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Effects of high-temperature ambient on cyclic fatigue of La0.8Sr0.2MnO3+δ

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Abstract

The effects of water vapor and oxygen on the cyclic fatigue behavior of oxygen-excess La0.8Sr0.2MnO3+δ (LSM) were investigated under three-point bending at 1273 K. Because the fatigue life did not obviously depend on the number of cycles, which also represented the effective time of the applied stress, the fracture was presumed to not be significantly controlled by stress-corrosion cracking. Under a low oxygen partial pressure (PO2), however, wet exposure inhibited both fatigue fracture and permanent deformation, in which the LSM crystal lattice was distorted and the unit cell free volume was reduced. Under a high PO2, on the contrary, the crystal symmetry was increased by the wet exposure. The inhibition of fatigue fracture and deformation at both high PH2O and low PO2 was probably caused by retardation of lanthanum diffusion through its vacancies.

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Acknowledgments

This work was supported by the Ministry of Education, Culture, Sports, Science and Technology, Regional Innovation Cluster Program (City-area type) for Western Tono area in Gifu prefecture. The authors are grateful to Professor J. Mizusaki, Tohoku University, Japan, for valuable discussions and advice during the course of this research.

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  1. Japan Fine Ceramics Center, Atsuta-ku, Nagoya, 456-8587, Japan

    Makoto Tanaka, Tsuneaki Matsudaira, Daisuke Igimi & Satoshi Kitaoka

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  1. Makoto Tanaka
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  2. Tsuneaki Matsudaira
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Correspondence to Makoto Tanaka.

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Tanaka, M., Matsudaira, T., Igimi, D. et al. Effects of high-temperature ambient on cyclic fatigue of La0.8Sr0.2MnO3+δ. Journal of Materials Research 26, 2450–2457 (2011). https://doi.org/10.1557/jmr.2011.199

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