Templated Assembly of Metal-Anion Arrays within Layered Hosts; Synthesis and Characterization of New Transition-Metal Oxyhalide Perovskites

MRS Online Proceedings Library volume 718, Article number: 34 (2002) Cite this article

Abstract

Ion exchange of Dion-Jacobson-type double- and triple-layered perovskites with divalent transition-metal halides leads to the templated assembly of metal-anion layers. A whole series of compounds of the form (MCl)LaNb2O7 (M = V, Cr, Mn, Fe, Co, Cu) and (CuCl)Ln2Ti2NbO10 (Ln = Pr, Nd, Sm, Eu) have been prepared. Additionally, a new series of host compounds is being developed to exploit this exchange chemistry; the new oxyfluorides, RbLnTiNbO6F (Ln = La, Pr, Nd) and RbLaM′NbO6F (M′ = V4+, Mn4+, Nb4+, Mo4+), have been prepared by a direct route.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

US$ 39.95

Tax calculation will be finalised during checkout.

References

  1. [1]

    M. Dion, M. Ganne, and M. Tournoux, Mater. Res. Bull., 16, 1429, (1981).

    CAS  Article  Google Scholar 

  2. [2]

    J. Gopalakrishnan, V. Bhat, and B. Raveau, Mater. Res. Bull., 22, 413, (1987).

    CAS  Article  Google Scholar 

  3. [3]

    J. Yoshimura, Y. Ebina, J. Kondo, K. Domen, and A. Tanaka, J. Phys. Chem., 97, 1970, (1993).

    CAS  Article  Google Scholar 

  4. [4]

    S. Ruddlesden and P. Popper, Acta Crystallogr., 10, 538, (1957).

    CAS  Article  Google Scholar 

  5. [5]

    A. J. Wright and C. Greaves, J. Mater. Chem., 6, 1823, (1996).

    CAS  Article  Google Scholar 

  6. [6]

    M. Richard, L. Brohan, and M. Tournoux, J. Solid State Chem., 112, 345, (1994).

    CAS  Article  Google Scholar 

  7. [7]

    K.-A. Hyeon and S.-H. Byeon, Chem. Mater. 11, 352, (1999).

    CAS  Article  Google Scholar 

  8. [8]

    R. E. Schaak and T. E. Mallouk, J. Solid State Chem., 161, 225, (2001).

    CAS  Article  Google Scholar 

  9. [9]

    A. J. Jacobson, J. W. Johnson, and J. T. Lewandowski, Inorg. Chem., 24, 3727, (1985).

    CAS  Article  Google Scholar 

  10. [10]

    S. Ikeda, A. Tanaka, K. Shinohara, M. Hara, J. N. Kondo, K. Maruya and K. Domen, Microporous Mater., 9, 253, (1997).

    CAS  Article  Google Scholar 

  11. [11]

    M. Sato, J. Abo, T. Jin, and M. Ohta, J. Alloys Comp. 192, 81, (1993).

    CAS  Article  Google Scholar 

  12. [12]

    J. G. Bednorz and K. A. Müller Z. Phys. B.: Condens. Matter. 64, 189, (1986).

    CAS  Article  Google Scholar 

  13. [13]

    M. Dion, M. Ganne, M. Tournoux, and J. Ravez Rev. Chim. Miner., 21, 92, (1984).

    CAS  Google Scholar 

  14. [14]

    R. Seshadri, C. Martin, M. Hervieu, B. Raveau, and C. N. R. Rao, Chem. Mater., 9, 270, (1997).

    CAS  Article  Google Scholar 

  15. [15]

    Y. Moritomo, A. Asamitsu, H. Kuwahara, and Y. Tokura Nature 380, 141, (1996).

    CAS  Article  Google Scholar 

  16. [16]

    T. A. Kodenkandath, J. N. Lalena, W. L. Zhou, E. E. Carpenter, C. Sangregorio, A. U. Falster, W. B. Simmons, C. J. O’Connor, and J. B. Wiley, J. Am. Chem. Soc., 121, 10743, (1999).

    CAS  Article  Google Scholar 

  17. [17]

    T. A. Kodenkandath, A. S. Kumbhar, W. L. Zhou and J. B. Wiley Inorg. Chem. 40, 710, (2001).

    CAS  Article  Google Scholar 

  18. [18]

    L. Viciu, G. Caruntu, N. Royant, J. Koenig, W. L. Zhou, T. A. Kodenkandath, and J. B. Wiley, Inorg. Chem., in press.

  19. [19]

    G. Caruntu, L. Spinu, and J. B. Wiley Mater. Res. Bull., 37, 133, (2002).

    CAS  Article  Google Scholar 

  20. [20]

    J.-H. Choy, J.-Y. Kim, S.-J. Kim, J.-S. Sohn, and O. H. Han, Chem. Mater. 13, 906, (2001).

    CAS  Article  Google Scholar 

  21. [21]

    N. S. P. Bhuvanesh and J. Gopalakrishnan J. Mater. Chem. 7, 2297, (1997).

    CAS  Article  Google Scholar 

Download references

Author information

Affiliations

  1. Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA, 70148-2820, USA

    Gabriel Caruntu, Liliana Viciu, Leonard Spinu, Weilie Zhou & John B. Wiley

Authors
  1. Gabriel Caruntu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Liliana Viciu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Leonard Spinu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Weilie Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. John B. Wiley
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to John B. Wiley.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Caruntu, G., Viciu, L., Spinu, L. et al. Templated Assembly of Metal-Anion Arrays within Layered Hosts; Synthesis and Characterization of New Transition-Metal Oxyhalide Perovskites. MRS Online Proceedings Library 718, 34 (2002). https://doi.org/10.1557/PROC-718-D3.4

Download citation