Abstract
We here report the synthesis of ordered ceramic materials with hierarchy produced by an in-situ mineralization of ordered wood cellular structures with surfactant-templated sol-gel at different pH. At low pH, a silicic acid is coated onto inner surface of wood cellular structure and it penetrates into pores left, where degraded lignin and hemicellulose are leached out, to form a positive replica, while at high pH the precipitating silica particles due to fast condensation clog the cells and pit structures to form a negative replica of wood. The calcined monoliths produced in different pHs contain ordered wood cellular structures, multi-layered cell walls, pits, vessels well-preserved with positive or negative contrasts, respectively. The surfactant-templated mineralization produces ordered hexagonal nanopores with 20Å in the cell walls after calcination.
Similar content being viewed by others
References
X. Feng G. E. Fryxell L.-Q. Wang A. Y. Kim J. Liu K. M. Kemner Science 276, 923 (1997).
K. Kageyama J. Tamajawa T. Aida Science 285, 2113 (1999)
P. T. Tanev M. Chibwe T. J. Pinnavaia Science 368, 321 (1994)
Y. Shin J. H. Chang J. Liu R. Williford Y.-K. Shin G. J. Exarhos J. Contr. Rel. 73, 1 (2001)
S. A. Davis S. L. Burkett N. H. Mendelson S. Mann Nature 385, 420 (1997)
C. T. Kresge M. E. Leonowicz W. J. Roth J. C. Vartuli J. S. Beck Nature 359, 710 (1992)
A. Karlsson M. Stöcker, R. Schmidt Microporous Mesoporous Mater. 27, 181 (1999)
B. T. Holland L. Abrams A. Stein A. J. Am. Chem. Soc. 121, 4308 (1999)
G. Scurfield E. R. Segnit Sedment. Geol. 39, 149 (1984)
R. W. Drum Science 161, 175 (1968)
T. Ota M. Takahashi T. Hibi M. Ozawa S. Suzuki Y. Hikichi J. Am. Ceram. Soc. 78, 3409 (1995)
Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing, ed. C. J. Brinker and G. W. Scherer (Academic Press:San Diego, CA,1990).
Lignin: Properties and Materials, ed. W. G. Glasser and S. Sarkanen S. (ACS Symposium Series 397;American Chemical Society:Washington, DC,1989).
R. H. Atalla J. C. Gast D. W. Sindorf V. J. Bartuska G. E. Maciel J. Am. Chem. Soc. 102, 3249 (1980)
N. G. Lewis R. A. Razal K. P. Dhara E. Tamamoto G. H. Bokelman J. B. Wooten, J. Chem. Soc. Chem. Commun. 1626 (1988)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Shin, Y., Liu, J., Wang, LQ. et al. Control of Hierarchically Ordered Positive and Negative Replicas of Wood Cellular Structures by Surfactant-Directed Sol-Gel Mineralization. MRS Online Proceedings Library 726, 54 (2002). https://doi.org/10.1557/PROC-726-Q5.4
Published:
DOI: https://doi.org/10.1557/PROC-726-Q5.4