11JCZDJC21400) and the Ph.D. Programs Foundation of Ministry of Education of China (Grant No. 20091201110002).
Author information
Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lei, Y., Sun, R. & Tang, Y. Thermodynamic modeling and experimental study on the microstructure of laser clad Ni–base alloy coatings on 45 steel. Journal of Materials Research 28, 1189–1195 (2013). https://doi.org/10.1557/jmr.2013.68
Received:
Accepted:
Published:
Issue Date: