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Application of SAS to Bulk Amorphous Polymers, Block Copolymers and Polymer Blends

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This article discusses the application of small-angle neutron and X-ray scattering techniques to the study of bulk amorphous polymers, block copolymers and polymer blends. The subject matter discussed include density fluctuation in single component amorphous polymers, concentration fluctuation in compatible polymer blends and its interpretation in terms of the random phase approximation theory, analysis of the scattering from incompatible polymer blends as developed by Porod, determination of the phase boundary thickness, order-disorder transition in block copolymer, interpretation of the scattering from disordered block copolymer systems by means of the random phase approximation theory, characterization of ordered block copolymer structure, and the study of block copolymer micelles.

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References

  1. W. Ruland, Prog. Colloid Polymer Sci. 57, 192 (1975).

    Article  CAS  Google Scholar 

  2. J. H. Wendorff and Ε. W. Fischer, Kolloid Ζ. Ζ. Polym. 251, 876, 884 (1973).

    Article  CAS  Google Scholar 

  3. J. Rathje and W. Ruland, Colloid Polymer Sci. 254, 358 (1976).

    Article  CAS  Google Scholar 

  4. R. J. Roe and J. J. Curro, Macromolecules 16, 428 (1983).

    Article  CAS  Google Scholar 

  5. R. J. Roe and H. H. Song, manuscript in preparation. See also H. H. Song, Ph.D. Dissertation, university of Cincinnati, 1986.

  6. P.-G. de Gennes, J. Phys. (Paris) 31, 235 (1970).

    Article  Google Scholar 

  7. P.-G. de Gennes, Scaling Concepts in Polymer Physics (Cornell university Press, Ithaca, NY, 1979), p. 109.

    Google Scholar 

  8. G. Porod, Kolloid Z. 124, 83 (1951).

    Article  CAS  Google Scholar 

  9. W. Ruland, J. Appl. Cryst. 4, 70 (1971).

    Article  Google Scholar 

  10. R. J. Roe, J. Appl. Cryst. 15, 182 (1982).

    Article  CAS  Google Scholar 

  11. L. Leibler, Macromoleculee 13, 1602 (1980).

    Article  CAS  Google Scholar 

  12. M. O. de la Cruz and I. C. Sanchez, Macromoleculee 19, 2501 (1986).

    Article  Google Scholar 

  13. A. Guinier, X-Rav Diffraction in Crystals, Imperfect Crystals, and Amorphous Bodies (W. H. Freeman, San Francisco, 1963).

    Google Scholar 

  14. S. Nojima and R. J. Roe, to be published.

  15. F. S. Bates, R. E. Cohen and C. V. Berney, Macromoleculee 15, 589 (1982).

    Article  CAS  Google Scholar 

  16. T. Hashimoto, M. Shibayama and H. Kawai, Macromoleculee 13, 1237 (1980).

    Article  CAS  Google Scholar 

  17. D. Rigby and R. J. Roe, Macromoleculee 19, 721 (1986).

    Article  CAS  Google Scholar 

  18. A. Vrij, J. Chem. Phys. 71, 3267 (1979); Van Beurten and A. Vrij, J. Chem. Phys. 74, 2744 (1981).

    Article  CAS  Google Scholar 

  19. L. Blum and G. Stell, J. Chem. Phys. 71, 42 (1979).

    Article  CAS  Google Scholar 

  20. M. Kotlarchyk and S. H. Chen, J. Chem. Phys. 79, 2461 (1983).

    Article  CAS  Google Scholar 

  21. D. J. Kinning and E. L. Thomas, Macromoleculee 17, 1712 (1984).

    Article  CAS  Google Scholar 

  22. J. Selb, P. Marie, A. Rameau, R. Duplessix and Y. Gallot, Polymer Bull. (Berlin) 10, 444 (1983).

    Article  CAS  Google Scholar 

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Roe, R.J. Application of SAS to Bulk Amorphous Polymers, Block Copolymers and Polymer Blends. MRS Online Proceedings Library 79, 59–69 (1986). https://doi.org/10.1557/PROC-79-59

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  • DOI: https://doi.org/10.1557/PROC-79-59

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