Novel Guest-Host NLO Polyimide Based on Two-Dimensional Carbazole Chromophores


Taking advantage of the multifunctional characteristics of carbazole along with rational molecular design, several two-dimensional carbazole chromophores were acquired. Doping the chromophores into poly(ether imide), a series of NLO-active guest-host polymers were obtained. The compatibility between chromophores and poly(ether imide) was investigated by SEM and extraction experiment. After poling, these NLO poly(ether imide)s with large second-order nonlinearities were achieved. Correlation between structure and nonlinear optical characteristics, and the chromophore size effect on the thermal and temporal stability have been probed. Large rotational cone volumes make the two-dimensional chromophores possessing excellent orientational stability at 60.

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  1. 1.

    Device Concepts, “Introduction to Nonlinear Optical Effects in Molecules and Polymers”, ed. P. N. Prasad, and D. J. Williams (John Wiley, 1991), pp272–294.

  2. 2.

    G. A. Lindsay, Second-Order Nonlinear Optical Polymers: An Overview, “Polymers for Second-Order Nonlinear Optics”, ed. G. A. Lindsay, K. D. Singer, (ACS, Washington, 1995) pp1–19.

    Google Scholar 

  3. 3.

    H. Yamamoto, S. Katogi, T. Watanabe, H. Sato, S. Miyata and T. Hosomi, Appl. Phys. Lett. 1992, 60, 935.

    CAS  Article  Google Scholar 

  4. 4.

    J. Zyss and L. L. Oudar, Phys. Rev. A 1982, 26, 2016 and 2018.

    Article  Google Scholar 

  5. 5.

    T. Wada, T. Isoshima, T. Aoyama, Y. Zhang, L. Wang, T. L. Bredas, K. Sasaki, and H. Sasabe, Two-dimensional charge-transfer molecules for poled polymer applications, Advances in Nonlinear Optic IV: Poled Polymers and Their Applications to SHG and EO Devices”, ed. S. Miyata, and H. Sasabe (Gordon and Breach Science, 1997) pp. 87–98.

    Google Scholar 

  6. 6.

    Z. Peng, Z. Bao, L. Yu, J. Am. Chem. Soc. 1994, 116, 6003.

    Article  Google Scholar 

  7. 7.

    Y. Zhang, S. Ghosal, M. K. Casstevens, R. Burzyaski, Appl. Phys. Lett. 1994, 66, 2561.

    Google Scholar 

  8. 8.

    W. J. Kuo, G. H. Hsiue and R. J. Jeng Macromolecules, 2001, 34 (7), 2373.

    CAS  Article  Google Scholar 

  9. 9.

    E. M. Breitung, C. F. Shu, R. J. McMahon, J. Am. Chem. Soc. 2000, 122, 1154.

    CAS  Article  Google Scholar 

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Correspondence to Wen-Jang Kuo.

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Kuo, WJ., Hsiue, GH. & Jeng, RJ. Novel Guest-Host NLO Polyimide Based on Two-Dimensional Carbazole Chromophores. MRS Online Proceedings Library 665, 526 (2000).

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