B and P Glass Formers as Stabilizers of Luminescent Ce(III) in Silica-Based Glasses


Ce3+-doped boro, phospho and borophosphosilicate monolithic glasses (BSG, PSG and BPSG) were prepared by sol-gel method. The inclusion of the glass formers P and B in silica lowered the tendency of rare earth (RE) to segregate as CeO2 with respect to pure SiO2 matrix (SG). In PSG and BPSG, Ce3+ co-ordination to P=O groups was responsible for the inhibition of both CeO2 segregation and oxidation of isolated Ce3+ ions to Ce4+. The better ion dispersion in the host matrix and the stabilization of Ce3+ oxidation state improved PSG and BPSG luminescence properties with respect to BSG and SG.

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  1. 1.

    van Loaf E.V.D.; Doorknobs P.; Van Eijk C.W.E.; Kramer K.; Guide H.U. Appl.Phys.Lett., 2000, 77, 1467

    Article  Google Scholar 

  2. 2.

    van Loef E.V.D.; Dorenbos P.; Van Eijk C.W.E.; Krämer K.; Güdel H.U. Appl.Phys.Lett., 2001, 79, 1573

    Article  Google Scholar 

  3. 3.

    F. Auzel, P. Goldner, Opt. Mater., 2001, 16, 93

    CAS  Article  Google Scholar 

  4. 4.

    G. Blasse, B.C. Grabmeier, Luminescent Materials, Springer Verlag, Berlin, 1994

    Google Scholar 

  5. 5.

    E. Auffray, D. Bouttet, I. Dafinei, J. Fay, P. Lecoq, J.A. Mares, M. Martini, G. Mazé, F. Meinardi, B. Moine, M. Nikl, C. Pedrini, M. Poulain, M. Schneegans, S. Tavernier, A. Vedda, Nucl. Instr. And Meth. A, 1996, 380, 524

    CAS  Article  Google Scholar 

  6. 6.

    C. Dujardin, C. Pedrini, M. Moysan, J.Y. Carreé, G. Mazé, J. Jiary, G. Zhang, M. Poulain, Proceedings of the International Conference on Inorganic Scintillators and their Applications (SCINT '97), Y. Zhiwen, L. Pejun, F. Xigi, X. Zhilin (Eds.), Shangai, R.P. China, September, 22-25 1997, CAS Shangai Branch Press, Shangai, 1997, p. 37

  7. 7.

    R. Reisfeld, A. Patra, G. Panczer, M. Gaft, Opt.Mater., 1999, 13, 81

    CAS  Article  Google Scholar 

  8. 8.

    K. Itoh, N. Kamata, T. Shimazu, C. Satoh, K. Tonooka, K. Yamada, J.Lumin., 2000, 87-89, 676

    Article  Google Scholar 

  9. 9.

    A. Vedda, A. Baraldi, C. Canevali, R. Capelletti, N. Chiodini, R. Francini, M. Martini, F. Morazzoni, M. Nikl, R. Scotti, G. Spinolo, Nucl.Instr.and Meth. A, 2002, 486, 259

    CAS  Article  Google Scholar 

  10. 10.

    N. Chiodini, M. Fasoli, M. Martini, F. Morazzoni, E. Rosetta, R. Scotti, G. Spinolo, A. Vedda, M. Nikl, N. Solovieva, A. Baraldi, R. Capelletti, R. Francini, Radiat. Eff. Defects Solids 2003, 158, 463

    CAS  Article  Google Scholar 

  11. 11.

    A. Baraldi, R. Capelletti, N. Chiodini, C. Mora, R. Scotti, E. Uccellini, A. Vedda, Nucl.Instr.and Meth. A, 2002, 486, 408

    CAS  Article  Google Scholar 

  12. 12.

    D. Di Martino, A. Vedda, G.Angella, M. Catti, E. Cazzini, N. Chiodini, F. Morazzoni, G. Spinolo, Chem. Mat. 2004, 16, 3352

    Article  Google Scholar 

  13. 13.

    J.Y. Kim, P.N. Kumpta, J.Phys.Chem. B, 1998, 102, 5744

    CAS  Article  Google Scholar 

  14. 14.

    C. Canevali, R. Scotti, A. Vedda, M. Mattoni, F. Morazzoni, L. Armelao, D. Barreca, G. Bottaro, Chem. Mat., 2004, 16, 315

    CAS  Article  Google Scholar 

  15. 15.

    M. Yamaga, M. Honda, K. Shimamura, T. Fukuda, T. Yonda, J.Phys.Cond.Matter 2000, 12, 5917

    CAS  Article  Google Scholar 

  16. 16.

    S.K. Misra, S. Isher, Physica B, 1998, 253, 111

    CAS  Article  Google Scholar 

  17. 17.

    S M. Nikl, K. Nitsch, E. Mihokova, N. Solovieva, J.A. Mares, P. Fabeni, G.P. Pazzi, M. Martini, A. Vedda, S. Baccaro, App. Phys. Lett., 2000, 77, 2159

    CAS  Article  Google Scholar 

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The Authors thank MIUR (PRIN 2003) for the financial support

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Canevali, C., Mattoni, M., Morazzoni, F. et al. B and P Glass Formers as Stabilizers of Luminescent Ce(III) in Silica-Based Glasses. MRS Online Proceedings Library 847, 12–17 (2004). https://doi.org/10.1557/PROC-847-EE13.41

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