Adhesion, microstrain, and corrosion behavior of ZrN-coated AZ91 alloy as a function of temperature

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In this study, nanocrystalline ZrN films were successfully deposited onto AZ91 alloy using an ion beam sputtering method at substrate temperatures of 373–673 K. Strain and adhesion were calculated using the classic Williamson–Hall and indentation cracking methods, respectively. Microstructure and crystalline properties were evaluated using scanning electron microscopy and x-ray diffraction. XRD results showed that the crystallographic properties of the films were strongly dependent upon substrate temperature. An increase in temperature increased adhesion of the film to the AZ91 alloy and decreased film microstrain. The corrosion behavior of ZrN/AZ91 samples in Ringer’s solution was studied to evaluate corrosion potential and corrosion current density. Potentiodynamic corrosion tests showed that all ZrN-coated samples had a corrosion resistance superior to the blank substrate, mainly at 400 °C. A correlation was also established between vacancy defects in the film and corrosion behavior.

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FIG. 5.
FIG. 6.
FIG. 7.
FIG. 8.
FIG. 9.
FIG. 10.

Change history


  1. 1.

    H. Jiménez, E. Restrepo, and A. Devia: Effect of the substrate temperature in ZrN coatings grown by the pulsed arc technique studied by XRD. Surf. Coat. Technol. 201, 1594 (2006).

    Article  Google Scholar 

  2. 2.

    M.M. Larijani, M. Elmi, M. Yari, M. Ghoranneviss, P. Balashabadi, and A. Shokouhy: Nitrogen effect on corrosion resistance of ion beam sputtered nanocrystalline zirconium nitride films. Surf. Coat. Technol. 203, 2591 (2009).

    CAS  Article  Google Scholar 

  3. 3.

    Z. Qi, R. Huang, F. Zhu, P. Sun, and Z. Wang: Effect of substrate temperature on structure and mechanical properties of ZrN coatings. Adv. Mater. Res. 154–155, 1664 (2011).

    Google Scholar 

  4. 4.

    H. Altun and H. Sinici: Corrosion behaviour of magnesium alloys coated with TiN by cathodic arc deposition in NaCl and Na2SO4 solutions. Mater. Charact. 59, 266 (2008).

    CAS  Article  Google Scholar 

  5. 5.

    W. Guo-Song, W. Ai-Ying, D. Ke-Jia, X. Cai-Yun, D. Wei, and X. Ai-Jiao: Fabrication of Cr coating on AZ31 magnesium alloy by magnetron sputtering. Trans. Nonferrous Met. Soc. China 18, 329 (2008).

    Article  Google Scholar 

  6. 6.

    C. Wen, S. Guan, L. Peng, C. Ren, X. Wang, and Z. Hu: Characterization and degradation behavior of AZ31 alloy surface modified by bone-like hydroxyapatite for implant applications. Appl. Surf. Sci. 255, 6433 (2009).

    CAS  Article  Google Scholar 

  7. 7.

    H. Altun and S. Sen: The effect of DC magnetron sputtering AlN coatings on the corrosion behaviour of magnesium alloys. Surf. Coat. Technol. 197, 193 (2005).

    CAS  Article  Google Scholar 

  8. 8.

    J. Takadoum and H.H. Bennani: Influence of substrate roughness and coating thickness on adhesion, friction and wear of TiN films. Surf. Coat. Technol. 96, 272 (1997).

    CAS  Article  Google Scholar 

  9. 9.

    L. Chang-Hao and M. Zhan-Qi: Effects of different simulated fluids on anticorrosion biometallic materials. Trans. Nonferrous Met. Soc. China 11, 579 (2001).

    Google Scholar 

  10. 10.

    J. Kim, J. Jeong, K. Lee, and D. Kwona: A new indentation cracking method for evaluating interfacial adhesion energy of hard films. Thin Solid Films 441, 172 (2003).

    CAS  Article  Google Scholar 

  11. 11.

    M. Nesladek, K. Vandierendonck, C. Quaeyhaegens, M. Kerkhofs, and M. Stals: Adhesion of diamond coatings on cemented carbides. Thin Solid Films 270, 184 (1995).

    CAS  Article  Google Scholar 

  12. 12.

    C.C. Ting, S.Y. Chen, and D.M.L. Liu: Preferential growth of thin rutile TiO2 films upon thermal oxidation of sputtered Ti films. Thin Solid Films 402, 290 (2002).

    CAS  Article  Google Scholar 

  13. 13.

    P. Barna and M. Adamik: Fundamental structure forming phenomena of polycrystalline films and the structure zone models. Thin Solid Films 317, 27 (1998).

    CAS  Article  Google Scholar 

  14. 14.

