Self-Organized Hybrid Solids

MRS Online Proceedings Library volume 726, Article number: 72 (2002) Cite this article

Abstract

A new method has been developed for the synthesis of shaped-controlled bridged silsesquioxanes by the acid hydrolysis of urea-derived silylated precursors. This method is based on the ability of the hydrogen bonds of the urea groups to organize the molecules in a supramolecular architecture and provides after hydrolysis a new access to hybrid materials with controlled morphologies. A chirality transcription from a molecular precursor to a hybrid solid has been achieved. A right- and a left-handed helices have been obtained respectively from the chiral (R,R)- and the (S,S)-enantiomers of the diureido derivatives of trans-diaminocyclohexane. In a related way, a long range ordered hybrid solid has been obtained. Long carbon chain as spacer between the urea groups of the precursor affords lamellar hybrid silicas.

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Affiliations

  1. Hétérochimie Moléculaire et Macromoléculaire (UMR-CNRS 5076), Ecole Normale Supérieure de Chimie de Montpellier, 8, rue de l’école normale, 34296, Montpellier Cedex 05, France

    Joël J. E. Moreau, Luc Vellutini, Michel Wong Chi Man & Catherine Bied

  2. Groupe de Dynamique des Phases Condensées (UMR-CNRS 5581), Université Montpellier, II, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France

    Jean-Louis Bantignies, Philippe Dieudonné & Jean-Louis Sauvajol

Authors
  1. Joël J. E. Moreau
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  2. Luc Vellutini
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  3. Michel Wong Chi Man
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  4. Catherine Bied
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  5. Jean-Louis Bantignies
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  6. Philippe Dieudonné
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  7. Jean-Louis Sauvajol
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Correspondence to Joël J. E. Moreau.

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Moreau, J.J.E., Vellutini, L., Man, M.W.C. et al. Self-Organized Hybrid Solids. MRS Online Proceedings Library 726, 72 (2002). https://doi.org/10.1557/PROC-726-Q7.2

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