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Synthesis and Characterization of the First 1:2 Ordered Perovskite Ruthenate

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Abstract

Perovskite-like mixed metal ruthenates are of interest owing to their varied electronic and magnetic properties, which are heavily dependent on the ordering of the transition metals. We report the synthesis and structural characterization of the first 1:2 ordered perovskite ruthenate, Sr3CaRu2O9. The structure was determined from a combination of powder X-ray, electron and neutron diffraction data and is characterized by a 1:2 ordering of Ca2+ and Ru5+ over the sixcoordinate B-sites of the perovskite lattice. Sr3CaRu2O9 is the first example of this structure-type to include a majority metal with d electrons (Ru(V), d3). The relationship of this material to the K2NiF4-type Sr1.5Ca0.5RuO4 (i.e., Sr3CaRu2O8) highlights the dramatic effects of the ruthenium valence on the resultant structure. Remarkably, these two structures can be quantitatively interconverted by the appropriate choice of reaction temperature and atmosphere.

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References

  1. M.T. Anderson, K.B. Greenwood, G.A. Taylor and K.R. Poeppelmeier, Prog. Solid State Chem., 22, 197, (1993).

    Article  CAS  Google Scholar 

  2. F. Galasso and J. Pyle, Inorg. Chem., 2, 482 (1963).

    Article  CAS  Google Scholar 

  3. J.A. Alonso, E. Mzayek and I. Rasines, Mater. Res. Bull., 22, 69 (1987).

    Article  CAS  Google Scholar 

  4. R.J. Cava, J. Mater. Chem., 11, 54 (2001).

    Article  CAS  Google Scholar 

  5. P.K. Davies, J.Z. Tong and T. Negas, J. Amer. Chem. Soc., 80, 1727 (1997).

    CAS  Google Scholar 

  6. J.T. Rijssenbeek, S. Malo, V. Caignaert and K.R. Poeppelmeier, J. Amer. Chem. Soc., 124, 2090 (2002).

    Article  CAS  Google Scholar 

  7. W. Kraus and G. Nolz, J. Appl. Crystallogr., 29, 301 (1996).

    Article  CAS  Google Scholar 

  8. A.C. Larson and R.B. Von Dreele, Los Alamos National Laboratory Report LAUR 86–748 (1994).

    Google Scholar 

  9. S. Nakatsuji, T. Ando, Z. Mao and Y. Maeno, Physica C, 261, 949 (1999).

    Article  Google Scholar 

  10. J. Wilkens and H. Müller-Buschbaum, J. Alloys Compd., 177, C31 (1991).

    Article  Google Scholar 

  11. M.T. Anderson and K.R. Poeppelmeier, Chem. Mater., 3, 476 (1991).

    Article  CAS  Google Scholar 

  12. A.J. Jacobson, B.M. Collins and B.E.F. Fender, Acta Crystallogr., B24, 1968 (1982).

    Google Scholar 

  13. I. Levin, L.A. Bendersky, J.P. Cline, R.S. Roth and T.A. Vanderah, J. Solid State Chem., 150, 43 (2000).

    Article  CAS  Google Scholar 

  14. A.M. Glazer, Acta Crystallogr., B28, 3384 (1972).

    Article  Google Scholar 

  15. M. Hervieu, F. Studer and B. Raveau, J. Solid State Chem., 22, 273 (1977).

    Article  CAS  Google Scholar 

  16. C. Dussarrat, J. Fompeyrine and J. Darriet, Eur. J. Solid State Inorg. Chem., 32, 3 (1995).

    CAS  Google Scholar 

  17. A. Kanbayashi, J. Phys. Soc. Jpn., 41, 1876 (1976).

    Article  Google Scholar 

  18. P.D. Battle and W.J. Macklin, J. Solid State Chem., 52, 138 (1984).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Northwestern University, Evanston, IL, 60208-3113, USA

    Job Rijssenbeek & Kenneth R. Poeppelmeier

  2. Laboratoire CRISMAT-ISMRA, Université de Caen, 6 Boulevard du Maréchal Juin, 14050 Caen, Cedex, France

    Sylvie Malo & Vincent Caignaert

  3. Institute for Chemical Research, Kyoto University, Uji, Kyoto-fu, 611, Japan

    Takashi Saito, Masaki Azuma & Mikio Takano

Authors
  1. Job Rijssenbeek
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  2. Sylvie Malo
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  3. Takashi Saito
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  4. Vincent Caignaert
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  5. Masaki Azuma
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  6. Mikio Takano
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  7. Kenneth R. Poeppelmeier
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Rijssenbeek, J., Malo, S., Saito, T. et al. Synthesis and Characterization of the First 1:2 Ordered Perovskite Ruthenate. MRS Online Proceedings Library 718, 13 (2002). https://doi.org/10.1557/PROC-718-D1.3

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  • DOI: https://doi.org/10.1557/PROC-718-D1.3

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