Skip to main content
Log in

Formation of interfacial η’-Cu6Sn5 in Sn–0.7Cu/Cu solder joints during isothermal aging

  • Materials Communication
  • Published:
Journal of Materials Research Aims and scope Submit manuscript

An Erratum to this article was published on 01 July 2011

This article has been updated

Abstract

The formation of interfacial η’-Cu6Sn5 in Sn–0.7Cu/Cu solder joints at different aging temperatures was studied using x-ray diffraction (XRD). The time-temperature-formation curve was obtained and is discussed based on the phase transformation from existing η-Cu6Sn5 and interfacial reaction at temperatures below 186 °C. A minimum formation time was observed in the temperature range of 135–150 °C.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

FIG. 1
FIG. 2
FIG. 3
FIG. 4

Similar content being viewed by others

Change history

References

  1. T. Laurila, V. Vuorinen, and J.K. Kivilahti: Interfacial reactions between lead-free solders and common base materials. Mater. Sci. Eng., R 49, 1 (2005).

    Article  Google Scholar 

  2. J.M. Tarascon and M. Armand: Issues and challenges facing rechargeable lithium batteries. Nature 414, 359 (2001).

    Article  CAS  Google Scholar 

  3. A.K. Larsson, L. Stenberg, and S. Lidin: The superstrusture of domain-twinned ?’-Cu6Sn5. Acta Crystallogr. B 50, 636 (1994).

    Article  Google Scholar 

  4. A.K. Larsson, L. Stenberg, and S. Lidin: Crystal structure modulations in ?-Cu5Sn4. Z. Kristallogr. 210, 832 (1995).

    CAS  Google Scholar 

  5. S. Lidin and A.K. Larsson: A survey of superstructures in intermetallic NiAs-Ni2In-type phases. J. Solid State Chem. 118, 313 (1995).

    Article  CAS  Google Scholar 

  6. A. Gangulee, G.C. Das, and M.B. Bever: An x-ray diffraction and calorimetric investigation of the compound Cu6Sn5. Metall. Trans. 4, 2063 (1973).

    Article  CAS  Google Scholar 

  7. G. Ghosh and M. Asta: Phase stability, phase transformations, and elastic properties of Cu6Sn5: Ab initio calculations and experimental results. J. Mater. Res. 20, 3102 (2005).

    Article  CAS  Google Scholar 

  8. K. Nogita, C.M. Gourlay, and T. Nishimura: Cracking and phase stability in reaction layers between Sn-Cu-Ni solders and Cu substrates. J. Miner. Met. Mater. Soc. 61, 45 (2009).

    Article  CAS  Google Scholar 

  9. U. Schwingenschlögl, C.D. Paola, K. Nogita, and C.M. Gourlay: The influence of Ni additions on the relative stability of η and η’ Cu6Sn5. Appl. Phys. Lett. 96, 061908 (2010).

    Article  Google Scholar 

  10. A. Savitzky and M.J.E. Golay: Smoothing and differentiation of data by simplified least squares procedures. Anal. Chem. 36, 1627 (1964).

    Article  CAS  Google Scholar 

  11. J.W. Christian: The Theory of Transformations in Metals and Alloys, 2nd ed. (Elsevier Science, Oxford, UK, 2002), pp. 11, 16, 532, 702–709.

    Book  Google Scholar 

Download references

Acknowledgment

The authors thank Prof. J.S. Zhang, Y.N. Wang, F. Ye, and Dr. L.J. Luo for their warm and sincere help.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jie Zhao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Luo, Z., Wang, L., Fu, Q. et al. Formation of interfacial η’-Cu6Sn5 in Sn–0.7Cu/Cu solder joints during isothermal aging. Journal of Materials Research 26, 1468–1471 (2011). https://doi.org/10.1557/jmr.2011.179

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/jmr.2011.179

Navigation