    B.E. Aufderheide: Sputtered Thin Film Coatings, 3rd ed. (Taylor & Francis, New Jersey, 2005), pp. 30–31.

    Google Scholar 

  15. 15.

    D.K. Lee, J.J.L. Lee, and J. Joo: Low temperature TiN deposition by ICP-assisted chemical vapor deposition. Surf. Coat. Technol. 173–174, 1234 (2003).

    Article  Google Scholar 

  16. 16.

    M. Kalita, K. Deka, J. Das, N. Hazarika, P. Dey, R. Das, S. Paul, T. Sarmah, and B. Sarma: X-ray diffraction line profile analysis of chemically synthesized lead sulphide nanocrystals. Mater. Lett. 87, 84 (2012).

    CAS  Article  Google Scholar 

  17. 17.

    D. Sciti, G. Celotti, G. Pezzoti, and S. Guiccardi: On the toughening mechanisms of MoSi2 reinforced Si3N4 ceramics. Appl. Phys. A 86, 243 (2007).

    CAS  Article  Google Scholar 

  18. 18.

    Y. Zhang and Y-P. Zhao: Applicability range of Stoney’s formula and modified formulas for a film/substrate bilayer. J. Appl. Phys. 99, 053513–1 (2006).

    Article  Google Scholar 

  19. 19.

    Y-P. Zhao, L.S. Wang, and T.X. Yu: Mechanics of adhesion in MEMS — a review. J. Adhes. Sci. Technol. 17, 519 (2003).

    CAS  Article  Google Scholar 

  20. 20.

    K. Pulker, A.J. Perry, and R. Berger: Adhes. Surf. Coat. Technol. 14, 25 (1981).

    CAS  Article  Google Scholar 

  21. 21.

    H. Altun and S. Sen: The effect of PVD coatings on the corrosion behaviour of AZ91 magnesium alloy. Mater. Des. 27, 1174 (2006).

    CAS  Article  Google Scholar 

  22. 22.

    K. Gruss and R. Davis: Adhesion measurement of zirconium nitride and amorphous silicon carbide coatings to nickel and titanium alloys. Surf. Coat. Technol. 114, 156, (1999).

    CAS  Article  Google Scholar 

  23. 23.

    J.H. Huang, Z.E. Tsa, and G.P. Yu: Mechanical properties and corrosion resistance of nanocrystalline ZrNxOy coatings on AISI304 stainless steel by ion plating. Surf. Coat. Technol. 202, 4992 (2008).

    CAS  Article  Google Scholar 

  24. 24.

    K. Schlüter, C. Zamponi, A. Piorra, and E. Quandt: Comparison of the corrosion behaviour of bulk and thin film magnesium alloys. Corros. Sci. 52, 3973 (2010).

    Article  Google Scholar 

  25. 25.

    A. Afshar, M. Yari, M. Larijani, and M. Eshghabadi: Effect of substrate temperature on structural properties and corrosion resistance of carbon thin films used as bipolar plates in polymer electrolyte membrane fuel cells. J. Alloys Compd. 502, 451 (2010).

    CAS  Article  Google Scholar 

  26. 26.

    W.J. Chou, G.P. Yu, and J.H. Huang: Corrosion resistance of ZrN films on AISI 304 stainless steel substrate. Surf. Coat. Technol. 167, 59 (2003).

    CAS  Article  Google Scholar 

  27. 27.

    D. Roman, J. Bernardi, C.L.G.D. Amorim, F.S.D. Souza, A. Spinelli, C. Giacomelli, C.A. Figueroa, I.J.R. Baumvol, and R.L.O. Basso: Effect of deposition temperature on microstructure and corrosion resistance of ZrN thin films deposited by DC reactive magnetron sputtering. Mater. Chem. Phys. 130, 147 (2011).

    CAS  Article  Google Scholar 

  28. 28.

    S. Simonetti, D.R. Saravia, G. Brizuela, and A. Juan: The effects of a hydrogen pair in the electronic structure of the FCC iron containing a vacancy. Int. J. Hydrogen Energy 35, 5957 (2010).

    CAS  Article  Google Scholar 

  29. 29.

    Z. Jiang, X. Dai, T. Norby, and H. Middleton: Investigation of pitting resistance of titanium based on a modified point defect model. Corros. Sci. 53, 815 (2011).

    CAS  Article  Google Scholar 

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Correspondence to Seyed Rahim Kiahosseini.

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Kiahosseini, S.R., Afshar, A., Larijani, M.M. et al. Adhesion, microstrain, and corrosion behavior of ZrN-coated AZ91 alloy as a function of temperature. Journal of Materials Research 28, 2709–2714 (2013).

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